PHOTOCHEMICAL OXIDATION OF HIGHMOLECULAR BR POLYDIMETHYLSILOXANE RUBBER

Photochemical oxidation of BR polydimethylsiloxane rubber during irradiation by the full light of DRT-1000 lamp over atmospheric oxygen was studied by the methods of Fourier Transform Infrared Spectroscopy and chemical treatment. The studies found that in these conditions crosslinking reaction of po...

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Main Authors: S. V. Luzgarev, A. S. Luzgarev, A. V. Voronezhtseva, Yu A. Sheveleva, V. Ya. Denisov
Format: Article
Language:English
Published: Kemerovo State University 2014-09-01
Series:Вестник Кемеровского государственного университета
Subjects:
Online Access:https://vestnik.kemsu.ru/jour/article/view/1254
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author S. V. Luzgarev
A. S. Luzgarev
A. V. Voronezhtseva
Yu A. Sheveleva
V. Ya. Denisov
author_facet S. V. Luzgarev
A. S. Luzgarev
A. V. Voronezhtseva
Yu A. Sheveleva
V. Ya. Denisov
author_sort S. V. Luzgarev
collection DOAJ
description Photochemical oxidation of BR polydimethylsiloxane rubber during irradiation by the full light of DRT-1000 lamp over atmospheric oxygen was studied by the methods of Fourier Transform Infrared Spectroscopy and chemical treatment. The studies found that in these conditions crosslinking reaction of polymer with formation of intermolecular dimethylene bonds are observed, accompanied by their subsequent oxidation and formation of relatively stable carbonyl and carboxyl polymeric compounds.
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spelling doaj.art-149bf95f3c8e4b6f844684f87d7ea1732023-07-13T12:08:49ZengKemerovo State UniversityВестник Кемеровского государственного университета2078-89752078-89832014-09-0103-32312341253PHOTOCHEMICAL OXIDATION OF HIGHMOLECULAR BR POLYDIMETHYLSILOXANE RUBBERS. V. Luzgarev0A. S. Luzgarev1A. V. Voronezhtseva2Yu A. Sheveleva3V. Ya. Denisov4Kemerovo State UniversityKemerovo State UniversityKemerovo State UniversityKemerovo State UniversityKemerovo State UniversityPhotochemical oxidation of BR polydimethylsiloxane rubber during irradiation by the full light of DRT-1000 lamp over atmospheric oxygen was studied by the methods of Fourier Transform Infrared Spectroscopy and chemical treatment. The studies found that in these conditions crosslinking reaction of polymer with formation of intermolecular dimethylene bonds are observed, accompanied by their subsequent oxidation and formation of relatively stable carbonyl and carboxyl polymeric compounds.https://vestnik.kemsu.ru/jour/article/view/1254polydimethylsiloxane rubberultraviolet lightphotochemical reactionsphotooxidation
spellingShingle S. V. Luzgarev
A. S. Luzgarev
A. V. Voronezhtseva
Yu A. Sheveleva
V. Ya. Denisov
PHOTOCHEMICAL OXIDATION OF HIGHMOLECULAR BR POLYDIMETHYLSILOXANE RUBBER
Вестник Кемеровского государственного университета
polydimethylsiloxane rubber
ultraviolet light
photochemical reactions
photooxidation
title PHOTOCHEMICAL OXIDATION OF HIGHMOLECULAR BR POLYDIMETHYLSILOXANE RUBBER
title_full PHOTOCHEMICAL OXIDATION OF HIGHMOLECULAR BR POLYDIMETHYLSILOXANE RUBBER
title_fullStr PHOTOCHEMICAL OXIDATION OF HIGHMOLECULAR BR POLYDIMETHYLSILOXANE RUBBER
title_full_unstemmed PHOTOCHEMICAL OXIDATION OF HIGHMOLECULAR BR POLYDIMETHYLSILOXANE RUBBER
title_short PHOTOCHEMICAL OXIDATION OF HIGHMOLECULAR BR POLYDIMETHYLSILOXANE RUBBER
title_sort photochemical oxidation of highmolecular br polydimethylsiloxane rubber
topic polydimethylsiloxane rubber
ultraviolet light
photochemical reactions
photooxidation
url https://vestnik.kemsu.ru/jour/article/view/1254
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AT asluzgarev photochemicaloxidationofhighmolecularbrpolydimethylsiloxanerubber
AT avvoronezhtseva photochemicaloxidationofhighmolecularbrpolydimethylsiloxanerubber
AT yuasheveleva photochemicaloxidationofhighmolecularbrpolydimethylsiloxanerubber
AT vyadenisov photochemicaloxidationofhighmolecularbrpolydimethylsiloxanerubber