Method for calculating the surface tension of hydrocarbons
A method of surface tension calculation used by Sugden is based on the difference in the densities of a liquid and its vapor. A similar result was obtained by Bachynskyi. To expand the field of application of the formula for polar liquids Steele polarity factor was introduced. The experimental data...
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Format: | Article |
Language: | Russian |
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MIREA - Russian Technological University
2013-12-01
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Series: | Тонкие химические технологии |
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Online Access: | https://www.finechem-mirea.ru/jour/article/view/512 |
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author | E. V. Rytova B. A. Arutyunov |
author_facet | E. V. Rytova B. A. Arutyunov |
author_sort | E. V. Rytova |
collection | DOAJ |
description | A method of surface tension calculation used by Sugden is based on the difference in the densities of a liquid and its vapor. A similar result was obtained by Bachynskyi. To expand the field of application of the formula for polar liquids Steele polarity factor was introduced. The experimental data have an error of up to 3%. The generalized processing of the experimental data by the surface tension of hydrocarbons enables to obtain a calculation formula for determining the temperature dependence of the modified surface tension of hydrocarbons. Parameters (temperature and surface tension) corresponding to minimum of free energy for the liquid – vapor phase transition were used as modification scales when constructing the generalized dependencies. The developed method was used to summarize the experimental data by the surface tension of gas condensates of different areas. |
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format | Article |
id | doaj.art-14a1dfe353f94e26b38534dcf60f960a |
institution | Directory Open Access Journal |
issn | 2410-6593 2686-7575 |
language | Russian |
last_indexed | 2024-04-10T03:29:21Z |
publishDate | 2013-12-01 |
publisher | MIREA - Russian Technological University |
record_format | Article |
series | Тонкие химические технологии |
spelling | doaj.art-14a1dfe353f94e26b38534dcf60f960a2023-03-13T07:25:35ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752013-12-018659621540Method for calculating the surface tension of hydrocarbonsE. V. Rytova0B. A. Arutyunov1M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571A method of surface tension calculation used by Sugden is based on the difference in the densities of a liquid and its vapor. A similar result was obtained by Bachynskyi. To expand the field of application of the formula for polar liquids Steele polarity factor was introduced. The experimental data have an error of up to 3%. The generalized processing of the experimental data by the surface tension of hydrocarbons enables to obtain a calculation formula for determining the temperature dependence of the modified surface tension of hydrocarbons. Parameters (temperature and surface tension) corresponding to minimum of free energy for the liquid – vapor phase transition were used as modification scales when constructing the generalized dependencies. The developed method was used to summarize the experimental data by the surface tension of gas condensates of different areas.https://www.finechem-mirea.ru/jour/article/view/512surface tension, density, dimensionless number, hydrocarbons. |
spellingShingle | E. V. Rytova B. A. Arutyunov Method for calculating the surface tension of hydrocarbons Тонкие химические технологии surface tension, density, dimensionless number, hydrocarbons. |
title | Method for calculating the surface tension of hydrocarbons |
title_full | Method for calculating the surface tension of hydrocarbons |
title_fullStr | Method for calculating the surface tension of hydrocarbons |
title_full_unstemmed | Method for calculating the surface tension of hydrocarbons |
title_short | Method for calculating the surface tension of hydrocarbons |
title_sort | method for calculating the surface tension of hydrocarbons |
topic | surface tension, density, dimensionless number, hydrocarbons. |
url | https://www.finechem-mirea.ru/jour/article/view/512 |
work_keys_str_mv | AT evrytova methodforcalculatingthesurfacetensionofhydrocarbons AT baarutyunov methodforcalculatingthesurfacetensionofhydrocarbons |