Intermetallics Formation during Solidification of Al-Si-Cu-Mg Cast Alloys

The present study was undertaken to examine the effect of iron, manganese, copper and magnesium on the microstructural characteristics of Al-11%Si-2%Cu-Mg-based alloy referred to as 396 under different working conditions. The results show that strontium (Sr) has high affinity to react with magnesium...

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Main Authors: Adel M. A. Mohamed, Ehab Samuel, Yasser Zedan, Agnes M. Samuel, Herbert W. Doty, Fawzy H. Samuel
Format: Article
Language:English
Published: MDPI AG 2022-02-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/15/4/1335
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author Adel M. A. Mohamed
Ehab Samuel
Yasser Zedan
Agnes M. Samuel
Herbert W. Doty
Fawzy H. Samuel
author_facet Adel M. A. Mohamed
Ehab Samuel
Yasser Zedan
Agnes M. Samuel
Herbert W. Doty
Fawzy H. Samuel
author_sort Adel M. A. Mohamed
collection DOAJ
description The present study was undertaken to examine the effect of iron, manganese, copper and magnesium on the microstructural characteristics of Al-11%Si-2%Cu-Mg-based alloy referred to as 396 under different working conditions. The results show that strontium (Sr) has high affinity to react with magnesium (Mg), resulting in reduced effectiveness as eutectic silicon modifier or age hardening agent. In addition, Sr alters the sequence of the precipitation of the α-AlFeMnSi phase from post-eutectic to pro-eutectic which would harden the soft α-Aluminum matrix. The mechanism is still under investigation. The interactions between iron (Fe) and Mg and Sr-Mg result in the formation of serval dissolvable intermetallics during the solutionizing treatment such as β-AlFeSi, π-AlFeMgSi and Q-AlMgSiCu phases. The study also emphasizes the role of modification and grain refining as well as intermetallics in porosity formation and hardness of samples aged in the temperature range 155–240 °C.
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spelling doaj.art-14c459d3b66542ccbd6d5a337bb27f2d2023-11-23T20:51:38ZengMDPI AGMaterials1996-19442022-02-01154133510.3390/ma15041335Intermetallics Formation during Solidification of Al-Si-Cu-Mg Cast AlloysAdel M. A. Mohamed0Ehab Samuel1Yasser Zedan2Agnes M. Samuel3Herbert W. Doty4Fawzy H. Samuel5Metallurgical and Materials Engineering Department, Faculty of Petroleum and Mining Engineering, Suez University, Suez 43721, EgyptDépartement des Sciences Appliquées, Université du Québec à Chicoutimi, Saguenay, QC G7H 2B1, CanadaÉcole de Technologie Supérieure, Département de Génie Mécanique, Montréal, QC H3C 1K3, CanadaDépartement des Sciences Appliquées, Université du Québec à Chicoutimi, Saguenay, QC G7H 2B1, CanadaGeneral Motors Global Technology Center, Materials Technology, Estes Bldg, 30003 Fisher Brothers Rd., Warren, MI 48093-2350, USADépartement des Sciences Appliquées, Université du Québec à Chicoutimi, Saguenay, QC G7H 2B1, CanadaThe present study was undertaken to examine the effect of iron, manganese, copper and magnesium on the microstructural characteristics of Al-11%Si-2%Cu-Mg-based alloy referred to as 396 under different working conditions. The results show that strontium (Sr) has high affinity to react with magnesium (Mg), resulting in reduced effectiveness as eutectic silicon modifier or age hardening agent. In addition, Sr alters the sequence of the precipitation of the α-AlFeMnSi phase from post-eutectic to pro-eutectic which would harden the soft α-Aluminum matrix. The mechanism is still under investigation. The interactions between iron (Fe) and Mg and Sr-Mg result in the formation of serval dissolvable intermetallics during the solutionizing treatment such as β-AlFeSi, π-AlFeMgSi and Q-AlMgSiCu phases. The study also emphasizes the role of modification and grain refining as well as intermetallics in porosity formation and hardness of samples aged in the temperature range 155–240 °C.https://www.mdpi.com/1996-1944/15/4/1335Al-Si alloysintermetallicssolidificationphase identificationEPMAporosity
spellingShingle Adel M. A. Mohamed
Ehab Samuel
Yasser Zedan
Agnes M. Samuel
Herbert W. Doty
Fawzy H. Samuel
Intermetallics Formation during Solidification of Al-Si-Cu-Mg Cast Alloys
Materials
Al-Si alloys
intermetallics
solidification
phase identification
EPMA
porosity
title Intermetallics Formation during Solidification of Al-Si-Cu-Mg Cast Alloys
title_full Intermetallics Formation during Solidification of Al-Si-Cu-Mg Cast Alloys
title_fullStr Intermetallics Formation during Solidification of Al-Si-Cu-Mg Cast Alloys
title_full_unstemmed Intermetallics Formation during Solidification of Al-Si-Cu-Mg Cast Alloys
title_short Intermetallics Formation during Solidification of Al-Si-Cu-Mg Cast Alloys
title_sort intermetallics formation during solidification of al si cu mg cast alloys
topic Al-Si alloys
intermetallics
solidification
phase identification
EPMA
porosity
url https://www.mdpi.com/1996-1944/15/4/1335
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