Poly[[(μ3-adamantane-1,3-dicarboxylato)aqua[μ-N-(pyridin-3-yl)isonicotinamide]nickel(II)] monohydrate], a layered coordination polymer with (4,4) topology

The title compound, {[Ni(C12H14O4)(C11H9N3O)(H2O)]·H2O}n, contains octahedrally coordinated NiII ions ligated by adamantane-1,3-dicarboxylate (adc) and N-(pyridin-3-yl)isonicotinamide (3-pina) ligands forming coordination polymer layers with a (4,4) grid topology. These diperiodic layer motifs aggre...

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Bibliographic Details
Main Authors: Jamelah Z. Travis, Robert L. LaDuca
Format: Article
Language:English
Published: International Union of Crystallography 2023-09-01
Series:IUCrData
Subjects:
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314623007587
Description
Summary:The title compound, {[Ni(C12H14O4)(C11H9N3O)(H2O)]·H2O}n, contains octahedrally coordinated NiII ions ligated by adamantane-1,3-dicarboxylate (adc) and N-(pyridin-3-yl)isonicotinamide (3-pina) ligands forming coordination polymer layers with a (4,4) grid topology. These diperiodic layer motifs aggregate in an AAA pattern mediated by supramolecular C—H...O interactions to form the full triperiodic crystal structure of the title compound.
ISSN:2414-3146