Short hydrogen-bond network confined on COF surfaces enables ultrahigh proton conductivity
When hydronium ions are enriched in confined water, short hydrogen bonds (SHBs) form due to the constrained space of excess protons between pairs of water molecules. Here authors demonstrate a SHB network confined on the surface of ionic COF membranes with tunable -SO3H groups, with proton conductiv...
| Main Authors: | , , , , , , , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2022-11-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-022-33868-8 |
| _version_ | 1811223833245384704 |
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| author | Benbing Shi Xiao Pang Shunning Li Hong Wu Jianliang Shen Xiaoyao Wang Chunyang Fan Li Cao Tianhao Zhu Ming Qiu Zhuoyu Yin Yan Kong Yiqin Liu Mingzheng Zhang Yawei Liu Feng Pan Zhongyi Jiang |
| author_facet | Benbing Shi Xiao Pang Shunning Li Hong Wu Jianliang Shen Xiaoyao Wang Chunyang Fan Li Cao Tianhao Zhu Ming Qiu Zhuoyu Yin Yan Kong Yiqin Liu Mingzheng Zhang Yawei Liu Feng Pan Zhongyi Jiang |
| author_sort | Benbing Shi |
| collection | DOAJ |
| description | When hydronium ions are enriched in confined water, short hydrogen bonds (SHBs) form due to the constrained space of excess protons between pairs of water molecules. Here authors demonstrate a SHB network confined on the surface of ionic COF membranes with tunable -SO3H groups, with proton conductivity of 1389 mS cm-1 at 90 oC. |
| first_indexed | 2024-04-12T08:39:11Z |
| format | Article |
| id | doaj.art-151dd91b1d64481699dae8f0838523a2 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-04-12T08:39:11Z |
| publishDate | 2022-11-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-151dd91b1d64481699dae8f0838523a22022-12-22T03:39:56ZengNature PortfolioNature Communications2041-17232022-11-011311910.1038/s41467-022-33868-8Short hydrogen-bond network confined on COF surfaces enables ultrahigh proton conductivityBenbing Shi0Xiao Pang1Shunning Li2Hong Wu3Jianliang Shen4Xiaoyao Wang5Chunyang Fan6Li Cao7Tianhao Zhu8Ming Qiu9Zhuoyu Yin10Yan Kong11Yiqin Liu12Mingzheng Zhang13Yawei Liu14Feng Pan15Zhongyi Jiang16Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin UniversityKey Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin UniversitySchool of Advanced Materials, Peking University Shenzhen Graduate SchoolKey Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin UniversityKey Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin UniversityKey Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin UniversityKey Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin UniversityKey Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin UniversityKey Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin UniversityKey Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin UniversityKey Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin UniversityKey Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin UniversityKey Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin UniversitySchool of Advanced Materials, Peking University Shenzhen Graduate SchoolBeijing Key Laboratory of Ionic Liquids Clean Process, CAS Key Laboratory of Green Process and Engineering, State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of SciencesSchool of Advanced Materials, Peking University Shenzhen Graduate SchoolKey Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin UniversityWhen hydronium ions are enriched in confined water, short hydrogen bonds (SHBs) form due to the constrained space of excess protons between pairs of water molecules. Here authors demonstrate a SHB network confined on the surface of ionic COF membranes with tunable -SO3H groups, with proton conductivity of 1389 mS cm-1 at 90 oC.https://doi.org/10.1038/s41467-022-33868-8 |
| spellingShingle | Benbing Shi Xiao Pang Shunning Li Hong Wu Jianliang Shen Xiaoyao Wang Chunyang Fan Li Cao Tianhao Zhu Ming Qiu Zhuoyu Yin Yan Kong Yiqin Liu Mingzheng Zhang Yawei Liu Feng Pan Zhongyi Jiang Short hydrogen-bond network confined on COF surfaces enables ultrahigh proton conductivity Nature Communications |
| title | Short hydrogen-bond network confined on COF surfaces enables ultrahigh proton conductivity |
| title_full | Short hydrogen-bond network confined on COF surfaces enables ultrahigh proton conductivity |
| title_fullStr | Short hydrogen-bond network confined on COF surfaces enables ultrahigh proton conductivity |
| title_full_unstemmed | Short hydrogen-bond network confined on COF surfaces enables ultrahigh proton conductivity |
| title_short | Short hydrogen-bond network confined on COF surfaces enables ultrahigh proton conductivity |
| title_sort | short hydrogen bond network confined on cof surfaces enables ultrahigh proton conductivity |
| url | https://doi.org/10.1038/s41467-022-33868-8 |
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