Dimeric Self-assembling via Hydrogen Bonding and Emissive Behavior of a New Copper (I) Complex
<p class="orbitalabstract">This work describes the synthesis, structural characterization and emissive behavior of a new copper (I) complex based on 1-thiocarbamoyl-5-(4-methoxiphenyl)-3-phenyl-4,5-dihydro-1H-pyrazole ligand. A dimeric self-assembling via hydrogen bonding was determi...
| Main Authors: | , , , , , , , , , |
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| Format: | Article |
| Language: | English |
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Universidade Federal de Mato Grosso do Sul
2017-04-01
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| Series: | Orbital: The Electronic Journal of Chemistry |
| Subjects: | |
| Online Access: | http://orbital.ufms.br/index.php/Chemistry/article/view/952 |
| _version_ | 1818976832783908864 |
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| author | Juciely M. dos Reis Bruna F. R. Martin Lis R. V. Favarin P. P. Rosa G. B. Laranjeira Cristiane F. Almeida Silvio Cesar de Oliveira Lucas Pizzuti Amilcar Machulek Junior Gleison Antonio Casagrande |
| author_facet | Juciely M. dos Reis Bruna F. R. Martin Lis R. V. Favarin P. P. Rosa G. B. Laranjeira Cristiane F. Almeida Silvio Cesar de Oliveira Lucas Pizzuti Amilcar Machulek Junior Gleison Antonio Casagrande |
| author_sort | Juciely M. dos Reis |
| collection | DOAJ |
| description | <p class="orbitalabstract">This work describes the synthesis, structural characterization and emissive behavior of a new copper (I) complex based on 1-thiocarbamoyl-5-(4-methoxiphenyl)-3-phenyl-4,5-dihydro-1H-pyrazole ligand. A dimeric self-assembling via hydrogen bonding was determined by analyzing the short contacts present in the solid-state structure by means of X-ray crystallography. The spectroscopic properties were determined using UV-Vis and fluorescence experiments and an interesting behavior as bluish luminescence was assigned mainly to the mixed (MLCT + IL) electronic transitions of the Cu(I)d<sup>10</sup> ® (S=C–N<sub>ligand</sub>) type. The complete characterization of the new copper (I) complex also included elemental analyses and IR spectroscopy.</p><p class="orbitalabstract"> </p><p class="orbitalabstract">DOI: <a href="http://dx.doi.org/10.17807/orbital.v9i1.952">http://dx.doi.org/10.17807/orbital.v9i1.952</a></p> |
| first_indexed | 2024-12-20T16:18:07Z |
| format | Article |
| id | doaj.art-1520f3c383ef4f61bfe19e1e190368c3 |
| institution | Directory Open Access Journal |
| issn | 1984-6428 |
| language | English |
| last_indexed | 2024-12-20T16:18:07Z |
| publishDate | 2017-04-01 |
| publisher | Universidade Federal de Mato Grosso do Sul |
| record_format | Article |
| series | Orbital: The Electronic Journal of Chemistry |
| spelling | doaj.art-1520f3c383ef4f61bfe19e1e190368c32022-12-21T19:33:43ZengUniversidade Federal de Mato Grosso do SulOrbital: The Electronic Journal of Chemistry1984-64282017-04-0191899410.17807/orbital.v9i1.952415Dimeric Self-assembling via Hydrogen Bonding and Emissive Behavior of a New Copper (I) ComplexJuciely M. dos Reis0Bruna F. R. Martin1Lis R. V. Favarin2P. P. Rosa3G. B. Laranjeira4Cristiane F. Almeida5Silvio Cesar de Oliveira6Lucas Pizzuti7Amilcar Machulek Junior8Gleison Antonio Casagrande9Universidade Federal de Mato Grosso do Sul, Campo Grande, MSUniversidade Federal de Mato Grosso do Sul, Campo Grande, MSUniversidade Federal de Mato Grosso do Sul, Campo Grande, MSUniversidade Federal de Mato Grosso do Sul, Campo Grande, MSUniversidade Federal de Mato Grosso do Sul, Campo Grande, MSUniversidade Federal de Mato Grosso do Sul, Campo Grande, MSUniversidade Federal de Mato Grosso do Sul, Campo Grande, MSUniversidade Federal da Grande Dourados, MSUniversidade Federal de Mato Grosso do Sul, Campo Grande, MSUniversidade Federal de Mato Grosso do Sul, Campo Grande, MS<p class="orbitalabstract">This work describes the synthesis, structural characterization and emissive behavior of a new copper (I) complex based on 1-thiocarbamoyl-5-(4-methoxiphenyl)-3-phenyl-4,5-dihydro-1H-pyrazole ligand. A dimeric self-assembling via hydrogen bonding was determined by analyzing the short contacts present in the solid-state structure by means of X-ray crystallography. The spectroscopic properties were determined using UV-Vis and fluorescence experiments and an interesting behavior as bluish luminescence was assigned mainly to the mixed (MLCT + IL) electronic transitions of the Cu(I)d<sup>10</sup> ® (S=C–N<sub>ligand</sub>) type. The complete characterization of the new copper (I) complex also included elemental analyses and IR spectroscopy.</p><p class="orbitalabstract"> </p><p class="orbitalabstract">DOI: <a href="http://dx.doi.org/10.17807/orbital.v9i1.952">http://dx.doi.org/10.17807/orbital.v9i1.952</a></p>http://orbital.ufms.br/index.php/Chemistry/article/view/952copper (i) complexluminescent materialsx-ray difractometry |
| spellingShingle | Juciely M. dos Reis Bruna F. R. Martin Lis R. V. Favarin P. P. Rosa G. B. Laranjeira Cristiane F. Almeida Silvio Cesar de Oliveira Lucas Pizzuti Amilcar Machulek Junior Gleison Antonio Casagrande Dimeric Self-assembling via Hydrogen Bonding and Emissive Behavior of a New Copper (I) Complex Orbital: The Electronic Journal of Chemistry copper (i) complex luminescent materials x-ray difractometry |
| title | Dimeric Self-assembling via Hydrogen Bonding and Emissive Behavior of a New Copper (I) Complex |
| title_full | Dimeric Self-assembling via Hydrogen Bonding and Emissive Behavior of a New Copper (I) Complex |
| title_fullStr | Dimeric Self-assembling via Hydrogen Bonding and Emissive Behavior of a New Copper (I) Complex |
| title_full_unstemmed | Dimeric Self-assembling via Hydrogen Bonding and Emissive Behavior of a New Copper (I) Complex |
| title_short | Dimeric Self-assembling via Hydrogen Bonding and Emissive Behavior of a New Copper (I) Complex |
| title_sort | dimeric self assembling via hydrogen bonding and emissive behavior of a new copper i complex |
| topic | copper (i) complex luminescent materials x-ray difractometry |
| url | http://orbital.ufms.br/index.php/Chemistry/article/view/952 |
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