STUDY ON SYNTHESIS AND CRYSTAL STRUCTURE OF TETRAKIS-(μ2-ACETATO)-DIHYDRATE-DICOPPER(II)
A new binuclear Cu(II) complex, tetrakis-(μ2-acetato)-dihydrate-dicopper (II), has been prepared by the reaction of Cu(OAc)2·H2O with 2-formyl-benzenesulfonate-hydrazine in the CH3CH2OH/H2O (v : v = 1 : 1). It was characterized by elemental analysis, IR and X-ray single crystal diffraction analysis....
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| Format: | Article |
| Language: | English |
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2015-10-01
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| Series: | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
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| Online Access: | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201503&vol=3&aid=4303 |
| _version_ | 1819062036939669504 |
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| author | LI-HUA WANG |
| author_facet | LI-HUA WANG |
| author_sort | LI-HUA WANG |
| collection | DOAJ |
| description | A new binuclear Cu(II) complex, tetrakis-(μ2-acetato)-dihydrate-dicopper (II), has been prepared by the reaction of Cu(OAc)2·H2O with 2-formyl-benzenesulfonate-hydrazine in the CH3CH2OH/H2O (v : v = 1 : 1). It was characterized by elemental analysis, IR and X-ray single crystal diffraction analysis. The crystal of the Cu(II) complex belongs to monoclinic, space group C2/c with a = 13.162(3) Å, b = 8.5572(17) Å, c = 13.860(3) Å, β = 117.06(3) º, V = 1390.1(5) Å3, Z = 4, Dc = 1.889 μg·m-3, μ = 3.103 mm-1, F(000) = 792, and final R1 = 0.0548, wR2 = 0.1410. Two Cu(II) centers are bridged by oxygen atoms of carboxylato groups. Each Cu(II) center is five-coordinated with four O donor atoms of acetate and a O donor of coordinated water molecule. The molecules form three dimensional network structures by the inaction of π-π stacking and hydrogen bonds. |
| first_indexed | 2024-12-21T14:52:24Z |
| format | Article |
| id | doaj.art-1522d1aa3cc74063885a51774fea1bc6 |
| institution | Directory Open Access Journal |
| issn | 1582-540X 1582-540X |
| language | English |
| last_indexed | 2024-12-21T14:52:24Z |
| publishDate | 2015-10-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| spelling | doaj.art-1522d1aa3cc74063885a51774fea1bc62022-12-21T18:59:51ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X1582-540X2015-10-01163261267STUDY ON SYNTHESIS AND CRYSTAL STRUCTURE OF TETRAKIS-(μ2-ACETATO)-DIHYDRATE-DICOPPER(II)LI-HUA WANG0College of Information and Engineering, Weifang University, Weifang 261061, P. R. China A new binuclear Cu(II) complex, tetrakis-(μ2-acetato)-dihydrate-dicopper (II), has been prepared by the reaction of Cu(OAc)2·H2O with 2-formyl-benzenesulfonate-hydrazine in the CH3CH2OH/H2O (v : v = 1 : 1). It was characterized by elemental analysis, IR and X-ray single crystal diffraction analysis. The crystal of the Cu(II) complex belongs to monoclinic, space group C2/c with a = 13.162(3) Å, b = 8.5572(17) Å, c = 13.860(3) Å, β = 117.06(3) º, V = 1390.1(5) Å3, Z = 4, Dc = 1.889 μg·m-3, μ = 3.103 mm-1, F(000) = 792, and final R1 = 0.0548, wR2 = 0.1410. Two Cu(II) centers are bridged by oxygen atoms of carboxylato groups. Each Cu(II) center is five-coordinated with four O donor atoms of acetate and a O donor of coordinated water molecule. The molecules form three dimensional network structures by the inaction of π-π stacking and hydrogen bonds.http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201503&vol=3&aid=4303binuclearcrystal structureCu (II) complexsynthesis |
| spellingShingle | LI-HUA WANG STUDY ON SYNTHESIS AND CRYSTAL STRUCTURE OF TETRAKIS-(μ2-ACETATO)-DIHYDRATE-DICOPPER(II) Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry binuclear crystal structure Cu (II) complex synthesis |
| title | STUDY ON SYNTHESIS AND CRYSTAL STRUCTURE OF TETRAKIS-(μ2-ACETATO)-DIHYDRATE-DICOPPER(II) |
| title_full | STUDY ON SYNTHESIS AND CRYSTAL STRUCTURE OF TETRAKIS-(μ2-ACETATO)-DIHYDRATE-DICOPPER(II) |
| title_fullStr | STUDY ON SYNTHESIS AND CRYSTAL STRUCTURE OF TETRAKIS-(μ2-ACETATO)-DIHYDRATE-DICOPPER(II) |
| title_full_unstemmed | STUDY ON SYNTHESIS AND CRYSTAL STRUCTURE OF TETRAKIS-(μ2-ACETATO)-DIHYDRATE-DICOPPER(II) |
| title_short | STUDY ON SYNTHESIS AND CRYSTAL STRUCTURE OF TETRAKIS-(μ2-ACETATO)-DIHYDRATE-DICOPPER(II) |
| title_sort | study on synthesis and crystal structure of tetrakis μ2 acetato dihydrate dicopper ii |
| topic | binuclear crystal structure Cu (II) complex synthesis |
| url | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201503&vol=3&aid=4303 |
| work_keys_str_mv | AT lihuawang studyonsynthesisandcrystalstructureoftetrakism2acetatodihydratedicopperii |