Roles of Interfacial Modifiers in Inorganic Titania/Organic Poly(3-hexylthiophene) Heterojunction Hybrid Solar Cells

Hybrid Titanium dioxide/Poly(3-hexylthiophene) heterojunction solar cells have gained research interest as they have the potential to become cost-effective solar technology in the future. Limited power conversion efficiencies of about 5–6% have been reported so far, and an enhancement in efficiency...

Full description

Bibliographic Details
Main Authors: Arumugam Pirashanthan, Thirunavukarasu Kajana, Dhayalan Velauthapillai, Yohi Shivatharsiny, Said Bentouba, Punniamoorthy Ravirajan
Format: Article
Language:English
Published: MDPI AG 2022-02-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/12/5/820
_version_ 1797474209357627392
author Arumugam Pirashanthan
Thirunavukarasu Kajana
Dhayalan Velauthapillai
Yohi Shivatharsiny
Said Bentouba
Punniamoorthy Ravirajan
author_facet Arumugam Pirashanthan
Thirunavukarasu Kajana
Dhayalan Velauthapillai
Yohi Shivatharsiny
Said Bentouba
Punniamoorthy Ravirajan
author_sort Arumugam Pirashanthan
collection DOAJ
description Hybrid Titanium dioxide/Poly(3-hexylthiophene) heterojunction solar cells have gained research interest as they have the potential to become cost-effective solar technology in the future. Limited power conversion efficiencies of about 5–6% have been reported so far, and an enhancement in efficiency was achieved through the engineering of the interface between Titanium dioxide (TiO<sub>2</sub>) and Poly(3-hexylthiophene) (P3HT). Evolution of this solar cell technology is relatively slow-moving due to the complex features of the metal oxide-polymer system and the limited understanding of the technology. In this review, we focus on recent developments in interface modified hybrid Titanium dioxide/Poly(3-hexylthiophene) solar cells, provide a short discussion on the working principle, device structure with interface modifiers, and summarize various types of interface modifiers studied to enhance the photovoltaic performance of hybrid TiO<sub>2</sub>/P3HT heterojunction solar cells. Further, we discuss the key factors influencing the power conversion efficiency and the role of a variety of interface modifiers in this regard. Finally, the challenges and perspectives related to hybrid TiO<sub>2</sub>/P3HT heterojunction solar cells are also explored.
first_indexed 2024-03-09T20:27:51Z
format Article
id doaj.art-155330e167c049b1acfb2be9ec42558f
institution Directory Open Access Journal
issn 2079-4991
language English
last_indexed 2024-03-09T20:27:51Z
publishDate 2022-02-01
publisher MDPI AG
record_format Article
series Nanomaterials
spelling doaj.art-155330e167c049b1acfb2be9ec42558f2023-11-23T23:30:41ZengMDPI AGNanomaterials2079-49912022-02-0112582010.3390/nano12050820Roles of Interfacial Modifiers in Inorganic Titania/Organic Poly(3-hexylthiophene) Heterojunction Hybrid Solar CellsArumugam Pirashanthan0Thirunavukarasu Kajana1Dhayalan Velauthapillai2Yohi Shivatharsiny3Said Bentouba4Punniamoorthy Ravirajan5Clean Energy Research Laboratory, Department of Physics, University of Jaffna, Jaffna 40000, Sri LankaClean Energy Research Laboratory, Department of Physics, University of Jaffna, Jaffna 40000, Sri LankaFaculty of Engineering, Western Norway University of Applied Sciences, 5020 Bergen, NorwayDepartment of Chemistry, University of Jaffna, Jaffna 40000, Sri LankaFaculty of Engineering, Western Norway University of Applied Sciences, 5020 Bergen, NorwayClean Energy Research Laboratory, Department of Physics, University of Jaffna, Jaffna 40000, Sri LankaHybrid Titanium dioxide/Poly(3-hexylthiophene) heterojunction solar cells have gained research interest as they have the potential to become cost-effective solar technology in the future. Limited power conversion efficiencies of about 5–6% have been reported so far, and an enhancement in efficiency was achieved through the engineering of the interface between Titanium dioxide (TiO<sub>2</sub>) and Poly(3-hexylthiophene) (P3HT). Evolution of this solar cell technology is relatively slow-moving due to the complex features of the metal oxide-polymer system and the limited understanding of the technology. In this review, we focus on recent developments in interface modified hybrid Titanium dioxide/Poly(3-hexylthiophene) solar cells, provide a short discussion on the working principle, device structure with interface modifiers, and summarize various types of interface modifiers studied to enhance the photovoltaic performance of hybrid TiO<sub>2</sub>/P3HT heterojunction solar cells. Further, we discuss the key factors influencing the power conversion efficiency and the role of a variety of interface modifiers in this regard. Finally, the challenges and perspectives related to hybrid TiO<sub>2</sub>/P3HT heterojunction solar cells are also explored.https://www.mdpi.com/2079-4991/12/5/820hybrid solar cellsinterfacial modifiersTitanium dioxidePoly(3-hexylthiophene)working principleself-assembled monolayers
spellingShingle Arumugam Pirashanthan
Thirunavukarasu Kajana
Dhayalan Velauthapillai
Yohi Shivatharsiny
Said Bentouba
Punniamoorthy Ravirajan
Roles of Interfacial Modifiers in Inorganic Titania/Organic Poly(3-hexylthiophene) Heterojunction Hybrid Solar Cells
Nanomaterials
hybrid solar cells
interfacial modifiers
Titanium dioxide
Poly(3-hexylthiophene)
working principle
self-assembled monolayers
title Roles of Interfacial Modifiers in Inorganic Titania/Organic Poly(3-hexylthiophene) Heterojunction Hybrid Solar Cells
title_full Roles of Interfacial Modifiers in Inorganic Titania/Organic Poly(3-hexylthiophene) Heterojunction Hybrid Solar Cells
title_fullStr Roles of Interfacial Modifiers in Inorganic Titania/Organic Poly(3-hexylthiophene) Heterojunction Hybrid Solar Cells
title_full_unstemmed Roles of Interfacial Modifiers in Inorganic Titania/Organic Poly(3-hexylthiophene) Heterojunction Hybrid Solar Cells
title_short Roles of Interfacial Modifiers in Inorganic Titania/Organic Poly(3-hexylthiophene) Heterojunction Hybrid Solar Cells
title_sort roles of interfacial modifiers in inorganic titania organic poly 3 hexylthiophene heterojunction hybrid solar cells
topic hybrid solar cells
interfacial modifiers
Titanium dioxide
Poly(3-hexylthiophene)
working principle
self-assembled monolayers
url https://www.mdpi.com/2079-4991/12/5/820
work_keys_str_mv AT arumugampirashanthan rolesofinterfacialmodifiersininorganictitaniaorganicpoly3hexylthiopheneheterojunctionhybridsolarcells
AT thirunavukarasukajana rolesofinterfacialmodifiersininorganictitaniaorganicpoly3hexylthiopheneheterojunctionhybridsolarcells
AT dhayalanvelauthapillai rolesofinterfacialmodifiersininorganictitaniaorganicpoly3hexylthiopheneheterojunctionhybridsolarcells
AT yohishivatharsiny rolesofinterfacialmodifiersininorganictitaniaorganicpoly3hexylthiopheneheterojunctionhybridsolarcells
AT saidbentouba rolesofinterfacialmodifiersininorganictitaniaorganicpoly3hexylthiopheneheterojunctionhybridsolarcells
AT punniamoorthyravirajan rolesofinterfacialmodifiersininorganictitaniaorganicpoly3hexylthiopheneheterojunctionhybridsolarcells