Poly[[(μ4-benzene-1,3,5-tricarboxylato-κ4O1:O1′:O2:O3)bis(2,2-bipyridine-κ2N,N′)(μ2-hydroxido)dicopper(II)] trihydrate]
In the title two-dimensional coordination polymer, {[Cu2(C9H3O6)(OH)(C10H8N2)2]·3H2O}n, each of the two independent CuII atoms is coordinated by a bridging OH group, two O atoms from two benzene-1,3,5-tricarboxylate (L) ligands and two N atoms from a 2,2- bipyridine (bipy) ligand in a distorted squa...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-07-01
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| Series: | Acta Crystallographica Section E |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814013877 |
| _version_ | 1819001883573878784 |
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| author | Mohamed N. El-kaheli Ramadan M. El-mehdawi Ramadan G. Abuhmaiera Mufida M. Ben Younes Fathia A. Treish Annalisa Guerri Carla Bazzicalupi |
| author_facet | Mohamed N. El-kaheli Ramadan M. El-mehdawi Ramadan G. Abuhmaiera Mufida M. Ben Younes Fathia A. Treish Annalisa Guerri Carla Bazzicalupi |
| author_sort | Mohamed N. El-kaheli |
| collection | DOAJ |
| description | In the title two-dimensional coordination polymer, {[Cu2(C9H3O6)(OH)(C10H8N2)2]·3H2O}n, each of the two independent CuII atoms is coordinated by a bridging OH group, two O atoms from two benzene-1,3,5-tricarboxylate (L) ligands and two N atoms from a 2,2- bipyridine (bipy) ligand in a distorted square-pyramidal geometry. Each L ligand coordinates four CuII atoms, thus forming a polymeric layer parallel to the bc plane with bipy molecules protruding up and down. The lattice water molecules involved in O—H...· O hydrogen bonding are situated in the inner part of each layer. The crystal packing is consolidated by π–π interactions between the aromatic rings of bipy ligands from neigbouring layers [intercentroid distance = 3.762 (3) Å]. |
| first_indexed | 2024-12-20T22:56:17Z |
| format | Article |
| id | doaj.art-15730dc71e0e468084b8e7213eeda120 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T22:56:17Z |
| publishDate | 2014-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-15730dc71e0e468084b8e7213eeda1202022-12-21T19:24:06ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-07-01707m270m27110.1107/S1600536814013877cv5448Poly[[(μ4-benzene-1,3,5-tricarboxylato-κ4O1:O1′:O2:O3)bis(2,2-bipyridine-κ2N,N′)(μ2-hydroxido)dicopper(II)] trihydrate]Mohamed N. El-kaheli0Ramadan M. El-mehdawi1Ramadan G. Abuhmaiera2Mufida M. Ben Younes3Fathia A. Treish4Annalisa Guerri5Carla Bazzicalupi6Chemistry Department, Tripoli University, Tripoli, LibyaChemistry Department, Tripoli University, Tripoli, LibyaChemistry Department, Tripoli University, Tripoli, LibyaChemistry Department, Tripoli University, Tripoli, LibyaChemistry Department, Tripoli University, Tripoli, LibyaChemistry Department "U. Schiff", University of Florence, Florence, ItalyChemistry Department "U. Schiff", University of Florence, Florence, ItalyIn the title two-dimensional coordination polymer, {[Cu2(C9H3O6)(OH)(C10H8N2)2]·3H2O}n, each of the two independent CuII atoms is coordinated by a bridging OH group, two O atoms from two benzene-1,3,5-tricarboxylate (L) ligands and two N atoms from a 2,2- bipyridine (bipy) ligand in a distorted square-pyramidal geometry. Each L ligand coordinates four CuII atoms, thus forming a polymeric layer parallel to the bc plane with bipy molecules protruding up and down. The lattice water molecules involved in O—H...· O hydrogen bonding are situated in the inner part of each layer. The crystal packing is consolidated by π–π interactions between the aromatic rings of bipy ligands from neigbouring layers [intercentroid distance = 3.762 (3) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536814013877Copper nitratebenzene-1,3,5-tricarboxylic acidBipyridineTopologyTwo-dimension.crystal structure |
| spellingShingle | Mohamed N. El-kaheli Ramadan M. El-mehdawi Ramadan G. Abuhmaiera Mufida M. Ben Younes Fathia A. Treish Annalisa Guerri Carla Bazzicalupi Poly[[(μ4-benzene-1,3,5-tricarboxylato-κ4O1:O1′:O2:O3)bis(2,2-bipyridine-κ2N,N′)(μ2-hydroxido)dicopper(II)] trihydrate] Acta Crystallographica Section E Copper nitrate benzene-1,3,5-tricarboxylic acid Bipyridine Topology Two-dimension. crystal structure |
| title | Poly[[(μ4-benzene-1,3,5-tricarboxylato-κ4O1:O1′:O2:O3)bis(2,2-bipyridine-κ2N,N′)(μ2-hydroxido)dicopper(II)] trihydrate] |
| title_full | Poly[[(μ4-benzene-1,3,5-tricarboxylato-κ4O1:O1′:O2:O3)bis(2,2-bipyridine-κ2N,N′)(μ2-hydroxido)dicopper(II)] trihydrate] |
| title_fullStr | Poly[[(μ4-benzene-1,3,5-tricarboxylato-κ4O1:O1′:O2:O3)bis(2,2-bipyridine-κ2N,N′)(μ2-hydroxido)dicopper(II)] trihydrate] |
| title_full_unstemmed | Poly[[(μ4-benzene-1,3,5-tricarboxylato-κ4O1:O1′:O2:O3)bis(2,2-bipyridine-κ2N,N′)(μ2-hydroxido)dicopper(II)] trihydrate] |
| title_short | Poly[[(μ4-benzene-1,3,5-tricarboxylato-κ4O1:O1′:O2:O3)bis(2,2-bipyridine-κ2N,N′)(μ2-hydroxido)dicopper(II)] trihydrate] |
| title_sort | poly μ4 benzene 1 3 5 tricarboxylato κ4o1 o1 o2 o3 bis 2 2 bipyridine κ2n n μ2 hydroxido dicopper ii trihydrate |
| topic | Copper nitrate benzene-1,3,5-tricarboxylic acid Bipyridine Topology Two-dimension. crystal structure |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814013877 |
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