STUDY OF THE MICROSTRUCTURE AND COMPOSITION OF TIN DIOXIDE LAYERS MODIFIED BY SILVER NANOPARTICLES
Tin dioxide layers were synthesized by hydrothermal method from an aqueous solution of SnF2. Silver nanoparticles were deposited on the surface of the obtained layers by the photoreduction method. The surface morphology of the samples was studied by atomic force microscopy. The size of the silver na...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | Russian |
| Published: |
Tver State University
2021-12-01
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| Series: | Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов |
| Subjects: | |
| Online Access: | https://physchemaspects.ru/2021/doi-10-26456-pcascnn-2021-13-447/?lang=en |
| Summary: | Tin dioxide layers were synthesized by hydrothermal method from an aqueous solution of SnF2. Silver nanoparticles were deposited on the surface of the obtained layers by the photoreduction method. The surface morphology of the samples was studied by atomic force microscopy. The size of the silver nanoparticles depends on the concentration of the AgNO3 solution used for the photoreduction reaction. When synthesized from 0,02 M solution with a concentration of, the size of the nanoparticles varies from 10 to 100 nm, when the concentration of the solution is doubled, the size of the nanoparticles is about 100 nm. The surface composition of the layers before and after the deposition of silver nanoparticles was studied using the X-ray photoelectron spectroscopy. It was shown that a layer of the tin dioxide is formed without external inclusions, and metallic silver is deposited. The chemical shift of the peaks of tin and oxygen after the deposition of silver nanoparticles indicates the exchange of electrons between tin and silver. The synthesized layers are of interest for application in the field of semiconductor adsorption gas sensors. |
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| ISSN: | 2226-4442 2658-4360 |