Progress and innovation of nanostructured sulfur cathodes and metal-free anodes for room-temperature Na–S batteries

Rechargeable batteries are a major element in the transition to renewable energie systems, but the current lithium-ion battery technology may face limitations in the future concerning the availability of raw materials and socio-economic insecurities. Sodium–sulfur (Na–S) batteries are a promising al...

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Main Authors: Marina Tabuyo-Martínez, Bernd Wicklein, Pilar Aranda
Format: Article
Language:English
Published: Beilstein-Institut 2021-09-01
Series:Beilstein Journal of Nanotechnology
Subjects:
Online Access:https://doi.org/10.3762/bjnano.12.75
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author Marina Tabuyo-Martínez
Bernd Wicklein
Pilar Aranda
author_facet Marina Tabuyo-Martínez
Bernd Wicklein
Pilar Aranda
author_sort Marina Tabuyo-Martínez
collection DOAJ
description Rechargeable batteries are a major element in the transition to renewable energie systems, but the current lithium-ion battery technology may face limitations in the future concerning the availability of raw materials and socio-economic insecurities. Sodium–sulfur (Na–S) batteries are a promising alternative energy storage device for small- to large-scale applications driven by more favorable environmental and economic perspectives. However, scientific and technological problems are still hindering a commercial breakthrough of these batteries. This review discusses strategies to remedy some of the current drawbacks such as the polysulfide shuttle effect, catastrophic volume expansion, Na dendrite growth, and slow reaction kinetics by nanostructuring both the sulfur cathode and the Na anode. Moreover, a survey of recent patents on room temperature (RT) Na–S batteries revealed that nanostructured sulfur and sodium electrodes are still in the minority, which suggests that much investigation and innovation is needed until RT Na–S batteries can be commercialized.
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spelling doaj.art-15869ee7a66e4388a22f210b7b9db6422022-12-21T18:39:49ZengBeilstein-InstitutBeilstein Journal of Nanotechnology2190-42862021-09-01121995102010.3762/bjnano.12.752190-4286-12-75Progress and innovation of nanostructured sulfur cathodes and metal-free anodes for room-temperature Na–S batteriesMarina Tabuyo-Martínez0Bernd Wicklein1Pilar Aranda2Instituto de Ciencia de Materiales de Madrid (ICMM), Consejo Superior de Investigaciones Científicas (CSIC), 28049 Madrid, SpainInstituto de Ciencia de Materiales de Madrid (ICMM), Consejo Superior de Investigaciones Científicas (CSIC), 28049 Madrid, SpainInstituto de Ciencia de Materiales de Madrid (ICMM), Consejo Superior de Investigaciones Científicas (CSIC), 28049 Madrid, SpainRechargeable batteries are a major element in the transition to renewable energie systems, but the current lithium-ion battery technology may face limitations in the future concerning the availability of raw materials and socio-economic insecurities. Sodium–sulfur (Na–S) batteries are a promising alternative energy storage device for small- to large-scale applications driven by more favorable environmental and economic perspectives. However, scientific and technological problems are still hindering a commercial breakthrough of these batteries. This review discusses strategies to remedy some of the current drawbacks such as the polysulfide shuttle effect, catastrophic volume expansion, Na dendrite growth, and slow reaction kinetics by nanostructuring both the sulfur cathode and the Na anode. Moreover, a survey of recent patents on room temperature (RT) Na–S batteries revealed that nanostructured sulfur and sodium electrodes are still in the minority, which suggests that much investigation and innovation is needed until RT Na–S batteries can be commercialized.https://doi.org/10.3762/bjnano.12.75compositesmetal-free anodena–ssodium nanostructuressodium–sulfur batteriessulfur nanostructures
spellingShingle Marina Tabuyo-Martínez
Bernd Wicklein
Pilar Aranda
Progress and innovation of nanostructured sulfur cathodes and metal-free anodes for room-temperature Na–S batteries
Beilstein Journal of Nanotechnology
composites
metal-free anode
na–s
sodium nanostructures
sodium–sulfur batteries
sulfur nanostructures
title Progress and innovation of nanostructured sulfur cathodes and metal-free anodes for room-temperature Na–S batteries
title_full Progress and innovation of nanostructured sulfur cathodes and metal-free anodes for room-temperature Na–S batteries
title_fullStr Progress and innovation of nanostructured sulfur cathodes and metal-free anodes for room-temperature Na–S batteries
title_full_unstemmed Progress and innovation of nanostructured sulfur cathodes and metal-free anodes for room-temperature Na–S batteries
title_short Progress and innovation of nanostructured sulfur cathodes and metal-free anodes for room-temperature Na–S batteries
title_sort progress and innovation of nanostructured sulfur cathodes and metal free anodes for room temperature na s batteries
topic composites
metal-free anode
na–s
sodium nanostructures
sodium–sulfur batteries
sulfur nanostructures
url https://doi.org/10.3762/bjnano.12.75
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