Theoretical Calculation of Reorientation Energy in Metal /Semiconductor Interface

A theoretical calculation of the reorientation energy for non adiabatic electron transfer at interface between metal and semiconductor system was carried out. The continuum outer sphere theory of electron transfer reaction has been extensively used for electron transfer between metal/semiconduct...

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Main Authors: H. J. M. A-Agealy, H. Kh. Mujbi
Format: Article
Language:English
Published: University of Baghdad 2017-05-01
Series:Ibn Al-Haitham Journal for Pure and Applied Sciences
Subjects:
Online Access:https://jih.uobaghdad.edu.iq/index.php/j/article/view/573
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author H. J. M. A-Agealy
H. Kh. Mujbi
author_facet H. J. M. A-Agealy
H. Kh. Mujbi
author_sort H. J. M. A-Agealy
collection DOAJ
description A theoretical calculation of the reorientation energy for non adiabatic electron transfer at interface between metal and semiconductor system was carried out. The continuum outer sphere theory of electron transfer reaction has been extensively used for electron transfer between metal/semiconductor interface .It is found that in these calculations the reorientation energy is proportional to the optical and statistical dielectric constant of semiconductor , properties of metal ,and the distance between metal and semiconductor .Results of reorientation energy show that ZnO semiconductor with metal Au possess a good matching as compared with ZnS and ZnSe . Theoretical calculation showed a good agreement with experimental value.
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spelling doaj.art-158d438047934549869d5076ea491d7f2022-12-22T02:54:08ZengUniversity of BaghdadIbn Al-Haitham Journal for Pure and Applied Sciences1609-40422521-34072017-05-01253Theoretical Calculation of Reorientation Energy in Metal /Semiconductor InterfaceH. J. M. A-AgealyH. Kh. Mujbi A theoretical calculation of the reorientation energy for non adiabatic electron transfer at interface between metal and semiconductor system was carried out. The continuum outer sphere theory of electron transfer reaction has been extensively used for electron transfer between metal/semiconductor interface .It is found that in these calculations the reorientation energy is proportional to the optical and statistical dielectric constant of semiconductor , properties of metal ,and the distance between metal and semiconductor .Results of reorientation energy show that ZnO semiconductor with metal Au possess a good matching as compared with ZnS and ZnSe . Theoretical calculation showed a good agreement with experimental value. https://jih.uobaghdad.edu.iq/index.php/j/article/view/573theoretical calculation , reorientation energy, metal semiconductor, metal/semiconductor, Gold(Au),ZnO,ZnS,and ZnSe semiconductors
spellingShingle H. J. M. A-Agealy
H. Kh. Mujbi
Theoretical Calculation of Reorientation Energy in Metal /Semiconductor Interface
Ibn Al-Haitham Journal for Pure and Applied Sciences
theoretical calculation , reorientation energy, metal semiconductor, metal/semiconductor, Gold(Au),ZnO,ZnS,and ZnSe semiconductors
title Theoretical Calculation of Reorientation Energy in Metal /Semiconductor Interface
title_full Theoretical Calculation of Reorientation Energy in Metal /Semiconductor Interface
title_fullStr Theoretical Calculation of Reorientation Energy in Metal /Semiconductor Interface
title_full_unstemmed Theoretical Calculation of Reorientation Energy in Metal /Semiconductor Interface
title_short Theoretical Calculation of Reorientation Energy in Metal /Semiconductor Interface
title_sort theoretical calculation of reorientation energy in metal semiconductor interface
topic theoretical calculation , reorientation energy, metal semiconductor, metal/semiconductor, Gold(Au),ZnO,ZnS,and ZnSe semiconductors
url https://jih.uobaghdad.edu.iq/index.php/j/article/view/573
work_keys_str_mv AT hjmaagealy theoreticalcalculationofreorientationenergyinmetalsemiconductorinterface
AT hkhmujbi theoreticalcalculationofreorientationenergyinmetalsemiconductorinterface