Luminescent Coatings Based on (3-Aminopropyl)triethoxysilane and Europium Complex β-Diketophosphazene
The reaction of β-diketophosphazene with the europium (III) salt synthesized the corresponding metal complex which was structured with (3-aminopropyl)triethoxysilane and treated with dibenzoylmethane for additional coordination of europium atoms. The polymer thus obtained exhibits luminescence with...
Main Authors: | , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2022-02-01
|
Series: | Polymers |
Subjects: | |
Online Access: | https://www.mdpi.com/2073-4360/14/4/728 |
_version_ | 1797477000414232576 |
---|---|
author | Violetta V. Maslennikova Sergey N. Filatov Alexey V. Orlov Nikolay M. Surin Evgeniya A. Svidchenko Evgeniy M. Chistyakov |
author_facet | Violetta V. Maslennikova Sergey N. Filatov Alexey V. Orlov Nikolay M. Surin Evgeniya A. Svidchenko Evgeniy M. Chistyakov |
author_sort | Violetta V. Maslennikova |
collection | DOAJ |
description | The reaction of β-diketophosphazene with the europium (III) salt synthesized the corresponding metal complex which was structured with (3-aminopropyl)triethoxysilane and treated with dibenzoylmethane for additional coordination of europium atoms. The polymer thus obtained exhibits luminescence with a maximum of 615 nm, which is characteristic of europium. The polymer is thermally stable up to 300 °C, the coating based on it has a contact angle of 101°, and the adhesive strength of the coating to non-finished glass (according to ISO 2409: 2013) is 1 point. |
first_indexed | 2024-03-09T21:11:43Z |
format | Article |
id | doaj.art-15933a3c04e14505b82f6c5ffb164fc6 |
institution | Directory Open Access Journal |
issn | 2073-4360 |
language | English |
last_indexed | 2024-03-09T21:11:43Z |
publishDate | 2022-02-01 |
publisher | MDPI AG |
record_format | Article |
series | Polymers |
spelling | doaj.art-15933a3c04e14505b82f6c5ffb164fc62023-11-23T21:44:57ZengMDPI AGPolymers2073-43602022-02-0114472810.3390/polym14040728Luminescent Coatings Based on (3-Aminopropyl)triethoxysilane and Europium Complex β-DiketophosphazeneVioletta V. Maslennikova0Sergey N. Filatov1Alexey V. Orlov2Nikolay M. Surin3Evgeniya A. Svidchenko4Evgeniy M. Chistyakov5D. Mendeleev University of Chemical Technology of Russia, 125047 Moscow, RussiaD. Mendeleev University of Chemical Technology of Russia, 125047 Moscow, RussiaD. Mendeleev University of Chemical Technology of Russia, 125047 Moscow, RussiaEnikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, 117393 Moscow, RussiaEnikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, 117393 Moscow, RussiaD. Mendeleev University of Chemical Technology of Russia, 125047 Moscow, RussiaThe reaction of β-diketophosphazene with the europium (III) salt synthesized the corresponding metal complex which was structured with (3-aminopropyl)triethoxysilane and treated with dibenzoylmethane for additional coordination of europium atoms. The polymer thus obtained exhibits luminescence with a maximum of 615 nm, which is characteristic of europium. The polymer is thermally stable up to 300 °C, the coating based on it has a contact angle of 101°, and the adhesive strength of the coating to non-finished glass (according to ISO 2409: 2013) is 1 point.https://www.mdpi.com/2073-4360/14/4/728phosphazenesiloxaneluminescencethermal resistancehydrophobicityadhesion |
spellingShingle | Violetta V. Maslennikova Sergey N. Filatov Alexey V. Orlov Nikolay M. Surin Evgeniya A. Svidchenko Evgeniy M. Chistyakov Luminescent Coatings Based on (3-Aminopropyl)triethoxysilane and Europium Complex β-Diketophosphazene Polymers phosphazene siloxane luminescence thermal resistance hydrophobicity adhesion |
title | Luminescent Coatings Based on (3-Aminopropyl)triethoxysilane and Europium Complex β-Diketophosphazene |
title_full | Luminescent Coatings Based on (3-Aminopropyl)triethoxysilane and Europium Complex β-Diketophosphazene |
title_fullStr | Luminescent Coatings Based on (3-Aminopropyl)triethoxysilane and Europium Complex β-Diketophosphazene |
title_full_unstemmed | Luminescent Coatings Based on (3-Aminopropyl)triethoxysilane and Europium Complex β-Diketophosphazene |
title_short | Luminescent Coatings Based on (3-Aminopropyl)triethoxysilane and Europium Complex β-Diketophosphazene |
title_sort | luminescent coatings based on 3 aminopropyl triethoxysilane and europium complex β diketophosphazene |
topic | phosphazene siloxane luminescence thermal resistance hydrophobicity adhesion |
url | https://www.mdpi.com/2073-4360/14/4/728 |
work_keys_str_mv | AT violettavmaslennikova luminescentcoatingsbasedon3aminopropyltriethoxysilaneandeuropiumcomplexbdiketophosphazene AT sergeynfilatov luminescentcoatingsbasedon3aminopropyltriethoxysilaneandeuropiumcomplexbdiketophosphazene AT alexeyvorlov luminescentcoatingsbasedon3aminopropyltriethoxysilaneandeuropiumcomplexbdiketophosphazene AT nikolaymsurin luminescentcoatingsbasedon3aminopropyltriethoxysilaneandeuropiumcomplexbdiketophosphazene AT evgeniyaasvidchenko luminescentcoatingsbasedon3aminopropyltriethoxysilaneandeuropiumcomplexbdiketophosphazene AT evgeniymchistyakov luminescentcoatingsbasedon3aminopropyltriethoxysilaneandeuropiumcomplexbdiketophosphazene |