Luminescent Coatings Based on (3-Aminopropyl)triethoxysilane and Europium Complex β-Diketophosphazene

The reaction of β-diketophosphazene with the europium (III) salt synthesized the corresponding metal complex which was structured with (3-aminopropyl)triethoxysilane and treated with dibenzoylmethane for additional coordination of europium atoms. The polymer thus obtained exhibits luminescence with...

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Main Authors: Violetta V. Maslennikova, Sergey N. Filatov, Alexey V. Orlov, Nikolay M. Surin, Evgeniya A. Svidchenko, Evgeniy M. Chistyakov
Format: Article
Language:English
Published: MDPI AG 2022-02-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/14/4/728
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author Violetta V. Maslennikova
Sergey N. Filatov
Alexey V. Orlov
Nikolay M. Surin
Evgeniya A. Svidchenko
Evgeniy M. Chistyakov
author_facet Violetta V. Maslennikova
Sergey N. Filatov
Alexey V. Orlov
Nikolay M. Surin
Evgeniya A. Svidchenko
Evgeniy M. Chistyakov
author_sort Violetta V. Maslennikova
collection DOAJ
description The reaction of β-diketophosphazene with the europium (III) salt synthesized the corresponding metal complex which was structured with (3-aminopropyl)triethoxysilane and treated with dibenzoylmethane for additional coordination of europium atoms. The polymer thus obtained exhibits luminescence with a maximum of 615 nm, which is characteristic of europium. The polymer is thermally stable up to 300 °C, the coating based on it has a contact angle of 101°, and the adhesive strength of the coating to non-finished glass (according to ISO 2409: 2013) is 1 point.
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spelling doaj.art-15933a3c04e14505b82f6c5ffb164fc62023-11-23T21:44:57ZengMDPI AGPolymers2073-43602022-02-0114472810.3390/polym14040728Luminescent Coatings Based on (3-Aminopropyl)triethoxysilane and Europium Complex β-DiketophosphazeneVioletta V. Maslennikova0Sergey N. Filatov1Alexey V. Orlov2Nikolay M. Surin3Evgeniya A. Svidchenko4Evgeniy M. Chistyakov5D. Mendeleev University of Chemical Technology of Russia, 125047 Moscow, RussiaD. Mendeleev University of Chemical Technology of Russia, 125047 Moscow, RussiaD. Mendeleev University of Chemical Technology of Russia, 125047 Moscow, RussiaEnikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, 117393 Moscow, RussiaEnikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, 117393 Moscow, RussiaD. Mendeleev University of Chemical Technology of Russia, 125047 Moscow, RussiaThe reaction of β-diketophosphazene with the europium (III) salt synthesized the corresponding metal complex which was structured with (3-aminopropyl)triethoxysilane and treated with dibenzoylmethane for additional coordination of europium atoms. The polymer thus obtained exhibits luminescence with a maximum of 615 nm, which is characteristic of europium. The polymer is thermally stable up to 300 °C, the coating based on it has a contact angle of 101°, and the adhesive strength of the coating to non-finished glass (according to ISO 2409: 2013) is 1 point.https://www.mdpi.com/2073-4360/14/4/728phosphazenesiloxaneluminescencethermal resistancehydrophobicityadhesion
spellingShingle Violetta V. Maslennikova
Sergey N. Filatov
Alexey V. Orlov
Nikolay M. Surin
Evgeniya A. Svidchenko
Evgeniy M. Chistyakov
Luminescent Coatings Based on (3-Aminopropyl)triethoxysilane and Europium Complex β-Diketophosphazene
Polymers
phosphazene
siloxane
luminescence
thermal resistance
hydrophobicity
adhesion
title Luminescent Coatings Based on (3-Aminopropyl)triethoxysilane and Europium Complex β-Diketophosphazene
title_full Luminescent Coatings Based on (3-Aminopropyl)triethoxysilane and Europium Complex β-Diketophosphazene
title_fullStr Luminescent Coatings Based on (3-Aminopropyl)triethoxysilane and Europium Complex β-Diketophosphazene
title_full_unstemmed Luminescent Coatings Based on (3-Aminopropyl)triethoxysilane and Europium Complex β-Diketophosphazene
title_short Luminescent Coatings Based on (3-Aminopropyl)triethoxysilane and Europium Complex β-Diketophosphazene
title_sort luminescent coatings based on 3 aminopropyl triethoxysilane and europium complex β diketophosphazene
topic phosphazene
siloxane
luminescence
thermal resistance
hydrophobicity
adhesion
url https://www.mdpi.com/2073-4360/14/4/728
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AT alexeyvorlov luminescentcoatingsbasedon3aminopropyltriethoxysilaneandeuropiumcomplexbdiketophosphazene
AT nikolaymsurin luminescentcoatingsbasedon3aminopropyltriethoxysilaneandeuropiumcomplexbdiketophosphazene
AT evgeniyaasvidchenko luminescentcoatingsbasedon3aminopropyltriethoxysilaneandeuropiumcomplexbdiketophosphazene
AT evgeniymchistyakov luminescentcoatingsbasedon3aminopropyltriethoxysilaneandeuropiumcomplexbdiketophosphazene