Cephalexin Adsorption by Acidic Pretreated Jackfruit Adsorbent: A Deep Learning Prediction Model Study

Cephalexin (CFX) residues in the environment represent a major threat to human health worldwide. Herein we investigate the use of novel approaches in deep learning in order to understand the mechanisms and optimal conditions for the sorption of cephalexin in water onto an acidic pretreated jackfruit...

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Main Authors: Adel Ali Al-Gheethi, Mohammad Shafiq Mohd Salleh, Efaq Ali Noman, Radin Maya Saphira Radin Mohamed, Rich Crane, Rafidah Hamdan, Mu. Naushad
Format: Article
Language:English
Published: MDPI AG 2022-07-01
Series:Water
Subjects:
Online Access:https://www.mdpi.com/2073-4441/14/14/2243
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author Adel Ali Al-Gheethi
Mohammad Shafiq Mohd Salleh
Efaq Ali Noman
Radin Maya Saphira Radin Mohamed
Rich Crane
Rafidah Hamdan
Mu. Naushad
author_facet Adel Ali Al-Gheethi
Mohammad Shafiq Mohd Salleh
Efaq Ali Noman
Radin Maya Saphira Radin Mohamed
Rich Crane
Rafidah Hamdan
Mu. Naushad
author_sort Adel Ali Al-Gheethi
collection DOAJ
description Cephalexin (CFX) residues in the environment represent a major threat to human health worldwide. Herein we investigate the use of novel approaches in deep learning in order to understand the mechanisms and optimal conditions for the sorption of cephalexin in water onto an acidic pretreated jackfruit peel adsorbent (APJPA). The interaction between the initial concentration of CFX (10–50 mg/100 mL), APJAP dosage (3–10 mg/100 mL), time (10–60 min), and the pH (4–9), was simulated using the one-factor-at-a-time method. APJPA was characterized by FESEM images showing that APJPA exhibits a smooth surface devoid of pores. FTIR spectra confirmed the presence of -C-O, C–H, C=C, and -COOH bonds within the APJPA. Maximum removal was recorded with 6.5 mg/100 mL of APJAP dosage, pH 6.5, after 35 min and with 25 mg/100 mL of CFX, at which the predicted and actual adsorption were 96.08 and 98.25%, respectively. The simulation results show that the dosage of APJAP exhibits a high degree of influence on the maximum adsorption of CFX removal (100%) between 2 and 8 mg dose/100 mL. The highest adsorption capacity of APJAP was 384.62 mg CFX/g. The simulation for the effect of pH determined that the best pH for the CFX adsorption lies between pH 5 and 8.
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spelling doaj.art-159e1bbb690c40f08bb65b817954e3cb2023-12-03T12:25:26ZengMDPI AGWater2073-44412022-07-011414224310.3390/w14142243Cephalexin Adsorption by Acidic Pretreated Jackfruit Adsorbent: A Deep Learning Prediction Model StudyAdel Ali Al-Gheethi0Mohammad Shafiq Mohd Salleh1Efaq Ali Noman2Radin Maya Saphira Radin Mohamed3Rich Crane4Rafidah Hamdan5Mu. Naushad6Department of Civil Engineering, Faculty of Civil Engineering and Built Environment, Universiti Tun Hussein Onn Malaysia, Parit Raja, Batu Pahat 86400, MalaysiaDepartment of Civil Engineering, Faculty of Civil Engineering and Built Environment, Universiti Tun Hussein Onn Malaysia, Parit Raja, Batu Pahat 86400, MalaysiaDepartment of Civil Engineering, Faculty of Civil Engineering and Built Environment, Universiti Tun Hussein Onn Malaysia, Parit Raja, Batu Pahat 86400, MalaysiaDepartment of Civil Engineering, Faculty of Civil Engineering and Built Environment, Universiti Tun Hussein Onn Malaysia, Parit Raja, Batu Pahat 86400, MalaysiaCamborne School of Mines, College of Engineering, Mathematics and Physical Sciences, University of Exeter, Exeter EX4 4QD, UKDepartment of Civil Engineering, Faculty of Civil Engineering and Built Environment, Universiti Tun Hussein Onn Malaysia, Parit Raja, Batu Pahat 86400, MalaysiaDepartment of Chemistry, College of Science, King Saud University (KSU), Riyadh P.O. Box 2455, Saudi ArabiaCephalexin (CFX) residues in the environment represent a major threat to human health worldwide. Herein we investigate the use of novel approaches in deep learning in order to understand the mechanisms and optimal conditions for the sorption of cephalexin in water onto an acidic pretreated jackfruit peel adsorbent (APJPA). The interaction between the initial concentration of CFX (10–50 mg/100 mL), APJAP dosage (3–10 mg/100 mL), time (10–60 min), and the pH (4–9), was simulated using the one-factor-at-a-time method. APJPA was characterized by FESEM images showing that APJPA exhibits a smooth surface devoid of pores. FTIR spectra confirmed the presence of -C-O, C–H, C=C, and -COOH bonds within the APJPA. Maximum removal was recorded with 6.5 mg/100 mL of APJAP dosage, pH 6.5, after 35 min and with 25 mg/100 mL of CFX, at which the predicted and actual adsorption were 96.08 and 98.25%, respectively. The simulation results show that the dosage of APJAP exhibits a high degree of influence on the maximum adsorption of CFX removal (100%) between 2 and 8 mg dose/100 mL. The highest adsorption capacity of APJAP was 384.62 mg CFX/g. The simulation for the effect of pH determined that the best pH for the CFX adsorption lies between pH 5 and 8.https://www.mdpi.com/2073-4441/14/14/2243adsorptioncephalexindeep learningoptimizationsimulation models
spellingShingle Adel Ali Al-Gheethi
Mohammad Shafiq Mohd Salleh
Efaq Ali Noman
Radin Maya Saphira Radin Mohamed
Rich Crane
Rafidah Hamdan
Mu. Naushad
Cephalexin Adsorption by Acidic Pretreated Jackfruit Adsorbent: A Deep Learning Prediction Model Study
Water
adsorption
cephalexin
deep learning
optimization
simulation models
title Cephalexin Adsorption by Acidic Pretreated Jackfruit Adsorbent: A Deep Learning Prediction Model Study
title_full Cephalexin Adsorption by Acidic Pretreated Jackfruit Adsorbent: A Deep Learning Prediction Model Study
title_fullStr Cephalexin Adsorption by Acidic Pretreated Jackfruit Adsorbent: A Deep Learning Prediction Model Study
title_full_unstemmed Cephalexin Adsorption by Acidic Pretreated Jackfruit Adsorbent: A Deep Learning Prediction Model Study
title_short Cephalexin Adsorption by Acidic Pretreated Jackfruit Adsorbent: A Deep Learning Prediction Model Study
title_sort cephalexin adsorption by acidic pretreated jackfruit adsorbent a deep learning prediction model study
topic adsorption
cephalexin
deep learning
optimization
simulation models
url https://www.mdpi.com/2073-4441/14/14/2243
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AT efaqalinoman cephalexinadsorptionbyacidicpretreatedjackfruitadsorbentadeeplearningpredictionmodelstudy
AT radinmayasaphiraradinmohamed cephalexinadsorptionbyacidicpretreatedjackfruitadsorbentadeeplearningpredictionmodelstudy
AT richcrane cephalexinadsorptionbyacidicpretreatedjackfruitadsorbentadeeplearningpredictionmodelstudy
AT rafidahhamdan cephalexinadsorptionbyacidicpretreatedjackfruitadsorbentadeeplearningpredictionmodelstudy
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