Free standing organometallic dimethylammonium zinc formate perovskite for photonic and antimicrobial applications

In this study, we have focused on the synthesis and analysis of a photoactive perovskite polymer composite film consisting of dimethylammonium zinc formate perovskite (DMAZF) as a crucial member of the metal-organic frameworks family, templated by polycarbonate. The characterization of DMAZF involve...

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Main Authors: Aparna Thankappan, Anshida Mayeen, Jiya Jose, Sabu Thomas
Format: Article
Language:English
Published: Elsevier 2023-09-01
Series:Results in Engineering
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2590123023005030
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author Aparna Thankappan
Anshida Mayeen
Jiya Jose
Sabu Thomas
author_facet Aparna Thankappan
Anshida Mayeen
Jiya Jose
Sabu Thomas
author_sort Aparna Thankappan
collection DOAJ
description In this study, we have focused on the synthesis and analysis of a photoactive perovskite polymer composite film consisting of dimethylammonium zinc formate perovskite (DMAZF) as a crucial member of the metal-organic frameworks family, templated by polycarbonate. The characterization of DMAZF involved a comprehensive analysis using various techniques, including UV-VIS absorption spectra, Raman spectra, Fourier-transform infrared spectra, Z Scan, thermal analysis, frequency-dependent dielectric measurements, and nuclear magnetic resonance. The results of the characterizations revealed that the DMAZF composite film exhibits excellent crystallinity, promising thermodynamic capability for water splitting, desirable dielectric properties, nonlinear effects, and a remarkable surface response to adhering microorganisms, particularly against E. coli and S. aureus. The antibacterial activity was evaluated using the well diffusion method, confirming the material's potential as an antimicrobial agent. Moreover, Z scan studies have unveiled exciting technological applications of DMAZF, further enhancing its appeal as an emerging class of nanomaterial in nanotechnology.
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spelling doaj.art-15a69357fbe74f68a80accf736cd16e02023-09-18T04:30:54ZengElsevierResults in Engineering2590-12302023-09-0119101376Free standing organometallic dimethylammonium zinc formate perovskite for photonic and antimicrobial applicationsAparna Thankappan0Anshida Mayeen1Jiya Jose2Sabu Thomas3International and Inter University Centre for Nanoscience and Nanotechnology, Mahatma Gandhi University, Kottayam, Kerala, 686560, India; Baselius College, Kottayam, Kerala, 686 001, India; Corresponding author. Baselius College, Kottayam, Kerala, 686 001, IndiaSchool of Pure and Applied Physics, Mahatma Gandhi University, Kottayam, Kerala, 686560, India; Inter University Centre for Nanomaterials and Devices, Cochin University of Science and Technology, Kerala, 682022, IndiaInternational and Inter University Centre for Nanoscience and Nanotechnology, Mahatma Gandhi University, Kottayam, Kerala, 686560, India; Division of Microbiology, Department of Biosciences, Rajagiri College of Social Science (Autonomous), Kochi, 683104, IndiaInternational and Inter University Centre for Nanoscience and Nanotechnology, Mahatma Gandhi University, Kottayam, Kerala, 686560, India; School of Chemical Science, Mahatma Gandhi University, Kottayam, Kerala, 686560, IndiaIn this study, we have focused on the synthesis and analysis of a photoactive perovskite polymer composite film consisting of dimethylammonium zinc formate perovskite (DMAZF) as a crucial member of the metal-organic frameworks family, templated by polycarbonate. The characterization of DMAZF involved a comprehensive analysis using various techniques, including UV-VIS absorption spectra, Raman spectra, Fourier-transform infrared spectra, Z Scan, thermal analysis, frequency-dependent dielectric measurements, and nuclear magnetic resonance. The results of the characterizations revealed that the DMAZF composite film exhibits excellent crystallinity, promising thermodynamic capability for water splitting, desirable dielectric properties, nonlinear effects, and a remarkable surface response to adhering microorganisms, particularly against E. coli and S. aureus. The antibacterial activity was evaluated using the well diffusion method, confirming the material's potential as an antimicrobial agent. Moreover, Z scan studies have unveiled exciting technological applications of DMAZF, further enhancing its appeal as an emerging class of nanomaterial in nanotechnology.http://www.sciencedirect.com/science/article/pii/S2590123023005030Photonics materialAntimicrobial activityThin filmsMetal-organic framework
spellingShingle Aparna Thankappan
Anshida Mayeen
Jiya Jose
Sabu Thomas
Free standing organometallic dimethylammonium zinc formate perovskite for photonic and antimicrobial applications
Results in Engineering
Photonics material
Antimicrobial activity
Thin films
Metal-organic framework
title Free standing organometallic dimethylammonium zinc formate perovskite for photonic and antimicrobial applications
title_full Free standing organometallic dimethylammonium zinc formate perovskite for photonic and antimicrobial applications
title_fullStr Free standing organometallic dimethylammonium zinc formate perovskite for photonic and antimicrobial applications
title_full_unstemmed Free standing organometallic dimethylammonium zinc formate perovskite for photonic and antimicrobial applications
title_short Free standing organometallic dimethylammonium zinc formate perovskite for photonic and antimicrobial applications
title_sort free standing organometallic dimethylammonium zinc formate perovskite for photonic and antimicrobial applications
topic Photonics material
Antimicrobial activity
Thin films
Metal-organic framework
url http://www.sciencedirect.com/science/article/pii/S2590123023005030
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AT anshidamayeen freestandingorganometallicdimethylammoniumzincformateperovskiteforphotonicandantimicrobialapplications
AT jiyajose freestandingorganometallicdimethylammoniumzincformateperovskiteforphotonicandantimicrobialapplications
AT sabuthomas freestandingorganometallicdimethylammoniumzincformateperovskiteforphotonicandantimicrobialapplications