Synthesis of ZnO with Enhanced Photocatalytic Activity: A Novel Approach Using Nanocellulose

Well-crystallized and hexagonal wurtzite ZnO was synthesized with nanocellulose using a facile hydrothermal method. Many highly active (001) facets were retained in the obtained ZnO nanocrystals, presumably due to interaction between the polar facet of ZnO and the nanocellulose. Given its effective...

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Main Authors: Guangyu Wei, Hong-Fen Zuo, Yuan-Ru Guo, Qing-Jiang Pan
Format: Article
Language:English
Published: North Carolina State University 2016-06-01
Series:BioResources
Subjects:
Online Access:http://ojs.cnr.ncsu.edu/index.php/BioRes/article/view/BioRes_11_3_6244_Wei_Synthesis_Photocatalytic_Activity_Nanocellulose
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author Guangyu Wei
Hong-Fen Zuo
Yuan-Ru Guo
Qing-Jiang Pan
author_facet Guangyu Wei
Hong-Fen Zuo
Yuan-Ru Guo
Qing-Jiang Pan
author_sort Guangyu Wei
collection DOAJ
description Well-crystallized and hexagonal wurtzite ZnO was synthesized with nanocellulose using a facile hydrothermal method. Many highly active (001) facets were retained in the obtained ZnO nanocrystals, presumably due to interaction between the polar facet of ZnO and the nanocellulose. Given its effective surface area, the synthesized ZnO exhibited good photocatalytic activity of degrading methylene blue. Its degradation efficiency reached 94.4% within 30 min (UV irradiation power of 6 W), which was 34% higher than that of Degussa TiO2 P25. The ZnO photocatalyst also exhibited excellent reusability, confirmed by no obvious abatement after its being re-used for 8 cycles. These ZnO nanomaterials were synthesized using renewable nanocellulose derived from cotton. This environmentally friendly and cost-effective approach is anticipated to be applied in the future synthesis of small-sized ZnO photocatalysts.
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spelling doaj.art-15a72ea440b14cf88ab765a2d940c4e52022-12-22T03:09:19ZengNorth Carolina State UniversityBioResources1930-21261930-21262016-06-011136244625310.15376/biores.11.3.6244-6253Synthesis of ZnO with Enhanced Photocatalytic Activity: A Novel Approach Using NanocelluloseGuangyu Wei0Hong-Fen Zuo1Yuan-Ru Guo2Qing-Jiang Pan3Heilongjiang University; ChinaNortheast Forestry University; ChinaNortheast Forestry University; ChinaHeilongjiang University; ChinaWell-crystallized and hexagonal wurtzite ZnO was synthesized with nanocellulose using a facile hydrothermal method. Many highly active (001) facets were retained in the obtained ZnO nanocrystals, presumably due to interaction between the polar facet of ZnO and the nanocellulose. Given its effective surface area, the synthesized ZnO exhibited good photocatalytic activity of degrading methylene blue. Its degradation efficiency reached 94.4% within 30 min (UV irradiation power of 6 W), which was 34% higher than that of Degussa TiO2 P25. The ZnO photocatalyst also exhibited excellent reusability, confirmed by no obvious abatement after its being re-used for 8 cycles. These ZnO nanomaterials were synthesized using renewable nanocellulose derived from cotton. This environmentally friendly and cost-effective approach is anticipated to be applied in the future synthesis of small-sized ZnO photocatalysts.http://ojs.cnr.ncsu.edu/index.php/BioRes/article/view/BioRes_11_3_6244_Wei_Synthesis_Photocatalytic_Activity_NanocelluloseNanocrystalline ZnOExposed (001) active facetsNanocelluloseHydrothermalPhotocatalytic activityHydrothermal method
spellingShingle Guangyu Wei
Hong-Fen Zuo
Yuan-Ru Guo
Qing-Jiang Pan
Synthesis of ZnO with Enhanced Photocatalytic Activity: A Novel Approach Using Nanocellulose
BioResources
Nanocrystalline ZnO
Exposed (001) active facets
Nanocellulose
Hydrothermal
Photocatalytic activity
Hydrothermal method
title Synthesis of ZnO with Enhanced Photocatalytic Activity: A Novel Approach Using Nanocellulose
title_full Synthesis of ZnO with Enhanced Photocatalytic Activity: A Novel Approach Using Nanocellulose
title_fullStr Synthesis of ZnO with Enhanced Photocatalytic Activity: A Novel Approach Using Nanocellulose
title_full_unstemmed Synthesis of ZnO with Enhanced Photocatalytic Activity: A Novel Approach Using Nanocellulose
title_short Synthesis of ZnO with Enhanced Photocatalytic Activity: A Novel Approach Using Nanocellulose
title_sort synthesis of zno with enhanced photocatalytic activity a novel approach using nanocellulose
topic Nanocrystalline ZnO
Exposed (001) active facets
Nanocellulose
Hydrothermal
Photocatalytic activity
Hydrothermal method
url http://ojs.cnr.ncsu.edu/index.php/BioRes/article/view/BioRes_11_3_6244_Wei_Synthesis_Photocatalytic_Activity_Nanocellulose
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AT hongfenzuo synthesisofznowithenhancedphotocatalyticactivityanovelapproachusingnanocellulose
AT yuanruguo synthesisofznowithenhancedphotocatalyticactivityanovelapproachusingnanocellulose
AT qingjiangpan synthesisofznowithenhancedphotocatalyticactivityanovelapproachusingnanocellulose