μ-1,1′-Bis(diphenylphosphino)ferrocene-κ2P:P′-bis{[(Z)-O-isopropyl N-(4-nitrophenyl)thiocarbamato-κS]gold(I)} chloroform disolvate
The dinuclear title molecule, [Au2Fe(C10H11N2O3S)2(C17H14P)2]·2CHCl3, has crystallographic twofold symmetry with the Fe atom (bonded to two η5-cyclopentadienyl rings) situated on the rotation axis. The Au atom exists within a linear geometry defined by an S,P-donor set with...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809043864 |
| _version_ | 1819280139659247616 |
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| author | Soo Yei Ho Edward R. T. Tiekink |
| author_facet | Soo Yei Ho Edward R. T. Tiekink |
| author_sort | Soo Yei Ho |
| collection | DOAJ |
| description | The dinuclear title molecule, [Au2Fe(C10H11N2O3S)2(C17H14P)2]·2CHCl3, has crystallographic twofold symmetry with the Fe atom (bonded to two η5-cyclopentadienyl rings) situated on the rotation axis. The Au atom exists within a linear geometry defined by an S,P-donor set with a deviation from linearity [S—Au—P = 176.86 (6)°] due to the close approach of the thiocarbamate O atom [Au...O = 3.108 (5) Å]. The molecule has a U-shaped geometry which facilitates the formation of an intramolecular Au...Au interaction [3.0231 (5) Å]. In the crystal, the presence of C—H...Onitro contacts leads to the formation of layers with substantial voids; these are occupied by the solvent molecules of crystallization, which are held in place by C—H...S contacts. |
| first_indexed | 2024-12-24T00:39:03Z |
| format | Article |
| id | doaj.art-15ae5d2de64742208333acf4a7ef3749 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:39:03Z |
| publishDate | 2009-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-15ae5d2de64742208333acf4a7ef37492022-12-21T17:24:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1466m146710.1107/S1600536809043864μ-1,1′-Bis(diphenylphosphino)ferrocene-κ2P:P′-bis{[(Z)-O-isopropyl N-(4-nitrophenyl)thiocarbamato-κS]gold(I)} chloroform disolvateSoo Yei HoEdward R. T. TiekinkThe dinuclear title molecule, [Au2Fe(C10H11N2O3S)2(C17H14P)2]·2CHCl3, has crystallographic twofold symmetry with the Fe atom (bonded to two η5-cyclopentadienyl rings) situated on the rotation axis. The Au atom exists within a linear geometry defined by an S,P-donor set with a deviation from linearity [S—Au—P = 176.86 (6)°] due to the close approach of the thiocarbamate O atom [Au...O = 3.108 (5) Å]. The molecule has a U-shaped geometry which facilitates the formation of an intramolecular Au...Au interaction [3.0231 (5) Å]. In the crystal, the presence of C—H...Onitro contacts leads to the formation of layers with substantial voids; these are occupied by the solvent molecules of crystallization, which are held in place by C—H...S contacts.http://scripts.iucr.org/cgi-bin/paper?S1600536809043864 |
| spellingShingle | Soo Yei Ho Edward R. T. Tiekink μ-1,1′-Bis(diphenylphosphino)ferrocene-κ2P:P′-bis{[(Z)-O-isopropyl N-(4-nitrophenyl)thiocarbamato-κS]gold(I)} chloroform disolvate Acta Crystallographica Section E |
| title | μ-1,1′-Bis(diphenylphosphino)ferrocene-κ2P:P′-bis{[(Z)-O-isopropyl N-(4-nitrophenyl)thiocarbamato-κS]gold(I)} chloroform disolvate |
| title_full | μ-1,1′-Bis(diphenylphosphino)ferrocene-κ2P:P′-bis{[(Z)-O-isopropyl N-(4-nitrophenyl)thiocarbamato-κS]gold(I)} chloroform disolvate |
| title_fullStr | μ-1,1′-Bis(diphenylphosphino)ferrocene-κ2P:P′-bis{[(Z)-O-isopropyl N-(4-nitrophenyl)thiocarbamato-κS]gold(I)} chloroform disolvate |
| title_full_unstemmed | μ-1,1′-Bis(diphenylphosphino)ferrocene-κ2P:P′-bis{[(Z)-O-isopropyl N-(4-nitrophenyl)thiocarbamato-κS]gold(I)} chloroform disolvate |
| title_short | μ-1,1′-Bis(diphenylphosphino)ferrocene-κ2P:P′-bis{[(Z)-O-isopropyl N-(4-nitrophenyl)thiocarbamato-κS]gold(I)} chloroform disolvate |
| title_sort | amp 956 1 1 amp 8242 bis diphenylphosphino ferrocene amp 954 2p p amp 8242 bis z o isopropyl n 4 nitrophenyl thiocarbamato amp 954 s gold i chloroform disolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809043864 |
| work_keys_str_mv | AT sooyeiho amp95611amp8242bisdiphenylphosphinoferroceneamp9542ppamp8242biszoisopropyln4nitrophenylthiocarbamatoamp954sgoldichloroformdisolvate AT edwardrttiekink amp95611amp8242bisdiphenylphosphinoferroceneamp9542ppamp8242biszoisopropyln4nitrophenylthiocarbamatoamp954sgoldichloroformdisolvate |