Diversified constructions and electrochemical cycling stability of metal oxide fiber supercapacitors

Rapid development of electronic technology put forward high requirements for sustainable energy storage systems, and fiber supercapacitors have been considered as one of the prospective research fields. Herein, five metal oxides of Al2O3, Fe2O3, MoO2, NiO and ZnO are chosen as electrochemical active...

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Main Authors: Qi Wang, Xu Tian, Qian Gao, Xiaolin Zhang, Kai Rong, Meilin Cao, Ling Han, Wei Fan
Format: Article
Language:English
Published: Elsevier 2023-05-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S223878542300491X
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author Qi Wang
Xu Tian
Qian Gao
Xiaolin Zhang
Kai Rong
Meilin Cao
Ling Han
Wei Fan
author_facet Qi Wang
Xu Tian
Qian Gao
Xiaolin Zhang
Kai Rong
Meilin Cao
Ling Han
Wei Fan
author_sort Qi Wang
collection DOAJ
description Rapid development of electronic technology put forward high requirements for sustainable energy storage systems, and fiber supercapacitors have been considered as one of the prospective research fields. Herein, five metal oxides of Al2O3, Fe2O3, MoO2, NiO and ZnO are chosen as electrochemical active materials to prepare fiber electrodes as well as parallel fiber supercapacitors, respectively. According to the test results, ZnO fiber supercapacitor exhibits the optimal electrochemical performance among them, achieving 1.19 μF·cm−1 at the current density of 0.25 μA·cm−1. In addition, the electrochemical performance of parallel and twisted ZnO fiber supercapacitors are compared systematically so as to illustrate the effect of device structures on their electrochemical performance, and the twisted ZnO fiber supercapacitor shows higher capacitance retention and energy density than the parallel fiber device. Furthermore, the electrochemical cycling stability of parallel as well as twisted ZnO fiber supercapacitors are studied after 10,000 galvanostatic charge–discharge cycles, and parallel ZnO fiber supercapacitor presents better cycle stability owing to the simpler device structure. This work would provide effective evidence for the design and development of high-performance metal oxide-based fiber supercapacitors in the future.
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spelling doaj.art-15d8b41d44874b54badedc2cd460a8632023-06-21T06:55:34ZengElsevierJournal of Materials Research and Technology2238-78542023-05-0124909917Diversified constructions and electrochemical cycling stability of metal oxide fiber supercapacitorsQi Wang0Xu Tian1Qian Gao2Xiaolin Zhang3Kai Rong4Meilin Cao5Ling Han6Wei Fan7School of Textile Science and Engineering, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, China; Key Laboratory of Functional Textile Material and Product (Xi'an Polytechnic University), Ministry of Education, China; Corresponding author. School of Textile Science and Engineering, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, ChinaSchool of Textile Science and Engineering, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, ChinaSchool of Textile Science and Engineering, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, ChinaSchool of Textile Science and Engineering, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, China; Key Laboratory of Functional Textile Material and Product (Xi'an Polytechnic University), Ministry of Education, ChinaSchool of Textile Science and Engineering, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, ChinaSchool of Textile Science and Engineering, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, ChinaSchool of Textile Science and Engineering, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, China; Key Laboratory of Functional Textile Material and Product (Xi'an Polytechnic University), Ministry of Education, ChinaSchool of Textile Science and Engineering, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, China; Key Laboratory of Functional Textile Material and Product (Xi'an Polytechnic University), Ministry of Education, China; Corresponding author. School of Textile Science and Engineering, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, ChinaRapid development of electronic technology put forward high requirements for sustainable energy storage systems, and fiber supercapacitors have been considered as one of the prospective research fields. Herein, five metal oxides of Al2O3, Fe2O3, MoO2, NiO and ZnO are chosen as electrochemical active materials to prepare fiber electrodes as well as parallel fiber supercapacitors, respectively. According to the test results, ZnO fiber supercapacitor exhibits the optimal electrochemical performance among them, achieving 1.19 μF·cm−1 at the current density of 0.25 μA·cm−1. In addition, the electrochemical performance of parallel and twisted ZnO fiber supercapacitors are compared systematically so as to illustrate the effect of device structures on their electrochemical performance, and the twisted ZnO fiber supercapacitor shows higher capacitance retention and energy density than the parallel fiber device. Furthermore, the electrochemical cycling stability of parallel as well as twisted ZnO fiber supercapacitors are studied after 10,000 galvanostatic charge–discharge cycles, and parallel ZnO fiber supercapacitor presents better cycle stability owing to the simpler device structure. This work would provide effective evidence for the design and development of high-performance metal oxide-based fiber supercapacitors in the future.http://www.sciencedirect.com/science/article/pii/S223878542300491XWet spinningMetal oxide fiber supercapacitorsElectrochemical performanceCycle stability
spellingShingle Qi Wang
Xu Tian
Qian Gao
Xiaolin Zhang
Kai Rong
Meilin Cao
Ling Han
Wei Fan
Diversified constructions and electrochemical cycling stability of metal oxide fiber supercapacitors
Journal of Materials Research and Technology
Wet spinning
Metal oxide fiber supercapacitors
Electrochemical performance
Cycle stability
title Diversified constructions and electrochemical cycling stability of metal oxide fiber supercapacitors
title_full Diversified constructions and electrochemical cycling stability of metal oxide fiber supercapacitors
title_fullStr Diversified constructions and electrochemical cycling stability of metal oxide fiber supercapacitors
title_full_unstemmed Diversified constructions and electrochemical cycling stability of metal oxide fiber supercapacitors
title_short Diversified constructions and electrochemical cycling stability of metal oxide fiber supercapacitors
title_sort diversified constructions and electrochemical cycling stability of metal oxide fiber supercapacitors
topic Wet spinning
Metal oxide fiber supercapacitors
Electrochemical performance
Cycle stability
url http://www.sciencedirect.com/science/article/pii/S223878542300491X
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AT xutian diversifiedconstructionsandelectrochemicalcyclingstabilityofmetaloxidefibersupercapacitors
AT qiangao diversifiedconstructionsandelectrochemicalcyclingstabilityofmetaloxidefibersupercapacitors
AT xiaolinzhang diversifiedconstructionsandelectrochemicalcyclingstabilityofmetaloxidefibersupercapacitors
AT kairong diversifiedconstructionsandelectrochemicalcyclingstabilityofmetaloxidefibersupercapacitors
AT meilincao diversifiedconstructionsandelectrochemicalcyclingstabilityofmetaloxidefibersupercapacitors
AT linghan diversifiedconstructionsandelectrochemicalcyclingstabilityofmetaloxidefibersupercapacitors
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