Parametrical Function Describing Influences of the Redistribution of Incorporated Oil for Rupture Process Reconstruction in Rubber

The present work is focused on finding (i) the tearing energy at rupture and (ii) the redistribution of incorporated paraffin oil on the ruptured surfaces as functions of (a) the initial oil concentration and (b) the speed of deformation to the total rupture in a uniaxially induced deformation to ru...

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Main Authors: Sanjoy Datta, Radek Stoček, Evghenii Harea
Format: Article
Language:English
Published: MDPI AG 2023-03-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/15/6/1363
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author Sanjoy Datta
Radek Stoček
Evghenii Harea
author_facet Sanjoy Datta
Radek Stoček
Evghenii Harea
author_sort Sanjoy Datta
collection DOAJ
description The present work is focused on finding (i) the tearing energy at rupture and (ii) the redistribution of incorporated paraffin oil on the ruptured surfaces as functions of (a) the initial oil concentration and (b) the speed of deformation to the total rupture in a uniaxially induced deformation to rupture on an initially homogeneously oil incorporated styrene butadiene rubber (SBR) matrix. The aim is to understand the deforming speed of the rupture by calculating the concentration of the redistributed oil after rupture using infrared (IR) spectroscopy in an advanced continuation of a previously published work. The redistribution of the oil after tensile rupture for samples that have three different initial oil concentrations with a control sample that has no initial oil has been studied at three defined deformation speeds of rupture along with a cryo-ruptured sample. Single-edge notched tensile (SENT) specimens were used in the study. Parametric fittings of data at different deformation speeds were used to relate the concentration of the initial oil against the concentration of the redistributed oil. The novelty of this work is in the use of a simple IR spectroscopic method to reconstruct a fractographic process to rupture in relation to the speed of the deformation to rupture.
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spelling doaj.art-15edd51258804c579c5b48e4397215cc2023-11-17T13:24:31ZengMDPI AGPolymers2073-43602023-03-01156136310.3390/polym15061363Parametrical Function Describing Influences of the Redistribution of Incorporated Oil for Rupture Process Reconstruction in RubberSanjoy Datta0Radek Stoček1Evghenii Harea2Centre of Polymer Systems, Tomas Bata University in Zlín, tř. Tomáše Bati 5678, 760 01 Zlín, Czech RepublicCentre of Polymer Systems, Tomas Bata University in Zlín, tř. Tomáše Bati 5678, 760 01 Zlín, Czech RepublicCentre of Polymer Systems, Tomas Bata University in Zlín, tř. Tomáše Bati 5678, 760 01 Zlín, Czech RepublicThe present work is focused on finding (i) the tearing energy at rupture and (ii) the redistribution of incorporated paraffin oil on the ruptured surfaces as functions of (a) the initial oil concentration and (b) the speed of deformation to the total rupture in a uniaxially induced deformation to rupture on an initially homogeneously oil incorporated styrene butadiene rubber (SBR) matrix. The aim is to understand the deforming speed of the rupture by calculating the concentration of the redistributed oil after rupture using infrared (IR) spectroscopy in an advanced continuation of a previously published work. The redistribution of the oil after tensile rupture for samples that have three different initial oil concentrations with a control sample that has no initial oil has been studied at three defined deformation speeds of rupture along with a cryo-ruptured sample. Single-edge notched tensile (SENT) specimens were used in the study. Parametric fittings of data at different deformation speeds were used to relate the concentration of the initial oil against the concentration of the redistributed oil. The novelty of this work is in the use of a simple IR spectroscopic method to reconstruct a fractographic process to rupture in relation to the speed of the deformation to rupture.https://www.mdpi.com/2073-4360/15/6/1363rubberfractographytearing energyoil concentrationdeformation speedinfrared spectroscopy
spellingShingle Sanjoy Datta
Radek Stoček
Evghenii Harea
Parametrical Function Describing Influences of the Redistribution of Incorporated Oil for Rupture Process Reconstruction in Rubber
Polymers
rubber
fractography
tearing energy
oil concentration
deformation speed
infrared spectroscopy
title Parametrical Function Describing Influences of the Redistribution of Incorporated Oil for Rupture Process Reconstruction in Rubber
title_full Parametrical Function Describing Influences of the Redistribution of Incorporated Oil for Rupture Process Reconstruction in Rubber
title_fullStr Parametrical Function Describing Influences of the Redistribution of Incorporated Oil for Rupture Process Reconstruction in Rubber
title_full_unstemmed Parametrical Function Describing Influences of the Redistribution of Incorporated Oil for Rupture Process Reconstruction in Rubber
title_short Parametrical Function Describing Influences of the Redistribution of Incorporated Oil for Rupture Process Reconstruction in Rubber
title_sort parametrical function describing influences of the redistribution of incorporated oil for rupture process reconstruction in rubber
topic rubber
fractography
tearing energy
oil concentration
deformation speed
infrared spectroscopy
url https://www.mdpi.com/2073-4360/15/6/1363
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AT radekstocek parametricalfunctiondescribinginfluencesoftheredistributionofincorporatedoilforruptureprocessreconstructioninrubber
AT evgheniiharea parametricalfunctiondescribinginfluencesoftheredistributionofincorporatedoilforruptureprocessreconstructioninrubber