Semiconductive 2D arrays of pancake-bonded oligomers of partially charged TCNQ radicals

Semiconductive 2D arrays of pancake-bonded oligomers of partially charged TCNQ radicals

Multicentre two-electron (mc/2e or `pancake bonding') bonding between 7,7,8,8-tetracyanoquinodimethane (TCNQ) radical anions was studied on its 14 novel salts with planar organic cations. The formal charges of the TCNQδ− moieties are −1/2 and −2/3, and they form mc/2e bonded dimers, trimers and...

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Bibliographic Details
Main Authors: Krešimir Molčanov, Valentina Milašinović, Biserka Kojić-Prodić, Nadica Maltar-Strmečki, Jiangyang You, Ana Šantić, Lidija Kanižaj, Vladimir Stilinović, Luka Fotović
Format: Article
Language:English
Published: International Union of Crystallography 2022-07-01
Series:IUCrJ
Subjects:
multicentre two-electron bonding
tcnq radical anions
pancake bonding
crystal structures
crystal engineering
magnetic properties
electrical properties
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2052252522004717

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http://scripts.iucr.org/cgi-bin/paper?S2052252522004717

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