Preliminary studies on hydrated cement for its reuse in geopolymers

The carbonation of hydrated ordinary Portland cement (OPC) allows the transformation of hydrated calcium aluminates and silicates into calcium carbonate and amorphous silica/ alumina. These carbonated materials are appropriate to being used as inorganic precursors for alkaline activation. The use of...

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Bibliographic Details
Main Authors: Yasna Segura Sierpes, María Victoria Borrachero Rosado, José María Monzó Balbuena, Jordi Payá Bernabeu
Format: Article
Language:English
Published: Universidad Nacional de Colombia 2016-03-01
Series:Dyna
Subjects:
Online Access:https://revistas.unal.edu.co/index.php/dyna/article/view/54189
Description
Summary:The carbonation of hydrated ordinary Portland cement (OPC) allows the transformation of hydrated calcium aluminates and silicates into calcium carbonate and amorphous silica/ alumina. These carbonated materials are appropriate to being used as inorganic precursors for alkaline activation. The use of sodium silicate and hydroxide solutions enables the production of cementitious gels. Two ways of carbonation of hydrated cement were studied: in a dry environment, where relative humidity did not exceed 70% and in an aqueous medium at a temperature of 5 ± 1 ° C. Both materials were micro-structurally characterised and they have been used for the manufacturing of geopolymeric mortars. These mortars reached mechanical strength between 10 and 20 MPa, depending on the activating solution, the water/binder ratio and curing time/temperature. These results show the feasibility of reusing hydrated cement contained in construction and demolition wastes.
ISSN:0012-7353
2346-2183