Novel Approach to the Preparation of Lead Chalcogenide Colloidal Quantum Dots and Properties Thereof
In this work, we report the study of resizing of lead chalcogenide quantum dots, both PbS and PbSe, in the presence of the oleylamine/oleic acid mixture. We demonstrate that the resizing of lead chalcogenide nanocrystals could be performed in aprotic non-polar solvents. The kinetics of the shrinking...
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MDPI AG
2023-05-01
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Online Access: | https://www.mdpi.com/2673-4605/14/1/30 |
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author | Ivan A. Shuklov Irina I. Soboleva |
author_facet | Ivan A. Shuklov Irina I. Soboleva |
author_sort | Ivan A. Shuklov |
collection | DOAJ |
description | In this work, we report the study of resizing of lead chalcogenide quantum dots, both PbS and PbSe, in the presence of the oleylamine/oleic acid mixture. We demonstrate that the resizing of lead chalcogenide nanocrystals could be performed in aprotic non-polar solvents. The kinetics of the shrinking could be followed by the measurement of absorption at 400 nm. The amount of a resizing reagent, namely the oleylamine/oleic acid mixture, influences the rate of reaction. This procedure could serve for the preparation of smaller lead chalcogenide quantum dots from a larger one. |
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institution | Directory Open Access Journal |
issn | 2673-4605 |
language | English |
last_indexed | 2024-03-10T22:29:39Z |
publishDate | 2023-05-01 |
publisher | MDPI AG |
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series | Materials Proceedings |
spelling | doaj.art-1651634ccd564f0c91545e1c180988162023-11-19T11:46:40ZengMDPI AGMaterials Proceedings2673-46052023-05-011413010.3390/IOCN2023-14522Novel Approach to the Preparation of Lead Chalcogenide Colloidal Quantum Dots and Properties ThereofIvan A. Shuklov0Irina I. Soboleva1Moscow Institute of Physics and Technology, National Research University, 141701 Dolgoprudny, RussiaMoscow Institute of Physics and Technology, National Research University, 141701 Dolgoprudny, RussiaIn this work, we report the study of resizing of lead chalcogenide quantum dots, both PbS and PbSe, in the presence of the oleylamine/oleic acid mixture. We demonstrate that the resizing of lead chalcogenide nanocrystals could be performed in aprotic non-polar solvents. The kinetics of the shrinking could be followed by the measurement of absorption at 400 nm. The amount of a resizing reagent, namely the oleylamine/oleic acid mixture, influences the rate of reaction. This procedure could serve for the preparation of smaller lead chalcogenide quantum dots from a larger one.https://www.mdpi.com/2673-4605/14/1/30colloidal quantum dotslead sulfidelead selenideresizingsolvent effect |
spellingShingle | Ivan A. Shuklov Irina I. Soboleva Novel Approach to the Preparation of Lead Chalcogenide Colloidal Quantum Dots and Properties Thereof Materials Proceedings colloidal quantum dots lead sulfide lead selenide resizing solvent effect |
title | Novel Approach to the Preparation of Lead Chalcogenide Colloidal Quantum Dots and Properties Thereof |
title_full | Novel Approach to the Preparation of Lead Chalcogenide Colloidal Quantum Dots and Properties Thereof |
title_fullStr | Novel Approach to the Preparation of Lead Chalcogenide Colloidal Quantum Dots and Properties Thereof |
title_full_unstemmed | Novel Approach to the Preparation of Lead Chalcogenide Colloidal Quantum Dots and Properties Thereof |
title_short | Novel Approach to the Preparation of Lead Chalcogenide Colloidal Quantum Dots and Properties Thereof |
title_sort | novel approach to the preparation of lead chalcogenide colloidal quantum dots and properties thereof |
topic | colloidal quantum dots lead sulfide lead selenide resizing solvent effect |
url | https://www.mdpi.com/2673-4605/14/1/30 |
work_keys_str_mv | AT ivanashuklov novelapproachtothepreparationofleadchalcogenidecolloidalquantumdotsandpropertiesthereof AT irinaisoboleva novelapproachtothepreparationofleadchalcogenidecolloidalquantumdotsandpropertiesthereof |