Ir-Catalyzed Chemo-, Regio-, and Enantioselective Allylic Enolization of 6,6-Dimethyl-3-((trimethylsilyl)oxy)cyclohex-2-en-1-one Involving Keto-Enol Isomerization

Ir-Catalyzed Chemo-, Regio-, and Enantioselective Allylic Enolization of 6,6-Dimethyl-3-((trimethylsilyl)oxy)cyclohex-2-en-1-one Involving Keto-Enol Isomerization

The utilization of 6,6-dimethyl-3-((trimethylsilyl)oxy)cyclohex-2-en-1-one made from an unsymmetrical 4,4-dimethylcyclohexane-1,3-dione in iridium-catalyzed allylic enolization involving keto-enol isomerization is accomplished under mild conditions. The chemoselectivity, regioselectivity, and enanti...

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Bibliographic Details
Main Authors: Xiao-Lin Wang, Ji-Teng Chen, Sheng-Cai Zheng, Xiao-Ming Zhao
Format: Article
Language:English
Published: MDPI AG 2022-10-01
Series:Molecules
Subjects:
enolization
chemoselectivity
regioselectivity
enantioselectivity
fluorination
Online Access:https://www.mdpi.com/1420-3049/27/20/6981

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