Facile Synthesis of Microporous Ferrocenyl Polymers Photocatalyst for Degradation of Cationic Dye
Microporous organic polymers (MOPs) were prepared by condensation reactions from substituent-group-free carbazole and pyrrole with 1,1′-ferrocenedicarboxaldehyde without adding any catalysts. The resultant MOPs were insoluble in common solvent and characterized by FTIR, XPS, TGA and SEM. An N<sub...
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| Format: | Article |
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MDPI AG
2022-05-01
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| Series: | Polymers |
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| Online Access: | https://www.mdpi.com/2073-4360/14/9/1900 |
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| author | Bing Zhang Zhiqiang Tan Yinhu Zhang Qingquan Liu Qianxia Li Gen Li |
| author_facet | Bing Zhang Zhiqiang Tan Yinhu Zhang Qingquan Liu Qianxia Li Gen Li |
| author_sort | Bing Zhang |
| collection | DOAJ |
| description | Microporous organic polymers (MOPs) were prepared by condensation reactions from substituent-group-free carbazole and pyrrole with 1,1′-ferrocenedicarboxaldehyde without adding any catalysts. The resultant MOPs were insoluble in common solvent and characterized by FTIR, XPS, TGA and SEM. An N<sub>2</sub> adsorption test showed that the obtained polymers PFcMOP and CFcMOP exhibited Brunauer–Emmett–Teller (BET) surface areas of 48 and 105 m<sup>2</sup> g<sup>−1</sup>, respectively, and both polymers possessed abundant micropores. The MOPs with a nitrogen and ferrocene unit could be potentially applied in degrading dye with high efficiency. |
| first_indexed | 2024-03-10T03:45:35Z |
| format | Article |
| id | doaj.art-1696d09bdc964cb1a08451c22528460d |
| institution | Directory Open Access Journal |
| issn | 2073-4360 |
| language | English |
| last_indexed | 2024-03-10T03:45:35Z |
| publishDate | 2022-05-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Polymers |
| spelling | doaj.art-1696d09bdc964cb1a08451c22528460d2023-11-23T09:07:56ZengMDPI AGPolymers2073-43602022-05-01149190010.3390/polym14091900Facile Synthesis of Microporous Ferrocenyl Polymers Photocatalyst for Degradation of Cationic DyeBing Zhang0Zhiqiang Tan1Yinhu Zhang2Qingquan Liu3Qianxia Li4Gen Li5Hunan Provincial Key Laboratory of Advanced Materials for New Energy Storage and Conversion, School of Materials Science and Engineering, Hunan University of Science and Technology, Taoyuan Street, Xiangtan 411201, ChinaHunan Provincial Key Laboratory of Advanced Materials for New Energy Storage and Conversion, School of Materials Science and Engineering, Hunan University of Science and Technology, Taoyuan Street, Xiangtan 411201, ChinaHunan Provincial Key Laboratory of Advanced Materials for New Energy Storage and Conversion, School of Materials Science and Engineering, Hunan University of Science and Technology, Taoyuan Street, Xiangtan 411201, ChinaHunan Provincial Key Laboratory of Advanced Materials for New Energy Storage and Conversion, School of Materials Science and Engineering, Hunan University of Science and Technology, Taoyuan Street, Xiangtan 411201, ChinaHunan Provincial Key Laboratory of Advanced Materials for New Energy Storage and Conversion, School of Materials Science and Engineering, Hunan University of Science and Technology, Taoyuan Street, Xiangtan 411201, ChinaHunan Provincial Key Laboratory of Advanced Materials for New Energy Storage and Conversion, School of Materials Science and Engineering, Hunan University of Science and Technology, Taoyuan Street, Xiangtan 411201, ChinaMicroporous organic polymers (MOPs) were prepared by condensation reactions from substituent-group-free carbazole and pyrrole with 1,1′-ferrocenedicarboxaldehyde without adding any catalysts. The resultant MOPs were insoluble in common solvent and characterized by FTIR, XPS, TGA and SEM. An N<sub>2</sub> adsorption test showed that the obtained polymers PFcMOP and CFcMOP exhibited Brunauer–Emmett–Teller (BET) surface areas of 48 and 105 m<sup>2</sup> g<sup>−1</sup>, respectively, and both polymers possessed abundant micropores. The MOPs with a nitrogen and ferrocene unit could be potentially applied in degrading dye with high efficiency.https://www.mdpi.com/2073-4360/14/9/1900microporous polymersferrocenylphotocatalystcationic dye |
| spellingShingle | Bing Zhang Zhiqiang Tan Yinhu Zhang Qingquan Liu Qianxia Li Gen Li Facile Synthesis of Microporous Ferrocenyl Polymers Photocatalyst for Degradation of Cationic Dye Polymers microporous polymers ferrocenyl photocatalyst cationic dye |
| title | Facile Synthesis of Microporous Ferrocenyl Polymers Photocatalyst for Degradation of Cationic Dye |
| title_full | Facile Synthesis of Microporous Ferrocenyl Polymers Photocatalyst for Degradation of Cationic Dye |
| title_fullStr | Facile Synthesis of Microporous Ferrocenyl Polymers Photocatalyst for Degradation of Cationic Dye |
| title_full_unstemmed | Facile Synthesis of Microporous Ferrocenyl Polymers Photocatalyst for Degradation of Cationic Dye |
| title_short | Facile Synthesis of Microporous Ferrocenyl Polymers Photocatalyst for Degradation of Cationic Dye |
| title_sort | facile synthesis of microporous ferrocenyl polymers photocatalyst for degradation of cationic dye |
| topic | microporous polymers ferrocenyl photocatalyst cationic dye |
| url | https://www.mdpi.com/2073-4360/14/9/1900 |
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