Tetraaquabis{5-[4-(imidazol-1-yl-κN3)phenyl]tetrazolido}manganese(II)

In the title complex, [Mn(C10H7N6)2(H2O)4], the Mn2+ cation is located on a twofold rotation axis and is coordinated by two N atoms from two 5-[4-(imidazol-1-yl)phenyl]tetrazolide ligands and four O atoms from four water molecules, displaying a distorted MnN2O4 octahedral geometry. The crystal struc...

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Bibliografische gegevens
Hoofdauteur: Xiao-Chun Cheng
Formaat: Artikel
Taal:English
Gepubliceerd in: International Union of Crystallography 2011-12-01
Reeks:Acta Crystallographica Section E
Online toegang:http://scripts.iucr.org/cgi-bin/paper?S1600536811047428
Omschrijving
Samenvatting:In the title complex, [Mn(C10H7N6)2(H2O)4], the Mn2+ cation is located on a twofold rotation axis and is coordinated by two N atoms from two 5-[4-(imidazol-1-yl)phenyl]tetrazolide ligands and four O atoms from four water molecules, displaying a distorted MnN2O4 octahedral geometry. The crystal structure is stabilized by intermolecular O—H...N hydrogen bonds involving the coordinated water molecules and the N atoms of the tetrazolide group.
ISSN:1600-5368