Crystal Structure of N,N-bis-(3-Carbomethoxy-5-methyl-pyrazol-1-ylmethyl)aniline

Crystal Structure of N,N-bis-(3-Carbomethoxy-5-methyl-pyrazol-1-ylmethyl)aniline

The tripodal ligand N,N-bis-(3-carbomethoxy-5-methylpyrazol-1-yl)methyl aniline (2) has been prepared by the condensation of aniline with two equivalents of N-hydroxymethyl[3-carbomethoxy-5-methyl]pyrazole. The molecule consists of two structurally analogous 3-carbomethoxy-5-methylpyrazol-1-ylmethyl...

Full description

Bibliographic Details
Main Authors: Taibi Ben-Hadda, Mostafa Mimouni, Joël Jaud, Jacques Bonvoisin, Jean Pierre Launay, Abdelali Kerbal, Driss Benjelloun, Najib Ben Larbi, Maria Daoudi
Format: Article
Language:English
Published: MDPI AG 2002-09-01
Series:Molecules
Subjects:
Structure
tripod
pyrazole
tridentate
flexible ligand
Online Access:http://www.mdpi.com/1420-3049/7/9/690/
Description
Summary:The tripodal ligand N,N-bis-(3-carbomethoxy-5-methylpyrazol-1-yl)methyl aniline (2) has been prepared by the condensation of aniline with two equivalents of N-hydroxymethyl[3-carbomethoxy-5-methyl]pyrazole. The molecule consists of two structurally analogous 3-carbomethoxy-5-methylpyrazol-1-ylmethyl moieties, which adopt a transoidal conformation via a central aniline ring, suggesting that this tripodal ligand is highly flexible and could accommodate many metals by coordination.
ISSN:1420-3049

Similar Items