Non-radiative processes in metal halide perovskite semiconductors probed by photoluminescence microscopy

Organo metal halide perovskites are solution processed semiconductors that recently attracted a great attention. They possess a rather “soft” and (photo) chemically active solid structure allowing for ion migration and other mass diffusion processes. This is a likely reason why non-radiative recombi...

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Main Authors: Merdasa Aboma, Gerhard Marina, Louis Boris, Li Jun, Dobrovolsky Alexander, Tian Yuxi, Hofkens Johan, Camacho Rafael, Unger Eva, Scheblykin Ivan G.
Format: Article
Language:English
Published: EDP Sciences 2018-01-01
Series:EPJ Web of Conferences
Online Access:https://doi.org/10.1051/epjconf/201819002011
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author Merdasa Aboma
Gerhard Marina
Louis Boris
Li Jun
Dobrovolsky Alexander
Tian Yuxi
Hofkens Johan
Camacho Rafael
Unger Eva
Scheblykin Ivan G.
author_facet Merdasa Aboma
Gerhard Marina
Louis Boris
Li Jun
Dobrovolsky Alexander
Tian Yuxi
Hofkens Johan
Camacho Rafael
Unger Eva
Scheblykin Ivan G.
author_sort Merdasa Aboma
collection DOAJ
description Organo metal halide perovskites are solution processed semiconductors that recently attracted a great attention. They possess a rather “soft” and (photo) chemically active solid structure allowing for ion migration and other mass diffusion processes. This is a likely reason why non-radiative recombination centres in these materials are activated and deactivated on relatively slow time-scales. This dynamics reveals as photoluminescence (PL) fluctuations (blinking) of individual microcrystals and local areas of films and allows for application of a broad range of single molecule spectroscopy methods including optical super-resolution. Studying PL blinking resolves properties of individual non-radiative centres and helps to unravel their chemical nature.
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spelling doaj.art-16e7b5b36e4d475896cf4c5b76e1a48b2022-12-21T22:36:04ZengEDP SciencesEPJ Web of Conferences2100-014X2018-01-011900201110.1051/epjconf/201819002011epjconf_hbsm2018_02011Non-radiative processes in metal halide perovskite semiconductors probed by photoluminescence microscopyMerdasa Aboma0Gerhard Marina1Louis BorisLi Jun2Dobrovolsky Alexander3Tian Yuxi4Hofkens Johan5Camacho Rafael6Unger Eva7Scheblykin Ivan G.8Helmholtz-Zentrum Berlin für Mater. und Energie GmbHChemical Physics and NanoLund, Lund UniversityChemical Physics and NanoLund, Lund UniversityChemical Physics and NanoLund, Lund UniversityDepartment of Chemistry, KU LeuvenDepartment of Chemistry, KU LeuvenDepartment of Chemistry, KU LeuvenSchool of Chem. & Chem. Engineering, Nanjing UniversityChemical Physics and NanoLund, Lund UniversityOrgano metal halide perovskites are solution processed semiconductors that recently attracted a great attention. They possess a rather “soft” and (photo) chemically active solid structure allowing for ion migration and other mass diffusion processes. This is a likely reason why non-radiative recombination centres in these materials are activated and deactivated on relatively slow time-scales. This dynamics reveals as photoluminescence (PL) fluctuations (blinking) of individual microcrystals and local areas of films and allows for application of a broad range of single molecule spectroscopy methods including optical super-resolution. Studying PL blinking resolves properties of individual non-radiative centres and helps to unravel their chemical nature.https://doi.org/10.1051/epjconf/201819002011
spellingShingle Merdasa Aboma
Gerhard Marina
Louis Boris
Li Jun
Dobrovolsky Alexander
Tian Yuxi
Hofkens Johan
Camacho Rafael
Unger Eva
Scheblykin Ivan G.
Non-radiative processes in metal halide perovskite semiconductors probed by photoluminescence microscopy
EPJ Web of Conferences
title Non-radiative processes in metal halide perovskite semiconductors probed by photoluminescence microscopy
title_full Non-radiative processes in metal halide perovskite semiconductors probed by photoluminescence microscopy
title_fullStr Non-radiative processes in metal halide perovskite semiconductors probed by photoluminescence microscopy
title_full_unstemmed Non-radiative processes in metal halide perovskite semiconductors probed by photoluminescence microscopy
title_short Non-radiative processes in metal halide perovskite semiconductors probed by photoluminescence microscopy
title_sort non radiative processes in metal halide perovskite semiconductors probed by photoluminescence microscopy
url https://doi.org/10.1051/epjconf/201819002011
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