Porous Hydrogen-Bonded Organic Frameworks

Ordered porous solid-state architectures constructed via non-covalent supramolecular self-assembly have attracted increasing interest due to their unique advantages and potential applications. Porous metal-coordination organic frameworks (MOFs) are generated by the assembly of metal coordination cen...

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Main Authors: Yi-Fei Han, Ying-Xue Yuan, Hong-Bo Wang
Format: Article
Language:English
Published: MDPI AG 2017-02-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/22/2/266
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author Yi-Fei Han
Ying-Xue Yuan
Hong-Bo Wang
author_facet Yi-Fei Han
Ying-Xue Yuan
Hong-Bo Wang
author_sort Yi-Fei Han
collection DOAJ
description Ordered porous solid-state architectures constructed via non-covalent supramolecular self-assembly have attracted increasing interest due to their unique advantages and potential applications. Porous metal-coordination organic frameworks (MOFs) are generated by the assembly of metal coordination centers and organic linkers. Compared to MOFs, porous hydrogen-bonded organic frameworks (HOFs) are readily purified and recovered via simple recrystallization. However, due to lacking of sufficiently ability to orientate self-aggregation of building motifs in predictable manners, rational design and preparation of porous HOFs are still challenging. Herein, we summarize recent developments about porous HOFs and attempt to gain deeper insights into the design strategies of basic building motifs.
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spelling doaj.art-1717aff4aafb44d4adf2887c1bd4ff422022-12-21T23:01:19ZengMDPI AGMolecules1420-30492017-02-0122226610.3390/molecules22020266molecules22020266Porous Hydrogen-Bonded Organic FrameworksYi-Fei Han0Ying-Xue Yuan1Hong-Bo Wang2Key Laboratory of Optoelectronic Chemical Materials and Devices of Ministry of Education, School of Chemical and Environmental Engineering, Jianghan University, Wuhan 430056, Hubei, ChinaKey Laboratory of Optoelectronic Chemical Materials and Devices of Ministry of Education, School of Chemical and Environmental Engineering, Jianghan University, Wuhan 430056, Hubei, ChinaKey Laboratory of Optoelectronic Chemical Materials and Devices of Ministry of Education, School of Chemical and Environmental Engineering, Jianghan University, Wuhan 430056, Hubei, ChinaOrdered porous solid-state architectures constructed via non-covalent supramolecular self-assembly have attracted increasing interest due to their unique advantages and potential applications. Porous metal-coordination organic frameworks (MOFs) are generated by the assembly of metal coordination centers and organic linkers. Compared to MOFs, porous hydrogen-bonded organic frameworks (HOFs) are readily purified and recovered via simple recrystallization. However, due to lacking of sufficiently ability to orientate self-aggregation of building motifs in predictable manners, rational design and preparation of porous HOFs are still challenging. Herein, we summarize recent developments about porous HOFs and attempt to gain deeper insights into the design strategies of basic building motifs.http://www.mdpi.com/1420-3049/22/2/266hydrogen bondsorganic porous frameworkssupramolecular self-assembly
spellingShingle Yi-Fei Han
Ying-Xue Yuan
Hong-Bo Wang
Porous Hydrogen-Bonded Organic Frameworks
Molecules
hydrogen bonds
organic porous frameworks
supramolecular self-assembly
title Porous Hydrogen-Bonded Organic Frameworks
title_full Porous Hydrogen-Bonded Organic Frameworks
title_fullStr Porous Hydrogen-Bonded Organic Frameworks
title_full_unstemmed Porous Hydrogen-Bonded Organic Frameworks
title_short Porous Hydrogen-Bonded Organic Frameworks
title_sort porous hydrogen bonded organic frameworks
topic hydrogen bonds
organic porous frameworks
supramolecular self-assembly
url http://www.mdpi.com/1420-3049/22/2/266
work_keys_str_mv AT yifeihan poroushydrogenbondedorganicframeworks
AT yingxueyuan poroushydrogenbondedorganicframeworks
AT hongbowang poroushydrogenbondedorganicframeworks