(E)-4-Methoxy-N′-(2,4,5-trifluorobenzylidene)benzohydrazide monohydrate
The title Schiff base compound, C15H11F3N2O2·H2O, crystallized as a monohydrate. The conformation about the C=N bond is E. The molecule is almost planar, with the dihedral angle between the planes of the methoxybenzene and trifluorobenzylidene rings being 7.46 (6)°. In the crystal, molecules are lin...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016-05-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314616008464 |
| _version_ | 1818853931935072256 |
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| author | R. Maheswari J. Manjula B. Gunasekaran G. Bakiyaraj |
| author_facet | R. Maheswari J. Manjula B. Gunasekaran G. Bakiyaraj |
| author_sort | R. Maheswari |
| collection | DOAJ |
| description | The title Schiff base compound, C15H11F3N2O2·H2O, crystallized as a monohydrate. The conformation about the C=N bond is E. The molecule is almost planar, with the dihedral angle between the planes of the methoxybenzene and trifluorobenzylidene rings being 7.46 (6)°. In the crystal, molecules are linked by bifurcated Owater—H...(O,N) hydrogen bonds and N—H...Owater and Owater—H...O and C—H...O hydrogen bonds, forming chains along [100]. The chains are linked by C—H...Owater hydrogen bonds, forming slabs parallel to the bc plane. Within the slabs there are offset π–π interactions present [intercentroid distance = 3.7883 (7) Å]. |
| first_indexed | 2024-12-19T07:44:40Z |
| format | Article |
| id | doaj.art-1720160b21ec4c7ba54a0e39ed1e84fc |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-19T07:44:40Z |
| publishDate | 2016-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-1720160b21ec4c7ba54a0e39ed1e84fc2022-12-21T20:30:23ZengInternational Union of CrystallographyIUCrData2414-31462016-05-0115x16084610.1107/S2414314616008464su4051(E)-4-Methoxy-N′-(2,4,5-trifluorobenzylidene)benzohydrazide monohydrateR. Maheswari0J. Manjula1B. Gunasekaran2G. Bakiyaraj3Department of Chemistry, Saranathan College of Engineering, Tiruchirappalli, Tamilnadu, IndiaPG and Research Department of Chemistry, Periyar EVR College, Tiruchirappalli, Tamilnadu, IndiaDepartment of Physics & Nano Technology, SRM University, SRM Nagar, Kattankulathur, Kancheepuram Dist, Chennai 603 203, Tamil Nadu, IndiaDepartment of Physics & Nano Technology, SRM University, SRM Nagar, Kattankulathur, Kancheepuram Dist, Chennai 603 203, Tamil Nadu, IndiaThe title Schiff base compound, C15H11F3N2O2·H2O, crystallized as a monohydrate. The conformation about the C=N bond is E. The molecule is almost planar, with the dihedral angle between the planes of the methoxybenzene and trifluorobenzylidene rings being 7.46 (6)°. In the crystal, molecules are linked by bifurcated Owater—H...(O,N) hydrogen bonds and N—H...Owater and Owater—H...O and C—H...O hydrogen bonds, forming chains along [100]. The chains are linked by C—H...Owater hydrogen bonds, forming slabs parallel to the bc plane. Within the slabs there are offset π–π interactions present [intercentroid distance = 3.7883 (7) Å].http://scripts.iucr.org/cgi-bin/paper?S2414314616008464crystal structurebenzohydrazideSchiff basebifurcated hydrogen bondshydrogen bonding |
| spellingShingle | R. Maheswari J. Manjula B. Gunasekaran G. Bakiyaraj (E)-4-Methoxy-N′-(2,4,5-trifluorobenzylidene)benzohydrazide monohydrate IUCrData crystal structure benzohydrazide Schiff base bifurcated hydrogen bonds hydrogen bonding |
| title | (E)-4-Methoxy-N′-(2,4,5-trifluorobenzylidene)benzohydrazide monohydrate |
| title_full | (E)-4-Methoxy-N′-(2,4,5-trifluorobenzylidene)benzohydrazide monohydrate |
| title_fullStr | (E)-4-Methoxy-N′-(2,4,5-trifluorobenzylidene)benzohydrazide monohydrate |
| title_full_unstemmed | (E)-4-Methoxy-N′-(2,4,5-trifluorobenzylidene)benzohydrazide monohydrate |
| title_short | (E)-4-Methoxy-N′-(2,4,5-trifluorobenzylidene)benzohydrazide monohydrate |
| title_sort | e 4 methoxy n 2 4 5 trifluorobenzylidene benzohydrazide monohydrate |
| topic | crystal structure benzohydrazide Schiff base bifurcated hydrogen bonds hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314616008464 |
| work_keys_str_mv | AT rmaheswari e4methoxyn245trifluorobenzylidenebenzohydrazidemonohydrate AT jmanjula e4methoxyn245trifluorobenzylidenebenzohydrazidemonohydrate AT bgunasekaran e4methoxyn245trifluorobenzylidenebenzohydrazidemonohydrate AT gbakiyaraj e4methoxyn245trifluorobenzylidenebenzohydrazidemonohydrate |