Synthesized PANI/CeO<sub>2</sub> Nanocomposite Films for Enhanced Anti-Corrosion Performance
This study introduces a novel nanocomposite coating composed of PANI/CeO<sub>2</sub> nanocomposite films, aimed at addressing corrosion protection needs. Analysis through FTIR spectra and XRD patterns confirms the successful formation of the nanocomposite films. Notably, the PANI/CeO<...
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MDPI AG
2024-03-01
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author | Ahmad M. Alsaad Mohannad Al-Hmoud Taha M. Rababah Mohammad W. Marashdeh Mamduh J. Aljaafreh Sharif Abu Alrub Ayed Binzowaimil Ahmad Telfah |
author_facet | Ahmad M. Alsaad Mohannad Al-Hmoud Taha M. Rababah Mohammad W. Marashdeh Mamduh J. Aljaafreh Sharif Abu Alrub Ayed Binzowaimil Ahmad Telfah |
author_sort | Ahmad M. Alsaad |
collection | DOAJ |
description | This study introduces a novel nanocomposite coating composed of PANI/CeO<sub>2</sub> nanocomposite films, aimed at addressing corrosion protection needs. Analysis through FTIR spectra and XRD patterns confirms the successful formation of the nanocomposite films. Notably, the PANI/CeO<sub>2</sub> nanocomposite films exhibit a hydrophilic nature. The bandgap energy of the PANI composite film is measured to be 3.74 eV, while the introduction of CeO<sub>2</sub> NPs into the PANI matrix reduces the bandgap energy to 3.67 eV. Furthermore, the electrical conductivity of the PANI composite film is observed to be 0.40 S·cm<sup>−1</sup>, with the incorporation of CeO<sub>2</sub> NPs leading to an increase in electrical conductivity to 1.07 S·cm<sup>−1</sup>. To evaluate its efficacy, electrochemical measurements were conducted to assess the corrosion protection performance. Results indicate a high protection efficiency of 92.25% for the PANI/CeO<sub>2</sub> nanocomposite film. |
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institution | Directory Open Access Journal |
issn | 2079-4991 |
language | English |
last_indexed | 2024-04-24T17:56:52Z |
publishDate | 2024-03-01 |
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series | Nanomaterials |
spelling | doaj.art-1795a81d494c4afd8e0b4d83cfc2c96f2024-03-27T13:57:36ZengMDPI AGNanomaterials2079-49912024-03-0114652610.3390/nano14060526Synthesized PANI/CeO<sub>2</sub> Nanocomposite Films for Enhanced Anti-Corrosion PerformanceAhmad M. Alsaad0Mohannad Al-Hmoud1Taha M. Rababah2Mohammad W. Marashdeh3Mamduh J. Aljaafreh4Sharif Abu Alrub5Ayed Binzowaimil6Ahmad Telfah7Department of Physics, Jordan University of Science and Technology, P.O. Box 3030, Irbid 22110, JordanDepartment of Physics, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), P.O. Box 90950, Riyadh 11623, Saudi ArabiaDepartment of Nutrition and Food Technology, Faculty of Agriculture, Jordan University of Science and Technology, P.O. Box 3030, Irbid 22110, JordanDepartment of Physics, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), P.O. Box 90950, Riyadh 11623, Saudi ArabiaDepartment of Physics, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), P.O. Box 90950, Riyadh 11623, Saudi ArabiaDepartment of Physics, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), P.O. Box 90950, Riyadh 11623, Saudi ArabiaDepartment of Physics, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), P.O. Box 90950, Riyadh 11623, Saudi ArabiaDepartment of Physics, University of Nebraska at Omaha, Omaha, NE 68182, USAThis study introduces a novel nanocomposite coating composed of PANI/CeO<sub>2</sub> nanocomposite films, aimed at addressing corrosion protection needs. Analysis through FTIR spectra and XRD patterns confirms the successful formation of the nanocomposite films. Notably, the PANI/CeO<sub>2</sub> nanocomposite films exhibit a hydrophilic nature. The bandgap energy of the PANI composite film is measured to be 3.74 eV, while the introduction of CeO<sub>2</sub> NPs into the PANI matrix reduces the bandgap energy to 3.67 eV. Furthermore, the electrical conductivity of the PANI composite film is observed to be 0.40 S·cm<sup>−1</sup>, with the incorporation of CeO<sub>2</sub> NPs leading to an increase in electrical conductivity to 1.07 S·cm<sup>−1</sup>. To evaluate its efficacy, electrochemical measurements were conducted to assess the corrosion protection performance. Results indicate a high protection efficiency of 92.25% for the PANI/CeO<sub>2</sub> nanocomposite film.https://www.mdpi.com/2079-4991/14/6/526corrosion protectionprotonated polyaniline (PANI)cerium dioxide (CeO<sub>2</sub>)optical bandgap energyelectrical conductivity |
spellingShingle | Ahmad M. Alsaad Mohannad Al-Hmoud Taha M. Rababah Mohammad W. Marashdeh Mamduh J. Aljaafreh Sharif Abu Alrub Ayed Binzowaimil Ahmad Telfah Synthesized PANI/CeO<sub>2</sub> Nanocomposite Films for Enhanced Anti-Corrosion Performance Nanomaterials corrosion protection protonated polyaniline (PANI) cerium dioxide (CeO<sub>2</sub>) optical bandgap energy electrical conductivity |
title | Synthesized PANI/CeO<sub>2</sub> Nanocomposite Films for Enhanced Anti-Corrosion Performance |
title_full | Synthesized PANI/CeO<sub>2</sub> Nanocomposite Films for Enhanced Anti-Corrosion Performance |
title_fullStr | Synthesized PANI/CeO<sub>2</sub> Nanocomposite Films for Enhanced Anti-Corrosion Performance |
title_full_unstemmed | Synthesized PANI/CeO<sub>2</sub> Nanocomposite Films for Enhanced Anti-Corrosion Performance |
title_short | Synthesized PANI/CeO<sub>2</sub> Nanocomposite Films for Enhanced Anti-Corrosion Performance |
title_sort | synthesized pani ceo sub 2 sub nanocomposite films for enhanced anti corrosion performance |
topic | corrosion protection protonated polyaniline (PANI) cerium dioxide (CeO<sub>2</sub>) optical bandgap energy electrical conductivity |
url | https://www.mdpi.com/2079-4991/14/6/526 |
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