Synthesized PANI/CeO<sub>2</sub> Nanocomposite Films for Enhanced Anti-Corrosion Performance

This study introduces a novel nanocomposite coating composed of PANI/CeO<sub>2</sub> nanocomposite films, aimed at addressing corrosion protection needs. Analysis through FTIR spectra and XRD patterns confirms the successful formation of the nanocomposite films. Notably, the PANI/CeO<...

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Main Authors: Ahmad M. Alsaad, Mohannad Al-Hmoud, Taha M. Rababah, Mohammad W. Marashdeh, Mamduh J. Aljaafreh, Sharif Abu Alrub, Ayed Binzowaimil, Ahmad Telfah
Format: Article
Language:English
Published: MDPI AG 2024-03-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/14/6/526
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author Ahmad M. Alsaad
Mohannad Al-Hmoud
Taha M. Rababah
Mohammad W. Marashdeh
Mamduh J. Aljaafreh
Sharif Abu Alrub
Ayed Binzowaimil
Ahmad Telfah
author_facet Ahmad M. Alsaad
Mohannad Al-Hmoud
Taha M. Rababah
Mohammad W. Marashdeh
Mamduh J. Aljaafreh
Sharif Abu Alrub
Ayed Binzowaimil
Ahmad Telfah
author_sort Ahmad M. Alsaad
collection DOAJ
description This study introduces a novel nanocomposite coating composed of PANI/CeO<sub>2</sub> nanocomposite films, aimed at addressing corrosion protection needs. Analysis through FTIR spectra and XRD patterns confirms the successful formation of the nanocomposite films. Notably, the PANI/CeO<sub>2</sub> nanocomposite films exhibit a hydrophilic nature. The bandgap energy of the PANI composite film is measured to be 3.74 eV, while the introduction of CeO<sub>2</sub> NPs into the PANI matrix reduces the bandgap energy to 3.67 eV. Furthermore, the electrical conductivity of the PANI composite film is observed to be 0.40 S·cm<sup>−1</sup>, with the incorporation of CeO<sub>2</sub> NPs leading to an increase in electrical conductivity to 1.07 S·cm<sup>−1</sup>. To evaluate its efficacy, electrochemical measurements were conducted to assess the corrosion protection performance. Results indicate a high protection efficiency of 92.25% for the PANI/CeO<sub>2</sub> nanocomposite film.
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spelling doaj.art-1795a81d494c4afd8e0b4d83cfc2c96f2024-03-27T13:57:36ZengMDPI AGNanomaterials2079-49912024-03-0114652610.3390/nano14060526Synthesized PANI/CeO<sub>2</sub> Nanocomposite Films for Enhanced Anti-Corrosion PerformanceAhmad M. Alsaad0Mohannad Al-Hmoud1Taha M. Rababah2Mohammad W. Marashdeh3Mamduh J. Aljaafreh4Sharif Abu Alrub5Ayed Binzowaimil6Ahmad Telfah7Department of Physics, Jordan University of Science and Technology, P.O. Box 3030, Irbid 22110, JordanDepartment of Physics, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), P.O. Box 90950, Riyadh 11623, Saudi ArabiaDepartment of Nutrition and Food Technology, Faculty of Agriculture, Jordan University of Science and Technology, P.O. Box 3030, Irbid 22110, JordanDepartment of Physics, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), P.O. Box 90950, Riyadh 11623, Saudi ArabiaDepartment of Physics, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), P.O. Box 90950, Riyadh 11623, Saudi ArabiaDepartment of Physics, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), P.O. Box 90950, Riyadh 11623, Saudi ArabiaDepartment of Physics, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), P.O. Box 90950, Riyadh 11623, Saudi ArabiaDepartment of Physics, University of Nebraska at Omaha, Omaha, NE 68182, USAThis study introduces a novel nanocomposite coating composed of PANI/CeO<sub>2</sub> nanocomposite films, aimed at addressing corrosion protection needs. Analysis through FTIR spectra and XRD patterns confirms the successful formation of the nanocomposite films. Notably, the PANI/CeO<sub>2</sub> nanocomposite films exhibit a hydrophilic nature. The bandgap energy of the PANI composite film is measured to be 3.74 eV, while the introduction of CeO<sub>2</sub> NPs into the PANI matrix reduces the bandgap energy to 3.67 eV. Furthermore, the electrical conductivity of the PANI composite film is observed to be 0.40 S·cm<sup>−1</sup>, with the incorporation of CeO<sub>2</sub> NPs leading to an increase in electrical conductivity to 1.07 S·cm<sup>−1</sup>. To evaluate its efficacy, electrochemical measurements were conducted to assess the corrosion protection performance. Results indicate a high protection efficiency of 92.25% for the PANI/CeO<sub>2</sub> nanocomposite film.https://www.mdpi.com/2079-4991/14/6/526corrosion protectionprotonated polyaniline (PANI)cerium dioxide (CeO<sub>2</sub>)optical bandgap energyelectrical conductivity
spellingShingle Ahmad M. Alsaad
Mohannad Al-Hmoud
Taha M. Rababah
Mohammad W. Marashdeh
Mamduh J. Aljaafreh
Sharif Abu Alrub
Ayed Binzowaimil
Ahmad Telfah
Synthesized PANI/CeO<sub>2</sub> Nanocomposite Films for Enhanced Anti-Corrosion Performance
Nanomaterials
corrosion protection
protonated polyaniline (PANI)
cerium dioxide (CeO<sub>2</sub>)
optical bandgap energy
electrical conductivity
title Synthesized PANI/CeO<sub>2</sub> Nanocomposite Films for Enhanced Anti-Corrosion Performance
title_full Synthesized PANI/CeO<sub>2</sub> Nanocomposite Films for Enhanced Anti-Corrosion Performance
title_fullStr Synthesized PANI/CeO<sub>2</sub> Nanocomposite Films for Enhanced Anti-Corrosion Performance
title_full_unstemmed Synthesized PANI/CeO<sub>2</sub> Nanocomposite Films for Enhanced Anti-Corrosion Performance
title_short Synthesized PANI/CeO<sub>2</sub> Nanocomposite Films for Enhanced Anti-Corrosion Performance
title_sort synthesized pani ceo sub 2 sub nanocomposite films for enhanced anti corrosion performance
topic corrosion protection
protonated polyaniline (PANI)
cerium dioxide (CeO<sub>2</sub>)
optical bandgap energy
electrical conductivity
url https://www.mdpi.com/2079-4991/14/6/526
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