Evaluation of Nitrogen Oxide Reduction Performance in Permeable Concrete Surfaces Treated with a TiO<sub>2</sub> Photocatalyst

Fine dust, recently classified as a carcinogen, has raised concerns about the health effects of air pollution. Vehicle emissions, particularly nitrogen oxide (NO<sub>x</sub>), contribute to ultrafine dust formation as a fine dust precursor. A photocatalyst, such as titanium dioxide (TiO&...

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Main Authors: Hyeok-jung Kim, Kinam Hong
Format: Article
Language:English
Published: MDPI AG 2023-08-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/16/16/5512
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author Hyeok-jung Kim
Kinam Hong
author_facet Hyeok-jung Kim
Kinam Hong
author_sort Hyeok-jung Kim
collection DOAJ
description Fine dust, recently classified as a carcinogen, has raised concerns about the health effects of air pollution. Vehicle emissions, particularly nitrogen oxide (NO<sub>x</sub>), contribute to ultrafine dust formation as a fine dust precursor. A photocatalyst, such as titanium dioxide (TiO<sub>2</sub>), is a material that causes a catalytic reaction when exposed to light, has exceptional characteristics such as decomposition of pollutants, and can be used permanently. This study aimed to investigate NO<sub>x</sub> reduction performance by developing ecofriendly permeable concrete with photocatalytic treatment to reduce fine dust generated from road mobile pollution sources. Permeable concrete specimens containing an activated loess and zeolite admixture were prepared and subjected to mechanical and durability tests. All specimens, including the control (CTRL) and admixture, met quality standard SPS-F-KSPIC-001-2006 for road pavement. Slip resistance and permeability coefficient also satisfied the standards, while freeze–thaw evaluation criteria were met only by CTRL and A1Z1 specimens. NO<sub>x</sub> reduction performance of the permeable concrete treated with TiO<sub>2</sub> photocatalyst was assessed using ISO standard and tank chambers. NO<sub>x</sub> reduction efficiency of up to 77.5% was confirmed in the permeable concrete specimen with TiO<sub>2</sub> content of 7.5%. Nitrate concentration measurements indirectly confirmed photolysis of nitrogen oxide. Incorporating TiO<sub>2</sub> in construction materials such as roads and sidewalks can improve the atmospheric environment for pedestrians near roads by reducing NO<sub>x</sub> levels through photocatalysis.
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spelling doaj.art-17999cc97f9c4db3bbf8596b80f2f6f22023-11-19T01:58:33ZengMDPI AGMaterials1996-19442023-08-011616551210.3390/ma16165512Evaluation of Nitrogen Oxide Reduction Performance in Permeable Concrete Surfaces Treated with a TiO<sub>2</sub> PhotocatalystHyeok-jung Kim0Kinam Hong1Industry Academic Cooperation Foundation, Hankyong National University, 327 Jangang-ro, Anseong 17579, Republic of KoreaDepartment of Civil Engineering, Chungbuk National University, 1 Chungdae-ro, Seowon-Gu, Cheongju 28644, Republic of KoreaFine dust, recently classified as a carcinogen, has raised concerns about the health effects of air pollution. Vehicle emissions, particularly nitrogen oxide (NO<sub>x</sub>), contribute to ultrafine dust formation as a fine dust precursor. A photocatalyst, such as titanium dioxide (TiO<sub>2</sub>), is a material that causes a catalytic reaction when exposed to light, has exceptional characteristics such as decomposition of pollutants, and can be used permanently. This study aimed to investigate NO<sub>x</sub> reduction performance by developing ecofriendly permeable concrete with photocatalytic treatment to reduce fine dust generated from road mobile pollution sources. Permeable concrete specimens containing an activated loess and zeolite admixture were prepared and subjected to mechanical and durability tests. All specimens, including the control (CTRL) and admixture, met quality standard SPS-F-KSPIC-001-2006 for road pavement. Slip resistance and permeability coefficient also satisfied the standards, while freeze–thaw evaluation criteria were met only by CTRL and A1Z1 specimens. NO<sub>x</sub> reduction performance of the permeable concrete treated with TiO<sub>2</sub> photocatalyst was assessed using ISO standard and tank chambers. NO<sub>x</sub> reduction efficiency of up to 77.5% was confirmed in the permeable concrete specimen with TiO<sub>2</sub> content of 7.5%. Nitrate concentration measurements indirectly confirmed photolysis of nitrogen oxide. Incorporating TiO<sub>2</sub> in construction materials such as roads and sidewalks can improve the atmospheric environment for pedestrians near roads by reducing NO<sub>x</sub> levels through photocatalysis.https://www.mdpi.com/1996-1944/16/16/5512ecofriendly permeable concretephotocatalysisfine dust precursorair pollutant degradationnitrate
spellingShingle Hyeok-jung Kim
Kinam Hong
Evaluation of Nitrogen Oxide Reduction Performance in Permeable Concrete Surfaces Treated with a TiO<sub>2</sub> Photocatalyst
Materials
ecofriendly permeable concrete
photocatalysis
fine dust precursor
air pollutant degradation
nitrate
title Evaluation of Nitrogen Oxide Reduction Performance in Permeable Concrete Surfaces Treated with a TiO<sub>2</sub> Photocatalyst
title_full Evaluation of Nitrogen Oxide Reduction Performance in Permeable Concrete Surfaces Treated with a TiO<sub>2</sub> Photocatalyst
title_fullStr Evaluation of Nitrogen Oxide Reduction Performance in Permeable Concrete Surfaces Treated with a TiO<sub>2</sub> Photocatalyst
title_full_unstemmed Evaluation of Nitrogen Oxide Reduction Performance in Permeable Concrete Surfaces Treated with a TiO<sub>2</sub> Photocatalyst
title_short Evaluation of Nitrogen Oxide Reduction Performance in Permeable Concrete Surfaces Treated with a TiO<sub>2</sub> Photocatalyst
title_sort evaluation of nitrogen oxide reduction performance in permeable concrete surfaces treated with a tio sub 2 sub photocatalyst
topic ecofriendly permeable concrete
photocatalysis
fine dust precursor
air pollutant degradation
nitrate
url https://www.mdpi.com/1996-1944/16/16/5512
work_keys_str_mv AT hyeokjungkim evaluationofnitrogenoxidereductionperformanceinpermeableconcretesurfacestreatedwithatiosub2subphotocatalyst
AT kinamhong evaluationofnitrogenoxidereductionperformanceinpermeableconcretesurfacestreatedwithatiosub2subphotocatalyst