Hydrogen-Bonding Interactions in Luminescent Quinoline-Triazoles with Dominant 1D Crystals

Quinoline-triazoles 2-((4-(diethoxymethyl)-1H-1,2,3-triazol-1-yl)methyl)quinoline (1), 2-((4-(m-tolyl)-1H-1,2,3-triazol-1-yl)methyl)quinoline (2) and 2-((4-(p-tolyl)-1H-1,2,3-triazol-1-yl)methyl)quinoline (3) have been prepared with CuAAC click reactions and used as a model series to probe the relat...

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Main Authors: Shi-Qiang Bai, David James Young, T. S. Andy Hor
Format: Article
Language:English
Published: MDPI AG 2017-09-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/22/10/1600
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author Shi-Qiang Bai
David James Young
T. S. Andy Hor
author_facet Shi-Qiang Bai
David James Young
T. S. Andy Hor
author_sort Shi-Qiang Bai
collection DOAJ
description Quinoline-triazoles 2-((4-(diethoxymethyl)-1H-1,2,3-triazol-1-yl)methyl)quinoline (1), 2-((4-(m-tolyl)-1H-1,2,3-triazol-1-yl)methyl)quinoline (2) and 2-((4-(p-tolyl)-1H-1,2,3-triazol-1-yl)methyl)quinoline (3) have been prepared with CuAAC click reactions and used as a model series to probe the relationship between lattice H-bonding interaction and crystal direction of growth. Crystals of 1–3 are 1D tape and prism shapes that correlate with their intermolecular and solvent 1D lattice H-bonding interactions. All compounds were thermally stable up to about 200 C and blue-green emissive in solution.
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spelling doaj.art-17c70114af9b4f628a53197c796386ee2022-12-22T02:20:56ZengMDPI AGMolecules1420-30492017-09-012210160010.3390/molecules22101600molecules22101600Hydrogen-Bonding Interactions in Luminescent Quinoline-Triazoles with Dominant 1D CrystalsShi-Qiang Bai0David James Young1T. S. Andy Hor2Institute of Materials Research and Engineering, ASTAR (Agency for Science, Technology and Research), 2 Fusionopolis Way, #08-03, Innovis, Singapore 138634, SingaporeInstitute of Materials Research and Engineering, ASTAR (Agency for Science, Technology and Research), 2 Fusionopolis Way, #08-03, Innovis, Singapore 138634, SingaporeDepartment of Chemistry, The University of Hong Kong, Pokfulam, Hong Kong, ChinaQuinoline-triazoles 2-((4-(diethoxymethyl)-1H-1,2,3-triazol-1-yl)methyl)quinoline (1), 2-((4-(m-tolyl)-1H-1,2,3-triazol-1-yl)methyl)quinoline (2) and 2-((4-(p-tolyl)-1H-1,2,3-triazol-1-yl)methyl)quinoline (3) have been prepared with CuAAC click reactions and used as a model series to probe the relationship between lattice H-bonding interaction and crystal direction of growth. Crystals of 1–3 are 1D tape and prism shapes that correlate with their intermolecular and solvent 1D lattice H-bonding interactions. All compounds were thermally stable up to about 200 C and blue-green emissive in solution.https://www.mdpi.com/1420-3049/22/10/1600structural relationshipH-bondingcrystal growth1,2,3-triazoleluminescence
spellingShingle Shi-Qiang Bai
David James Young
T. S. Andy Hor
Hydrogen-Bonding Interactions in Luminescent Quinoline-Triazoles with Dominant 1D Crystals
Molecules
structural relationship
H-bonding
crystal growth
1,2,3-triazole
luminescence
title Hydrogen-Bonding Interactions in Luminescent Quinoline-Triazoles with Dominant 1D Crystals
title_full Hydrogen-Bonding Interactions in Luminescent Quinoline-Triazoles with Dominant 1D Crystals
title_fullStr Hydrogen-Bonding Interactions in Luminescent Quinoline-Triazoles with Dominant 1D Crystals
title_full_unstemmed Hydrogen-Bonding Interactions in Luminescent Quinoline-Triazoles with Dominant 1D Crystals
title_short Hydrogen-Bonding Interactions in Luminescent Quinoline-Triazoles with Dominant 1D Crystals
title_sort hydrogen bonding interactions in luminescent quinoline triazoles with dominant 1d crystals
topic structural relationship
H-bonding
crystal growth
1,2,3-triazole
luminescence
url https://www.mdpi.com/1420-3049/22/10/1600
work_keys_str_mv AT shiqiangbai hydrogenbondinginteractionsinluminescentquinolinetriazoleswithdominant1dcrystals
AT davidjamesyoung hydrogenbondinginteractionsinluminescentquinolinetriazoleswithdominant1dcrystals
AT tsandyhor hydrogenbondinginteractionsinluminescentquinolinetriazoleswithdominant1dcrystals