Hydrogen-Bonding Interactions in Luminescent Quinoline-Triazoles with Dominant 1D Crystals
Quinoline-triazoles 2-((4-(diethoxymethyl)-1H-1,2,3-triazol-1-yl)methyl)quinoline (1), 2-((4-(m-tolyl)-1H-1,2,3-triazol-1-yl)methyl)quinoline (2) and 2-((4-(p-tolyl)-1H-1,2,3-triazol-1-yl)methyl)quinoline (3) have been prepared with CuAAC click reactions and used as a model series to probe the relat...
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MDPI AG
2017-09-01
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Online Access: | https://www.mdpi.com/1420-3049/22/10/1600 |
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author | Shi-Qiang Bai David James Young T. S. Andy Hor |
author_facet | Shi-Qiang Bai David James Young T. S. Andy Hor |
author_sort | Shi-Qiang Bai |
collection | DOAJ |
description | Quinoline-triazoles 2-((4-(diethoxymethyl)-1H-1,2,3-triazol-1-yl)methyl)quinoline (1), 2-((4-(m-tolyl)-1H-1,2,3-triazol-1-yl)methyl)quinoline (2) and 2-((4-(p-tolyl)-1H-1,2,3-triazol-1-yl)methyl)quinoline (3) have been prepared with CuAAC click reactions and used as a model series to probe the relationship between lattice H-bonding interaction and crystal direction of growth. Crystals of 1–3 are 1D tape and prism shapes that correlate with their intermolecular and solvent 1D lattice H-bonding interactions. All compounds were thermally stable up to about 200 C and blue-green emissive in solution. |
first_indexed | 2024-04-14T01:13:49Z |
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institution | Directory Open Access Journal |
issn | 1420-3049 |
language | English |
last_indexed | 2024-04-14T01:13:49Z |
publishDate | 2017-09-01 |
publisher | MDPI AG |
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series | Molecules |
spelling | doaj.art-17c70114af9b4f628a53197c796386ee2022-12-22T02:20:56ZengMDPI AGMolecules1420-30492017-09-012210160010.3390/molecules22101600molecules22101600Hydrogen-Bonding Interactions in Luminescent Quinoline-Triazoles with Dominant 1D CrystalsShi-Qiang Bai0David James Young1T. S. Andy Hor2Institute of Materials Research and Engineering, ASTAR (Agency for Science, Technology and Research), 2 Fusionopolis Way, #08-03, Innovis, Singapore 138634, SingaporeInstitute of Materials Research and Engineering, ASTAR (Agency for Science, Technology and Research), 2 Fusionopolis Way, #08-03, Innovis, Singapore 138634, SingaporeDepartment of Chemistry, The University of Hong Kong, Pokfulam, Hong Kong, ChinaQuinoline-triazoles 2-((4-(diethoxymethyl)-1H-1,2,3-triazol-1-yl)methyl)quinoline (1), 2-((4-(m-tolyl)-1H-1,2,3-triazol-1-yl)methyl)quinoline (2) and 2-((4-(p-tolyl)-1H-1,2,3-triazol-1-yl)methyl)quinoline (3) have been prepared with CuAAC click reactions and used as a model series to probe the relationship between lattice H-bonding interaction and crystal direction of growth. Crystals of 1–3 are 1D tape and prism shapes that correlate with their intermolecular and solvent 1D lattice H-bonding interactions. All compounds were thermally stable up to about 200 C and blue-green emissive in solution.https://www.mdpi.com/1420-3049/22/10/1600structural relationshipH-bondingcrystal growth1,2,3-triazoleluminescence |
spellingShingle | Shi-Qiang Bai David James Young T. S. Andy Hor Hydrogen-Bonding Interactions in Luminescent Quinoline-Triazoles with Dominant 1D Crystals Molecules structural relationship H-bonding crystal growth 1,2,3-triazole luminescence |
title | Hydrogen-Bonding Interactions in Luminescent Quinoline-Triazoles with Dominant 1D Crystals |
title_full | Hydrogen-Bonding Interactions in Luminescent Quinoline-Triazoles with Dominant 1D Crystals |
title_fullStr | Hydrogen-Bonding Interactions in Luminescent Quinoline-Triazoles with Dominant 1D Crystals |
title_full_unstemmed | Hydrogen-Bonding Interactions in Luminescent Quinoline-Triazoles with Dominant 1D Crystals |
title_short | Hydrogen-Bonding Interactions in Luminescent Quinoline-Triazoles with Dominant 1D Crystals |
title_sort | hydrogen bonding interactions in luminescent quinoline triazoles with dominant 1d crystals |
topic | structural relationship H-bonding crystal growth 1,2,3-triazole luminescence |
url | https://www.mdpi.com/1420-3049/22/10/1600 |
work_keys_str_mv | AT shiqiangbai hydrogenbondinginteractionsinluminescentquinolinetriazoleswithdominant1dcrystals AT davidjamesyoung hydrogenbondinginteractionsinluminescentquinolinetriazoleswithdominant1dcrystals AT tsandyhor hydrogenbondinginteractionsinluminescentquinolinetriazoleswithdominant1dcrystals |