Performance and Durability of the Zr-Doped CaO Sorbent under Cyclic Carbonation–Decarbonation at Different Operating Parameters
The effect of cyclic carbonation–decarbonation operating parameters on Zr-doped CaO sorbent CO<sub>2</sub> uptake capacity evolution is examined. It is revealed that the capacity steady state value increases with the decrease in the carbonation temperature, CO<sub>2</sub> con...
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| Format: | Article |
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MDPI AG
2021-08-01
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| Series: | Energies |
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| Online Access: | https://www.mdpi.com/1996-1073/14/16/4822 |
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| author | Vyacheslav V. Rodaev Svetlana S. Razlivalova |
| author_facet | Vyacheslav V. Rodaev Svetlana S. Razlivalova |
| author_sort | Vyacheslav V. Rodaev |
| collection | DOAJ |
| description | The effect of cyclic carbonation–decarbonation operating parameters on Zr-doped CaO sorbent CO<sub>2</sub> uptake capacity evolution is examined. It is revealed that the capacity steady state value increases with the decrease in the carbonation temperature, CO<sub>2</sub> concentration in the gas flow upon carbonation and with the increase in the heating rate from the carbonation to the decarbonation stages. The rise in decarbonation temperature leads to a dramatic decrease in the sorbent performance. It is found that if carbonation occurs at 630 °C in the gas flow containing 15 vol.% CO<sub>2</sub> and decarbonation is carried out at 742 °C, the sorbent shows the highest values of the initial and steady state CO<sub>2</sub> uptake capacity, namely, 10.7 mmol/g and 9.4 mmol/g, respectively. |
| first_indexed | 2024-03-10T08:51:19Z |
| format | Article |
| id | doaj.art-17c91eed833b44488342642749b13a16 |
| institution | Directory Open Access Journal |
| issn | 1996-1073 |
| language | English |
| last_indexed | 2024-03-10T08:51:19Z |
| publishDate | 2021-08-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Energies |
| spelling | doaj.art-17c91eed833b44488342642749b13a162023-11-22T07:27:56ZengMDPI AGEnergies1996-10732021-08-011416482210.3390/en14164822Performance and Durability of the Zr-Doped CaO Sorbent under Cyclic Carbonation–Decarbonation at Different Operating ParametersVyacheslav V. Rodaev0Svetlana S. Razlivalova1Institute for Nanotechnology and Nanomaterials, Derzhavin Tambov State University, Internatsionalnaya Str. 33, 392000 Tambov, RussiaInstitute for Nanotechnology and Nanomaterials, Derzhavin Tambov State University, Internatsionalnaya Str. 33, 392000 Tambov, RussiaThe effect of cyclic carbonation–decarbonation operating parameters on Zr-doped CaO sorbent CO<sub>2</sub> uptake capacity evolution is examined. It is revealed that the capacity steady state value increases with the decrease in the carbonation temperature, CO<sub>2</sub> concentration in the gas flow upon carbonation and with the increase in the heating rate from the carbonation to the decarbonation stages. The rise in decarbonation temperature leads to a dramatic decrease in the sorbent performance. It is found that if carbonation occurs at 630 °C in the gas flow containing 15 vol.% CO<sub>2</sub> and decarbonation is carried out at 742 °C, the sorbent shows the highest values of the initial and steady state CO<sub>2</sub> uptake capacity, namely, 10.7 mmol/g and 9.4 mmol/g, respectively.https://www.mdpi.com/1996-1073/14/16/4822CaO-based sorbenthigh-energy millingCO<sub>2</sub> capturecyclic carbonation–decarbonationsorbent sintering |
| spellingShingle | Vyacheslav V. Rodaev Svetlana S. Razlivalova Performance and Durability of the Zr-Doped CaO Sorbent under Cyclic Carbonation–Decarbonation at Different Operating Parameters Energies CaO-based sorbent high-energy milling CO<sub>2</sub> capture cyclic carbonation–decarbonation sorbent sintering |
| title | Performance and Durability of the Zr-Doped CaO Sorbent under Cyclic Carbonation–Decarbonation at Different Operating Parameters |
| title_full | Performance and Durability of the Zr-Doped CaO Sorbent under Cyclic Carbonation–Decarbonation at Different Operating Parameters |
| title_fullStr | Performance and Durability of the Zr-Doped CaO Sorbent under Cyclic Carbonation–Decarbonation at Different Operating Parameters |
| title_full_unstemmed | Performance and Durability of the Zr-Doped CaO Sorbent under Cyclic Carbonation–Decarbonation at Different Operating Parameters |
| title_short | Performance and Durability of the Zr-Doped CaO Sorbent under Cyclic Carbonation–Decarbonation at Different Operating Parameters |
| title_sort | performance and durability of the zr doped cao sorbent under cyclic carbonation decarbonation at different operating parameters |
| topic | CaO-based sorbent high-energy milling CO<sub>2</sub> capture cyclic carbonation–decarbonation sorbent sintering |
| url | https://www.mdpi.com/1996-1073/14/16/4822 |
| work_keys_str_mv | AT vyacheslavvrodaev performanceanddurabilityofthezrdopedcaosorbentundercycliccarbonationdecarbonationatdifferentoperatingparameters AT svetlanasrazlivalova performanceanddurabilityofthezrdopedcaosorbentundercycliccarbonationdecarbonationatdifferentoperatingparameters |