Diaquabis(4-bromobenzoato-κO)bis(N,N′-diethylnicotinamide-κN1)zinc(II)
The title compound, [Zn(C7H4BrO2)2(C10H14N2O)2(H2O)2], is a monomeric complex with the ZnII atom lying on an inversion center. It contains two 4-bromobenzoate, two diethylnicotinamide ligands and two water molecules, all of which are monodentate. The four O atoms in the equatorial plane around the Z...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808027074 |
| _version_ | 1818083309935132672 |
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| author | Hacali Necefoğlu Fureya Elif Özbek Tuncer Hökelek Aslı Öztürk |
| author_facet | Hacali Necefoğlu Fureya Elif Özbek Tuncer Hökelek Aslı Öztürk |
| author_sort | Hacali Necefoğlu |
| collection | DOAJ |
| description | The title compound, [Zn(C7H4BrO2)2(C10H14N2O)2(H2O)2], is a monomeric complex with the ZnII atom lying on an inversion center. It contains two 4-bromobenzoate, two diethylnicotinamide ligands and two water molecules, all of which are monodentate. The four O atoms in the equatorial plane around the Zn atom form a slightly distorted square-planar arrangement, while the distorted octahedral geometry is completed by two N atoms in the axial positions. The methyl group of one of the ethyl groups is disordered over two positions, with occupancies of ca 0.65 and 0.35. The two aromatic rings are oriented at an angle of 77.22 (14)°. In the crystal structure, O—H...O hydrogen bonds link the molecules into chains along the a axis. |
| first_indexed | 2024-12-10T19:35:57Z |
| format | Article |
| id | doaj.art-17f3a9d50caa42ffa0dcb6cb98e4d523 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T19:35:57Z |
| publishDate | 2008-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-17f3a9d50caa42ffa0dcb6cb98e4d5232022-12-22T01:36:08ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-09-01649m1218m121910.1107/S1600536808027074Diaquabis(4-bromobenzoato-κO)bis(N,N′-diethylnicotinamide-κN1)zinc(II)Hacali NecefoğluFureya Elif ÖzbekTuncer HökelekAslı ÖztürkThe title compound, [Zn(C7H4BrO2)2(C10H14N2O)2(H2O)2], is a monomeric complex with the ZnII atom lying on an inversion center. It contains two 4-bromobenzoate, two diethylnicotinamide ligands and two water molecules, all of which are monodentate. The four O atoms in the equatorial plane around the Zn atom form a slightly distorted square-planar arrangement, while the distorted octahedral geometry is completed by two N atoms in the axial positions. The methyl group of one of the ethyl groups is disordered over two positions, with occupancies of ca 0.65 and 0.35. The two aromatic rings are oriented at an angle of 77.22 (14)°. In the crystal structure, O—H...O hydrogen bonds link the molecules into chains along the a axis.http://scripts.iucr.org/cgi-bin/paper?S1600536808027074 |
| spellingShingle | Hacali Necefoğlu Fureya Elif Özbek Tuncer Hökelek Aslı Öztürk Diaquabis(4-bromobenzoato-κO)bis(N,N′-diethylnicotinamide-κN1)zinc(II) Acta Crystallographica Section E |
| title | Diaquabis(4-bromobenzoato-κO)bis(N,N′-diethylnicotinamide-κN1)zinc(II) |
| title_full | Diaquabis(4-bromobenzoato-κO)bis(N,N′-diethylnicotinamide-κN1)zinc(II) |
| title_fullStr | Diaquabis(4-bromobenzoato-κO)bis(N,N′-diethylnicotinamide-κN1)zinc(II) |
| title_full_unstemmed | Diaquabis(4-bromobenzoato-κO)bis(N,N′-diethylnicotinamide-κN1)zinc(II) |
| title_short | Diaquabis(4-bromobenzoato-κO)bis(N,N′-diethylnicotinamide-κN1)zinc(II) |
| title_sort | diaquabis 4 bromobenzoato 954 o bis n n 8242 diethylnicotinamide 954 n1 zinc ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808027074 |
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