Study on Leather Modified with Nitrogen-Phosphorus Intumescent Flame Retardant in Fat Liquoring Process
Adding flame retardant into leather is an effective way to improve the flame resistance of leather products. In this paper, a Nitrogen-Phosphorus Intumescent (NPI) flame retardant was synthesized and then added to the fatliquoring process to modify leather. The effect of NPI flame retardant on the f...
Main Authors: | , , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
2021-04-01
|
Series: | Iranian Journal of Chemistry & Chemical Engineering |
Subjects: | |
Online Access: | http://www.ijcce.ac.ir/article_242814_4bf5def2a895f76efec5a3572c102ec0.pdf |
_version_ | 1818892792569528320 |
---|---|
author | Baorong Duan Quanjie Wang Xue Wang Qiyan Wang Pengfei Ren Shen Diao Haoyu Yin |
author_facet | Baorong Duan Quanjie Wang Xue Wang Qiyan Wang Pengfei Ren Shen Diao Haoyu Yin |
author_sort | Baorong Duan |
collection | DOAJ |
description | Adding flame retardant into leather is an effective way to improve the flame resistance of leather products. In this paper, a Nitrogen-Phosphorus Intumescent (NPI) flame retardant was synthesized and then added to the fatliquoring process to modify leather. The effect of NPI flame retardant on the flame-retardant properties of leather was investigated using Limiting Oxygen Index (LOI), smoke density, vertical combustion, cone calorimeter tests, and SEM. The results revealed that LOI of leather modified with NPI flame retardant increased with the increase of flame retardant. The flame and flameless combustion time of the modified leather was effectively reduced. Compared with unmodified leather, HRR of the modified leather with 6% NPI flame retardant decreased from 80.32 MJ/m2 to 63.45 MJ/m2; the peak HRR dropped from 108.71 MJ/m2 to 77.23 MJ/m2. Moreover, the fire growth index of the modified leather with 6% NPI flame retardant is close to half of that of the unmodified sample. The results certified the enhancing effect of NPI flame retardant added in the fatliquoring process on flame retardancy of leather samples. |
first_indexed | 2024-12-19T18:02:20Z |
format | Article |
id | doaj.art-1830dba32eca4c6f828dc7cd05c28212 |
institution | Directory Open Access Journal |
issn | 1021-9986 1021-9986 |
language | English |
last_indexed | 2024-12-19T18:02:20Z |
publishDate | 2021-04-01 |
publisher | Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR |
record_format | Article |
series | Iranian Journal of Chemistry & Chemical Engineering |
spelling | doaj.art-1830dba32eca4c6f828dc7cd05c282122022-12-21T20:11:34ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering1021-99861021-99862021-04-0140268368910.30492/ijcce.2021.522673.4511242814Study on Leather Modified with Nitrogen-Phosphorus Intumescent Flame Retardant in Fat Liquoring ProcessBaorong Duan0Quanjie Wang1Xue Wang2Qiyan Wang3Pengfei Ren4Shen Diao5Haoyu Yin6Leather and Protein Laboratory, College of Chemistry and Chemical Engineering, Yantai University, Yantai 264005, P.R. CHINALeather and Protein Laboratory, College of Chemistry and Chemical Engineering, Yantai University, Yantai 264005, P.R. CHINALeather and Protein Laboratory, College of Chemistry and Chemical Engineering, Yantai University, Yantai 264005, P.R. CHINALeather and Protein Laboratory, College of Chemistry and Chemical Engineering, Yantai University, Yantai 264005, P.R. CHINALeather and Protein Laboratory, College of Chemistry and Chemical Engineering, Yantai University, Yantai 264005, P.R. CHINALeather and Protein Laboratory, College of Chemistry and Chemical Engineering, Yantai University, Yantai 264005, P.R. CHINAChina (Yantai) Intellectual Property Protection Center,Shandong Yantai, 264005, P.R. CHINAAdding flame retardant into leather is an effective way to improve the flame resistance of leather products. In this paper, a Nitrogen-Phosphorus Intumescent (NPI) flame retardant was synthesized and then added to the fatliquoring process to modify leather. The effect of NPI flame retardant on the flame-retardant properties of leather was investigated using Limiting Oxygen Index (LOI), smoke density, vertical combustion, cone calorimeter tests, and SEM. The results revealed that LOI of leather modified with NPI flame retardant increased with the increase of flame retardant. The flame and flameless combustion time of the modified leather was effectively reduced. Compared with unmodified leather, HRR of the modified leather with 6% NPI flame retardant decreased from 80.32 MJ/m2 to 63.45 MJ/m2; the peak HRR dropped from 108.71 MJ/m2 to 77.23 MJ/m2. Moreover, the fire growth index of the modified leather with 6% NPI flame retardant is close to half of that of the unmodified sample. The results certified the enhancing effect of NPI flame retardant added in the fatliquoring process on flame retardancy of leather samples.http://www.ijcce.ac.ir/article_242814_4bf5def2a895f76efec5a3572c102ec0.pdfleather modifiednitrogen-phosphorusfatliquoring processflame resistance |
spellingShingle | Baorong Duan Quanjie Wang Xue Wang Qiyan Wang Pengfei Ren Shen Diao Haoyu Yin Study on Leather Modified with Nitrogen-Phosphorus Intumescent Flame Retardant in Fat Liquoring Process Iranian Journal of Chemistry & Chemical Engineering leather modified nitrogen-phosphorus fatliquoring process flame resistance |
title | Study on Leather Modified with Nitrogen-Phosphorus Intumescent Flame Retardant in Fat Liquoring Process |
title_full | Study on Leather Modified with Nitrogen-Phosphorus Intumescent Flame Retardant in Fat Liquoring Process |
title_fullStr | Study on Leather Modified with Nitrogen-Phosphorus Intumescent Flame Retardant in Fat Liquoring Process |
title_full_unstemmed | Study on Leather Modified with Nitrogen-Phosphorus Intumescent Flame Retardant in Fat Liquoring Process |
title_short | Study on Leather Modified with Nitrogen-Phosphorus Intumescent Flame Retardant in Fat Liquoring Process |
title_sort | study on leather modified with nitrogen phosphorus intumescent flame retardant in fat liquoring process |
topic | leather modified nitrogen-phosphorus fatliquoring process flame resistance |
url | http://www.ijcce.ac.ir/article_242814_4bf5def2a895f76efec5a3572c102ec0.pdf |
work_keys_str_mv | AT baorongduan studyonleathermodifiedwithnitrogenphosphorusintumescentflameretardantinfatliquoringprocess AT quanjiewang studyonleathermodifiedwithnitrogenphosphorusintumescentflameretardantinfatliquoringprocess AT xuewang studyonleathermodifiedwithnitrogenphosphorusintumescentflameretardantinfatliquoringprocess AT qiyanwang studyonleathermodifiedwithnitrogenphosphorusintumescentflameretardantinfatliquoringprocess AT pengfeiren studyonleathermodifiedwithnitrogenphosphorusintumescentflameretardantinfatliquoringprocess AT shendiao studyonleathermodifiedwithnitrogenphosphorusintumescentflameretardantinfatliquoringprocess AT haoyuyin studyonleathermodifiedwithnitrogenphosphorusintumescentflameretardantinfatliquoringprocess |