Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems
This work highlights unexpected, not so well known responses of ionic liquids and ionic liquid-containing systems, which are reported in a collective manner, as a short review. Examples include: (i) Minima in the temperature dependence of the isobaric thermal expansion coefficient of some ILs; (ii)...
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| Format: | Article |
| Language: | English |
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Frontiers Media S.A.
2019-06-01
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| Series: | Frontiers in Chemistry |
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| Online Access: | https://www.frontiersin.org/article/10.3389/fchem.2019.00450/full |
| _version_ | 1811324780020760576 |
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| author | José M. S. S. Esperança Mohammad Tariq Ana B. Pereiro João M. M. Araújo Kenneth R. Seddon Luis Paulo N. Rebelo |
| author_facet | José M. S. S. Esperança Mohammad Tariq Ana B. Pereiro João M. M. Araújo Kenneth R. Seddon Luis Paulo N. Rebelo |
| author_sort | José M. S. S. Esperança |
| collection | DOAJ |
| description | This work highlights unexpected, not so well known responses of ionic liquids and ionic liquid-containing systems, which are reported in a collective manner, as a short review. Examples include: (i) Minima in the temperature dependence of the isobaric thermal expansion coefficient of some ILs; (ii) Viscosity Minima in binary mixtures of IL + Molecular solvents; (iii) Anomalies in the surface tension within a family of ILs; (iv) The constancy among IL substitution of Cp/Vm at and around room temperature; (v) ILs as glass forming liquids; (vi) Alternate odd-even side alkyl chain length effects; (vii) Absolute negative pressures in ILs and IL-containing systems; (viii) Reversed-charged ionic liquid pairs; (ix) LCST immiscibility behavior in IL + solvent systems. |
| first_indexed | 2024-04-13T14:20:30Z |
| format | Article |
| id | doaj.art-184d756cd68d4562a6124964d1a9d13f |
| institution | Directory Open Access Journal |
| issn | 2296-2646 |
| language | English |
| last_indexed | 2024-04-13T14:20:30Z |
| publishDate | 2019-06-01 |
| publisher | Frontiers Media S.A. |
| record_format | Article |
| series | Frontiers in Chemistry |
| spelling | doaj.art-184d756cd68d4562a6124964d1a9d13f2022-12-22T02:43:28ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462019-06-01710.3389/fchem.2019.00450454415Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing SystemsJosé M. S. S. Esperança0Mohammad Tariq1Ana B. Pereiro2João M. M. Araújo3Kenneth R. Seddon4Luis Paulo N. Rebelo5LAQV/REQUIMTE, Faculdade de Ciências e Tecnologia da Universidade Nova de Lisboa, Caparica, PortugalLAQV/REQUIMTE, Faculdade de Ciências e Tecnologia da Universidade Nova de Lisboa, Caparica, PortugalLAQV/REQUIMTE, Faculdade de Ciências e Tecnologia da Universidade Nova de Lisboa, Caparica, PortugalLAQV/REQUIMTE, Faculdade de Ciências e Tecnologia da Universidade Nova de Lisboa, Caparica, PortugalQUILL Research Centre, the Queen's University of Belfast, Belfast, United KingdomLAQV/REQUIMTE, Faculdade de Ciências e Tecnologia da Universidade Nova de Lisboa, Caparica, PortugalThis work highlights unexpected, not so well known responses of ionic liquids and ionic liquid-containing systems, which are reported in a collective manner, as a short review. Examples include: (i) Minima in the temperature dependence of the isobaric thermal expansion coefficient of some ILs; (ii) Viscosity Minima in binary mixtures of IL + Molecular solvents; (iii) Anomalies in the surface tension within a family of ILs; (iv) The constancy among IL substitution of Cp/Vm at and around room temperature; (v) ILs as glass forming liquids; (vi) Alternate odd-even side alkyl chain length effects; (vii) Absolute negative pressures in ILs and IL-containing systems; (viii) Reversed-charged ionic liquid pairs; (ix) LCST immiscibility behavior in IL + solvent systems.https://www.frontiersin.org/article/10.3389/fchem.2019.00450/fullionic liquidsunusual behaviorthermal expansion coefficientviscositysurface tensionodd-even effects |
| spellingShingle | José M. S. S. Esperança Mohammad Tariq Ana B. Pereiro João M. M. Araújo Kenneth R. Seddon Luis Paulo N. Rebelo Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems Frontiers in Chemistry ionic liquids unusual behavior thermal expansion coefficient viscosity surface tension odd-even effects |
| title | Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems |
| title_full | Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems |
| title_fullStr | Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems |
| title_full_unstemmed | Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems |
| title_short | Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems |
| title_sort | anomalous and not so common behavior in common ionic liquids and ionic liquid containing systems |
| topic | ionic liquids unusual behavior thermal expansion coefficient viscosity surface tension odd-even effects |
| url | https://www.frontiersin.org/article/10.3389/fchem.2019.00450/full |
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