Temperature Effect on the Surface Properties of ZnO(am)
The point of zero charge and surface acidity constants of zinc oxide were determined over the temperature range 293–323 K. Both the point of zero charge (pzc) and the surface acidity constants (pK a1 and pK a2 ) were found to decrease with increasing temperature. The values of the dissociation const...
Main Authors: | , , , |
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Format: | Article |
Language: | English |
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SAGE Publications
1997-11-01
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Series: | Adsorption Science & Technology |
Online Access: | https://doi.org/10.1177/026361749701501005 |
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author | S. Mustafa Shahida Parveen Aftab Ahmad Dilara Begum |
author_facet | S. Mustafa Shahida Parveen Aftab Ahmad Dilara Begum |
author_sort | S. Mustafa |
collection | DOAJ |
description | The point of zero charge and surface acidity constants of zinc oxide were determined over the temperature range 293–323 K. Both the point of zero charge (pzc) and the surface acidity constants (pK a1 and pK a2 ) were found to decrease with increasing temperature. The values of the dissociation constants (pK a1 and pK a2 ) determined from the Henderson-Hasselbach equation agreed very well with those determined using the Gaines-Thomas equation. The thermodynamic parameters ΔH 0 and ΔS 0 for the processes were also evaluated. |
first_indexed | 2024-03-07T17:37:42Z |
format | Article |
id | doaj.art-1850f1c9111440ca944db7a49df66007 |
institution | Directory Open Access Journal |
issn | 0263-6174 2048-4038 |
language | English |
last_indexed | 2024-03-07T17:37:42Z |
publishDate | 1997-11-01 |
publisher | SAGE Publications |
record_format | Article |
series | Adsorption Science & Technology |
spelling | doaj.art-1850f1c9111440ca944db7a49df660072024-03-02T16:23:57ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40381997-11-011510.1177/026361749701501005Temperature Effect on the Surface Properties of ZnO(am)S. MustafaShahida ParveenAftab AhmadDilara BegumThe point of zero charge and surface acidity constants of zinc oxide were determined over the temperature range 293–323 K. Both the point of zero charge (pzc) and the surface acidity constants (pK a1 and pK a2 ) were found to decrease with increasing temperature. The values of the dissociation constants (pK a1 and pK a2 ) determined from the Henderson-Hasselbach equation agreed very well with those determined using the Gaines-Thomas equation. The thermodynamic parameters ΔH 0 and ΔS 0 for the processes were also evaluated.https://doi.org/10.1177/026361749701501005 |
spellingShingle | S. Mustafa Shahida Parveen Aftab Ahmad Dilara Begum Temperature Effect on the Surface Properties of ZnO(am) Adsorption Science & Technology |
title | Temperature Effect on the Surface Properties of ZnO(am) |
title_full | Temperature Effect on the Surface Properties of ZnO(am) |
title_fullStr | Temperature Effect on the Surface Properties of ZnO(am) |
title_full_unstemmed | Temperature Effect on the Surface Properties of ZnO(am) |
title_short | Temperature Effect on the Surface Properties of ZnO(am) |
title_sort | temperature effect on the surface properties of zno am |
url | https://doi.org/10.1177/026361749701501005 |
work_keys_str_mv | AT smustafa temperatureeffectonthesurfacepropertiesofznoam AT shahidaparveen temperatureeffectonthesurfacepropertiesofznoam AT aftabahmad temperatureeffectonthesurfacepropertiesofznoam AT dilarabegum temperatureeffectonthesurfacepropertiesofznoam |