Temperature Effect on the Surface Properties of ZnO(am)

The point of zero charge and surface acidity constants of zinc oxide were determined over the temperature range 293–323 K. Both the point of zero charge (pzc) and the surface acidity constants (pK a1 and pK a2 ) were found to decrease with increasing temperature. The values of the dissociation const...

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Main Authors: S. Mustafa, Shahida Parveen, Aftab Ahmad, Dilara Begum
Format: Article
Language:English
Published: SAGE Publications 1997-11-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1177/026361749701501005
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author S. Mustafa
Shahida Parveen
Aftab Ahmad
Dilara Begum
author_facet S. Mustafa
Shahida Parveen
Aftab Ahmad
Dilara Begum
author_sort S. Mustafa
collection DOAJ
description The point of zero charge and surface acidity constants of zinc oxide were determined over the temperature range 293–323 K. Both the point of zero charge (pzc) and the surface acidity constants (pK a1 and pK a2 ) were found to decrease with increasing temperature. The values of the dissociation constants (pK a1 and pK a2 ) determined from the Henderson-Hasselbach equation agreed very well with those determined using the Gaines-Thomas equation. The thermodynamic parameters ΔH 0 and ΔS 0 for the processes were also evaluated.
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spelling doaj.art-1850f1c9111440ca944db7a49df660072024-03-02T16:23:57ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40381997-11-011510.1177/026361749701501005Temperature Effect on the Surface Properties of ZnO(am)S. MustafaShahida ParveenAftab AhmadDilara BegumThe point of zero charge and surface acidity constants of zinc oxide were determined over the temperature range 293–323 K. Both the point of zero charge (pzc) and the surface acidity constants (pK a1 and pK a2 ) were found to decrease with increasing temperature. The values of the dissociation constants (pK a1 and pK a2 ) determined from the Henderson-Hasselbach equation agreed very well with those determined using the Gaines-Thomas equation. The thermodynamic parameters ΔH 0 and ΔS 0 for the processes were also evaluated.https://doi.org/10.1177/026361749701501005
spellingShingle S. Mustafa
Shahida Parveen
Aftab Ahmad
Dilara Begum
Temperature Effect on the Surface Properties of ZnO(am)
Adsorption Science & Technology
title Temperature Effect on the Surface Properties of ZnO(am)
title_full Temperature Effect on the Surface Properties of ZnO(am)
title_fullStr Temperature Effect on the Surface Properties of ZnO(am)
title_full_unstemmed Temperature Effect on the Surface Properties of ZnO(am)
title_short Temperature Effect on the Surface Properties of ZnO(am)
title_sort temperature effect on the surface properties of zno am
url https://doi.org/10.1177/026361749701501005
work_keys_str_mv AT smustafa temperatureeffectonthesurfacepropertiesofznoam
AT shahidaparveen temperatureeffectonthesurfacepropertiesofznoam
AT aftabahmad temperatureeffectonthesurfacepropertiesofznoam
AT dilarabegum temperatureeffectonthesurfacepropertiesofznoam