Desalination Using the Capacitive Deionization Technology with Graphite/AC Electrodes: Effect of the Flow Rate and Electrode Thickness

Capacitive deionization (CDI) is an emerging water desalination technology whose principle lies in ion electrosorption at the surface of a pair of electrically charged electrodes. The aim of this study was to obtain the best performance of a CDI cell made of activated carbon as the active material f...

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Main Authors: Jhonatan Martinez, Martín Colán, Ronald Catillón, Jesús Huamán, Robert Paria, Luis Sánchez, Juan M. Rodríguez
Format: Article
Language:English
Published: MDPI AG 2022-07-01
Series:Membranes
Subjects:
Online Access:https://www.mdpi.com/2077-0375/12/7/717
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author Jhonatan Martinez
Martín Colán
Ronald Catillón
Jesús Huamán
Robert Paria
Luis Sánchez
Juan M. Rodríguez
author_facet Jhonatan Martinez
Martín Colán
Ronald Catillón
Jesús Huamán
Robert Paria
Luis Sánchez
Juan M. Rodríguez
author_sort Jhonatan Martinez
collection DOAJ
description Capacitive deionization (CDI) is an emerging water desalination technology whose principle lies in ion electrosorption at the surface of a pair of electrically charged electrodes. The aim of this study was to obtain the best performance of a CDI cell made of activated carbon as the active material for water desalination. In this work, electrodes of different active layer thicknesses were fabricated from a slurry of activated carbon deposited on graphite sheets. The as-prepared electrodes were characterized by cyclic voltammetry, and their physical properties were also studied using SEM and DRX. A CDI cell was fabricated with nine pairs of electrodes with the highest specific capacitance. The effect of the flow rate on the electrochemical performance of the CDI cell operating in charge–discharge electrochemical cycling was analyzed. We obtained a specific absorption capacity (SAC) of 10.2 mg/g and a specific energetic consumption (SEC) of 217.8 Wh/m<sup>3</sup> at a flow rate of 55 mL/min. These results were contrasted with those available in the literature; in addition, other parameters such as Neff and SAR, which are necessary for the characterization and optimal operating conditions of the CDI cell, were analyzed. The findings from this study lay the groundwork for future research and increase the existing knowledge on CDI based on activated carbon electrodes.
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spelling doaj.art-18a788bae2ed46a399aa5d46cdd7f47e2023-11-30T21:26:20ZengMDPI AGMembranes2077-03752022-07-0112771710.3390/membranes12070717Desalination Using the Capacitive Deionization Technology with Graphite/AC Electrodes: Effect of the Flow Rate and Electrode ThicknessJhonatan Martinez0Martín Colán1Ronald Catillón2Jesús Huamán3Robert Paria4Luis Sánchez5Juan M. Rodríguez6Center for the Development of Advanced Materials and Nanotechnology, Universidad Nacional de Ingeniería, Av. Túpac Amaru 210, Lima 15333, PeruCenter for the Development of Advanced Materials and Nanotechnology, Universidad Nacional de Ingeniería, Av. Túpac Amaru 210, Lima 15333, PeruCenter for the Development of Advanced Materials and Nanotechnology, Universidad Nacional de Ingeniería, Av. Túpac Amaru 210, Lima 15333, PeruCenter for the Development of Advanced Materials and Nanotechnology, Universidad Nacional de Ingeniería, Av. Túpac Amaru 210, Lima 15333, PeruCenter for the Development of Advanced Materials and Nanotechnology, Universidad Nacional de Ingeniería, Av. Túpac Amaru 210, Lima 15333, PeruCenter for the Development of Advanced Materials and Nanotechnology, Universidad Nacional de Ingeniería, Av. Túpac Amaru 210, Lima 15333, PeruCenter for the Development of Advanced Materials and Nanotechnology, Universidad Nacional de Ingeniería, Av. Túpac Amaru 210, Lima 15333, PeruCapacitive deionization (CDI) is an emerging water desalination technology whose principle lies in ion electrosorption at the surface of a pair of electrically charged electrodes. The aim of this study was to obtain the best performance of a CDI cell made of activated carbon as the active material for water desalination. In this work, electrodes of different active layer thicknesses were fabricated from a slurry of activated carbon deposited on graphite sheets. The as-prepared electrodes were characterized by cyclic voltammetry, and their physical properties were also studied using SEM and DRX. A CDI cell was fabricated with nine pairs of electrodes with the highest specific capacitance. The effect of the flow rate on the electrochemical performance of the CDI cell operating in charge–discharge electrochemical cycling was analyzed. We obtained a specific absorption capacity (SAC) of 10.2 mg/g and a specific energetic consumption (SEC) of 217.8 Wh/m<sup>3</sup> at a flow rate of 55 mL/min. These results were contrasted with those available in the literature; in addition, other parameters such as Neff and SAR, which are necessary for the characterization and optimal operating conditions of the CDI cell, were analyzed. The findings from this study lay the groundwork for future research and increase the existing knowledge on CDI based on activated carbon electrodes.https://www.mdpi.com/2077-0375/12/7/717activated carboncapacitive deionizationCDIwater desalinizationgraphite electrodesporous materials
spellingShingle Jhonatan Martinez
Martín Colán
Ronald Catillón
Jesús Huamán
Robert Paria
Luis Sánchez
Juan M. Rodríguez
Desalination Using the Capacitive Deionization Technology with Graphite/AC Electrodes: Effect of the Flow Rate and Electrode Thickness
Membranes
activated carbon
capacitive deionization
CDI
water desalinization
graphite electrodes
porous materials
title Desalination Using the Capacitive Deionization Technology with Graphite/AC Electrodes: Effect of the Flow Rate and Electrode Thickness
title_full Desalination Using the Capacitive Deionization Technology with Graphite/AC Electrodes: Effect of the Flow Rate and Electrode Thickness
title_fullStr Desalination Using the Capacitive Deionization Technology with Graphite/AC Electrodes: Effect of the Flow Rate and Electrode Thickness
title_full_unstemmed Desalination Using the Capacitive Deionization Technology with Graphite/AC Electrodes: Effect of the Flow Rate and Electrode Thickness
title_short Desalination Using the Capacitive Deionization Technology with Graphite/AC Electrodes: Effect of the Flow Rate and Electrode Thickness
title_sort desalination using the capacitive deionization technology with graphite ac electrodes effect of the flow rate and electrode thickness
topic activated carbon
capacitive deionization
CDI
water desalinization
graphite electrodes
porous materials
url https://www.mdpi.com/2077-0375/12/7/717
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