(±)-N-(3-Hydroxy-1,2-diphenylpropyl)-4-methylbenzenesulfonamide

In the title compound, C22H23NO3S, the relative stereochemistry of the two stereogenic centres is anti with respect to the H atoms. The molecular packing of the crystal shows a double-strand arrangement, consisting of one strand of (S*,S*) enantiomers and one strand of (R*,R*) enantiomers. Both stra...

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Bibliographic Details
Main Authors: Margaret A. Brimble, Peter D. W. Boyd, Ka Wai Choi, David Barker, Sok Teng Tong
Format: Article
Language:English
Published: International Union of Crystallography 2008-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808028948
Description
Summary:In the title compound, C22H23NO3S, the relative stereochemistry of the two stereogenic centres is anti with respect to the H atoms. The molecular packing of the crystal shows a double-strand arrangement, consisting of one strand of (S*,S*) enantiomers and one strand of (R*,R*) enantiomers. Both strands lie parallel to each other along the a axis. Each strand is made up of dimers in which the molecules are connected to each other via an intermolecular O—H...O hydrogen bond between the hydroxyl groups and an O—H...π interaction with the aromatic ring. These units are then connected to neighbouring dimers via N—H...O hydrogen bonds and C—H...O interactions. Intramolecular C—H...O interactions are also observed.
ISSN:1600-5368