Factors Influencing Degradation of Mercaptans by Thiobacillus thioparus TK-m (1)

Degradation of methylmercaptans by Thiobacillus thioparus TK-m was influenced by pH of the reaction medium. Ratios of headspace concentrations in empty vials and those of acidified buffer solutions were less than 1.0. 95% of the H2S was in headspace with the remaining 5% in solution upon acidificati...

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Main Author: A Adoki
Format: Article
Language:English
Published: Joint Coordination Centre of the World Bank assisted National Agricultural Research Programme (NARP) 2010-06-01
Series:Journal of Applied Sciences and Environmental Management
Online Access:https://www.ajol.info/index.php/jasem/article/view/55083
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author A Adoki
author_facet A Adoki
author_sort A Adoki
collection DOAJ
description Degradation of methylmercaptans by Thiobacillus thioparus TK-m was influenced by pH of the reaction medium. Ratios of headspace concentrations in empty vials and those of acidified buffer solutions were less than 1.0. 95% of the H2S was in headspace with the remaining 5% in solution upon acidification. The values for MM were 80% in headspace and 20% in solution. Different buffer solutions also influence the rate of removal of mercaptans from reaction vessels. For methylmercaptan oxidase, using Tris/HCl buffer, the highest level of oxygen uptake was recorded at pH 8.5. Mild changes in the pH levels were recorded at the end of the reactions. Compared to Tris/HCl buffer, phosphate buffer supports a significantly lower reactivity of MMoxidase towards methylmercaptan
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spelling doaj.art-18fbd5f25f62469887b76cd7a4846c8f2024-04-02T19:54:24ZengJoint Coordination Centre of the World Bank assisted National Agricultural Research Programme (NARP)Journal of Applied Sciences and Environmental Management2659-15022659-14992010-06-0111310.4314/jasem.v11i3.55083Factors Influencing Degradation of Mercaptans by Thiobacillus thioparus TK-m (1)A AdokiDegradation of methylmercaptans by Thiobacillus thioparus TK-m was influenced by pH of the reaction medium. Ratios of headspace concentrations in empty vials and those of acidified buffer solutions were less than 1.0. 95% of the H2S was in headspace with the remaining 5% in solution upon acidification. The values for MM were 80% in headspace and 20% in solution. Different buffer solutions also influence the rate of removal of mercaptans from reaction vessels. For methylmercaptan oxidase, using Tris/HCl buffer, the highest level of oxygen uptake was recorded at pH 8.5. Mild changes in the pH levels were recorded at the end of the reactions. Compared to Tris/HCl buffer, phosphate buffer supports a significantly lower reactivity of MMoxidase towards methylmercaptanhttps://www.ajol.info/index.php/jasem/article/view/55083
spellingShingle A Adoki
Factors Influencing Degradation of Mercaptans by Thiobacillus thioparus TK-m (1)
Journal of Applied Sciences and Environmental Management
title Factors Influencing Degradation of Mercaptans by Thiobacillus thioparus TK-m (1)
title_full Factors Influencing Degradation of Mercaptans by Thiobacillus thioparus TK-m (1)
title_fullStr Factors Influencing Degradation of Mercaptans by Thiobacillus thioparus TK-m (1)
title_full_unstemmed Factors Influencing Degradation of Mercaptans by Thiobacillus thioparus TK-m (1)
title_short Factors Influencing Degradation of Mercaptans by Thiobacillus thioparus TK-m (1)
title_sort factors influencing degradation of mercaptans by thiobacillus thioparus tk m 1
url https://www.ajol.info/index.php/jasem/article/view/55083
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