Synthesis of composite thin-film polymer consisting of tungsten and zinc oxide as hydrogen gas detector

A composite polymer consisting of polyaniline (PANI) was synthesised via oxidative polymerisation by varying concentrations of transitional metal oxides and the presence of a hydrogen dissociation catalyst, palladium (Pd). The metal oxides chosen for this study were tungsten oxide (WO3) and zinc oxi...

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Main Authors: Alister G. Willis, Haron Saharudin
Format: Article
Language:English
Published: EDP Sciences 2019-01-01
Series:E3S Web of Conferences
Online Access:https://www.e3s-conferences.org/articles/e3sconf/pdf/2019/16/e3sconf_concept2019_01008.pdf
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author Alister G. Willis
Haron Saharudin
author_facet Alister G. Willis
Haron Saharudin
author_sort Alister G. Willis
collection DOAJ
description A composite polymer consisting of polyaniline (PANI) was synthesised via oxidative polymerisation by varying concentrations of transitional metal oxides and the presence of a hydrogen dissociation catalyst, palladium (Pd). The metal oxides chosen for this study were tungsten oxide (WO3) and zinc oxide (ZnO). The composite polymer samples were characterised using Fourier transform infrared (FTIR) spectroscopy where ultraviolet-visible (UV-Vis) spectroscopy was used to observe the optical changes of the thin films due to exposure to hydrogen. The FTIR spectra obtained confirmed the synthesis of PANI composite. Based on the UV-VIS analysis, PANI-ZnO composite polymer showed the highest difference in peak intensity before and after exposure to hydrogen with 11.4% difference.
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spelling doaj.art-19046cc05b5d482a8f0acc255250802d2022-12-21T22:57:18ZengEDP SciencesE3S Web of Conferences2267-12422019-01-01900100810.1051/e3sconf/20199001008e3sconf_concept2019_01008Synthesis of composite thin-film polymer consisting of tungsten and zinc oxide as hydrogen gas detectorAlister G. WillisHaron Saharudin0Centre of Hydrogen Economy, Institute of Future Energy, Universiti Teknologi MalaysiaA composite polymer consisting of polyaniline (PANI) was synthesised via oxidative polymerisation by varying concentrations of transitional metal oxides and the presence of a hydrogen dissociation catalyst, palladium (Pd). The metal oxides chosen for this study were tungsten oxide (WO3) and zinc oxide (ZnO). The composite polymer samples were characterised using Fourier transform infrared (FTIR) spectroscopy where ultraviolet-visible (UV-Vis) spectroscopy was used to observe the optical changes of the thin films due to exposure to hydrogen. The FTIR spectra obtained confirmed the synthesis of PANI composite. Based on the UV-VIS analysis, PANI-ZnO composite polymer showed the highest difference in peak intensity before and after exposure to hydrogen with 11.4% difference.https://www.e3s-conferences.org/articles/e3sconf/pdf/2019/16/e3sconf_concept2019_01008.pdf
spellingShingle Alister G. Willis
Haron Saharudin
Synthesis of composite thin-film polymer consisting of tungsten and zinc oxide as hydrogen gas detector
E3S Web of Conferences
title Synthesis of composite thin-film polymer consisting of tungsten and zinc oxide as hydrogen gas detector
title_full Synthesis of composite thin-film polymer consisting of tungsten and zinc oxide as hydrogen gas detector
title_fullStr Synthesis of composite thin-film polymer consisting of tungsten and zinc oxide as hydrogen gas detector
title_full_unstemmed Synthesis of composite thin-film polymer consisting of tungsten and zinc oxide as hydrogen gas detector
title_short Synthesis of composite thin-film polymer consisting of tungsten and zinc oxide as hydrogen gas detector
title_sort synthesis of composite thin film polymer consisting of tungsten and zinc oxide as hydrogen gas detector
url https://www.e3s-conferences.org/articles/e3sconf/pdf/2019/16/e3sconf_concept2019_01008.pdf
work_keys_str_mv AT alistergwillis synthesisofcompositethinfilmpolymerconsistingoftungstenandzincoxideashydrogengasdetector
AT haronsaharudin synthesisofcompositethinfilmpolymerconsistingoftungstenandzincoxideashydrogengasdetector