Age-hardenability and related microstructural changes during and after phase transformation in an Au-Ag-Cu-based dental alloy

The aim of this study was to clarify how the microstructural changes during and after phase transformation determine the age-hardenability of an Au-Ag-Cu-based dental alloy. The rapid increase in hardness in the initial stage was the result of rapid atomic diffusion by spinodal decomposition into me...

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Main Authors: Hyung-Il Kim, Tae-Wan Kim, Young-Oh Kim, Su-Yeon Cho, Gwang-Young Lee, Yong Hoon Kwon, Hyo-Joung Seol
Format: Article
Language:English
Published: Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) 2013-02-01
Series:Materials Research
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392013000100009
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author Hyung-Il Kim
Tae-Wan Kim
Young-Oh Kim
Su-Yeon Cho
Gwang-Young Lee
Yong Hoon Kwon
Hyo-Joung Seol
author_facet Hyung-Il Kim
Tae-Wan Kim
Young-Oh Kim
Su-Yeon Cho
Gwang-Young Lee
Yong Hoon Kwon
Hyo-Joung Seol
author_sort Hyung-Il Kim
collection DOAJ
description The aim of this study was to clarify how the microstructural changes during and after phase transformation determine the age-hardenability of an Au-Ag-Cu-based dental alloy. The rapid increase in hardness in the initial stage was the result of rapid atomic diffusion by spinodal decomposition into metastable Ag-rich' and Cu-rich' phases. The constant hardening after apparent initial hardening was the result of a subsequent transformation of the metastable Ag-rich' and Cu-rich' phases to the stable Ag-rich α1phase and AuCu I phase through the metastable AuCu I' phase. During the increase in hardness, fine block-like structure with high coherency formed in the grain interior, which changed to a fine cross-hatched structure. A relatively coarse lamellar structure composed of Ag-rich α1and AuCu I phases grew from the grain boundaries, initiating softening before the grain interior reached its maximum hardness. As a result, the spinodal decomposition attributed to rapid hardening by forming the fine block-like structure, and the subsequent ordering into AuCu I, which is a famous hardening mechanism, weakened its hardening effect by accelerating the lamellar-forming grain boundary reaction.
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spelling doaj.art-19079ebe8794424aab61c63885f8b8662022-12-22T01:18:15ZengAssociação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)Materials Research1516-14392013-02-011617187Age-hardenability and related microstructural changes during and after phase transformation in an Au-Ag-Cu-based dental alloyHyung-Il KimTae-Wan KimYoung-Oh KimSu-Yeon ChoGwang-Young LeeYong Hoon KwonHyo-Joung SeolThe aim of this study was to clarify how the microstructural changes during and after phase transformation determine the age-hardenability of an Au-Ag-Cu-based dental alloy. The rapid increase in hardness in the initial stage was the result of rapid atomic diffusion by spinodal decomposition into metastable Ag-rich' and Cu-rich' phases. The constant hardening after apparent initial hardening was the result of a subsequent transformation of the metastable Ag-rich' and Cu-rich' phases to the stable Ag-rich α1phase and AuCu I phase through the metastable AuCu I' phase. During the increase in hardness, fine block-like structure with high coherency formed in the grain interior, which changed to a fine cross-hatched structure. A relatively coarse lamellar structure composed of Ag-rich α1and AuCu I phases grew from the grain boundaries, initiating softening before the grain interior reached its maximum hardness. As a result, the spinodal decomposition attributed to rapid hardening by forming the fine block-like structure, and the subsequent ordering into AuCu I, which is a famous hardening mechanism, weakened its hardening effect by accelerating the lamellar-forming grain boundary reaction.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392013000100009spinodal decompositionmetastable phaseage-hardeninglamellar-forming grain boundary reaction
spellingShingle Hyung-Il Kim
Tae-Wan Kim
Young-Oh Kim
Su-Yeon Cho
Gwang-Young Lee
Yong Hoon Kwon
Hyo-Joung Seol
Age-hardenability and related microstructural changes during and after phase transformation in an Au-Ag-Cu-based dental alloy
Materials Research
spinodal decomposition
metastable phase
age-hardening
lamellar-forming grain boundary reaction
title Age-hardenability and related microstructural changes during and after phase transformation in an Au-Ag-Cu-based dental alloy
title_full Age-hardenability and related microstructural changes during and after phase transformation in an Au-Ag-Cu-based dental alloy
title_fullStr Age-hardenability and related microstructural changes during and after phase transformation in an Au-Ag-Cu-based dental alloy
title_full_unstemmed Age-hardenability and related microstructural changes during and after phase transformation in an Au-Ag-Cu-based dental alloy
title_short Age-hardenability and related microstructural changes during and after phase transformation in an Au-Ag-Cu-based dental alloy
title_sort age hardenability and related microstructural changes during and after phase transformation in an au ag cu based dental alloy
topic spinodal decomposition
metastable phase
age-hardening
lamellar-forming grain boundary reaction
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392013000100009
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