A Novel Energy-from-Waste Approach for Electrical Energy Production by Galvano–Fenton Process

A novel approach allowing the production of electrical energy by an advanced oxidation process is proposed to eliminate organic micropollutants (MPs) in wastewaters. This approach is based on associating the Galvano–Fenton process to the generation of electrical power. In the previous studies descri...

Full description

Bibliographic Details
Main Authors: Intissar Gasmi, Naoufel Haddour, Oualid Hamdaoui, Kaouther Kerboua, Abdulaziz Alghyamah, François Buret
Format: Article
Language:English
Published: MDPI AG 2021-06-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/26/13/4013
_version_ 1827688342254256128
author Intissar Gasmi
Naoufel Haddour
Oualid Hamdaoui
Kaouther Kerboua
Abdulaziz Alghyamah
François Buret
author_facet Intissar Gasmi
Naoufel Haddour
Oualid Hamdaoui
Kaouther Kerboua
Abdulaziz Alghyamah
François Buret
author_sort Intissar Gasmi
collection DOAJ
description A novel approach allowing the production of electrical energy by an advanced oxidation process is proposed to eliminate organic micropollutants (MPs) in wastewaters. This approach is based on associating the Galvano–Fenton process to the generation of electrical power. In the previous studies describing the Galvano–Fenton (GF) process, iron was directly coupled to a metal of more positive potential to ensure degradation of organic pollutants without any possibility of producing electrical energy. In this new approach, the Galvano–Fenton process is constructed as an electrochemical cell with an external circuit allowing recovering electrons exchanged during the process. In this study, Malachite Green (MG) dye was used as a model of organic pollutant. Simultaneous MG degradation and electrical energy production with the GF method were investigated in batch process. The investigation of various design parameters emphasis that utilization of copper as a low-cost cathode material in the galvanic couple, provides the best treatment and electrical production performances. Moreover, these performances are improved by increasing the surface area of the cathode. The present work reveals that the GF process has a potential to provide an electrical power density of about 200 W m<sup>−2</sup>. These interesting performances indicate that this novel Energy-from-Waste strategy of the GF process could serve as an ecological solution for wastewater treatment.
first_indexed 2024-03-10T09:53:28Z
format Article
id doaj.art-192c188ee4554864b9b98b4881162548
institution Directory Open Access Journal
issn 1420-3049
language English
last_indexed 2024-03-10T09:53:28Z
publishDate 2021-06-01
publisher MDPI AG
record_format Article
series Molecules
spelling doaj.art-192c188ee4554864b9b98b48811625482023-11-22T02:31:07ZengMDPI AGMolecules1420-30492021-06-012613401310.3390/molecules26134013A Novel Energy-from-Waste Approach for Electrical Energy Production by Galvano–Fenton ProcessIntissar Gasmi0Naoufel Haddour1Oualid Hamdaoui2Kaouther Kerboua3Abdulaziz Alghyamah4François Buret5Laboratoire Ampère, École Centrale de Lyon, 36 Avenue Guy de Collongue, 69134 Ecully, FranceLaboratoire Ampère, École Centrale de Lyon, 36 Avenue Guy de Collongue, 69134 Ecully, FranceLaboratory of Environmental Engineering, Process Engineering Department, Faculty of Engineering, Badji Mokhtar-Annaba University, P.O. Box 12, Annaba 23000, AlgeriaLaboratory of Environmental Engineering, Process Engineering Department, Faculty of Engineering, Badji Mokhtar-Annaba University, P.O. Box 12, Annaba 23000, AlgeriaChemical Engineering Department, College of Engineering, King Saud University, P.O. Box 800, Riyadh 11421, Saudi ArabiaLaboratoire Ampère, École Centrale de Lyon, 36 Avenue Guy de Collongue, 69134 Ecully, FranceA novel approach allowing the production of electrical energy by an advanced oxidation process is proposed to eliminate organic micropollutants (MPs) in wastewaters. This approach is based on associating the Galvano–Fenton process to the generation of electrical power. In the previous studies describing the Galvano–Fenton (GF) process, iron was directly coupled to a metal of more positive potential to ensure degradation of organic pollutants without any possibility of producing electrical energy. In this new approach, the Galvano–Fenton process is constructed as an electrochemical cell with an external circuit allowing recovering electrons exchanged during the process. In this study, Malachite Green (MG) dye was used as a model of organic pollutant. Simultaneous MG degradation and electrical energy production with the GF method were investigated in batch process. The investigation of various design parameters emphasis that utilization of copper as a low-cost cathode material in the galvanic couple, provides the best treatment and electrical production performances. Moreover, these performances are improved by increasing the surface area of the cathode. The present work reveals that the GF process has a potential to provide an electrical power density of about 200 W m<sup>−2</sup>. These interesting performances indicate that this novel Energy-from-Waste strategy of the GF process could serve as an ecological solution for wastewater treatment.https://www.mdpi.com/1420-3049/26/13/4013Galvano–Fenton processnew energy sourcesmicropollutantsferrous scrap recoveryelectrochemical wastewater treatment
spellingShingle Intissar Gasmi
Naoufel Haddour
Oualid Hamdaoui
Kaouther Kerboua
Abdulaziz Alghyamah
François Buret
A Novel Energy-from-Waste Approach for Electrical Energy Production by Galvano–Fenton Process
Molecules
Galvano–Fenton process
new energy sources
micropollutants
ferrous scrap recovery
electrochemical wastewater treatment
title A Novel Energy-from-Waste Approach for Electrical Energy Production by Galvano–Fenton Process
title_full A Novel Energy-from-Waste Approach for Electrical Energy Production by Galvano–Fenton Process
title_fullStr A Novel Energy-from-Waste Approach for Electrical Energy Production by Galvano–Fenton Process
title_full_unstemmed A Novel Energy-from-Waste Approach for Electrical Energy Production by Galvano–Fenton Process
title_short A Novel Energy-from-Waste Approach for Electrical Energy Production by Galvano–Fenton Process
title_sort novel energy from waste approach for electrical energy production by galvano fenton process
topic Galvano–Fenton process
new energy sources
micropollutants
ferrous scrap recovery
electrochemical wastewater treatment
url https://www.mdpi.com/1420-3049/26/13/4013
work_keys_str_mv AT intissargasmi anovelenergyfromwasteapproachforelectricalenergyproductionbygalvanofentonprocess
AT naoufelhaddour anovelenergyfromwasteapproachforelectricalenergyproductionbygalvanofentonprocess
AT oualidhamdaoui anovelenergyfromwasteapproachforelectricalenergyproductionbygalvanofentonprocess
AT kaoutherkerboua anovelenergyfromwasteapproachforelectricalenergyproductionbygalvanofentonprocess
AT abdulazizalghyamah anovelenergyfromwasteapproachforelectricalenergyproductionbygalvanofentonprocess
AT francoisburet anovelenergyfromwasteapproachforelectricalenergyproductionbygalvanofentonprocess
AT intissargasmi novelenergyfromwasteapproachforelectricalenergyproductionbygalvanofentonprocess
AT naoufelhaddour novelenergyfromwasteapproachforelectricalenergyproductionbygalvanofentonprocess
AT oualidhamdaoui novelenergyfromwasteapproachforelectricalenergyproductionbygalvanofentonprocess
AT kaoutherkerboua novelenergyfromwasteapproachforelectricalenergyproductionbygalvanofentonprocess
AT abdulazizalghyamah novelenergyfromwasteapproachforelectricalenergyproductionbygalvanofentonprocess
AT francoisburet novelenergyfromwasteapproachforelectricalenergyproductionbygalvanofentonprocess