I2/TBHP promoted isocyanide insertion cyclization reaction for the synthesis of quinazolin fused benzoimidazole as a selective methanol detection probe
An efficient I2/TBHP promoted isocyanide insertion cyclization reaction for the synthesis of quinazolines-fused benzoimidazole was reported. The synthesized compounds have a unique potential to use as a selective solvatochromic fluorescence probe for methanol detection from other solvents, especiall...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2021-09-01
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| Series: | Catalysis Communications |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S1566736721000546 |
| _version_ | 1818657461795553280 |
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| author | Fereshteh Ahmadi Nafiseh Ahmadi Yaser Balmohammadi Mohammad Reza Naimi-Jamal Ayoob Bazgir |
| author_facet | Fereshteh Ahmadi Nafiseh Ahmadi Yaser Balmohammadi Mohammad Reza Naimi-Jamal Ayoob Bazgir |
| author_sort | Fereshteh Ahmadi |
| collection | DOAJ |
| description | An efficient I2/TBHP promoted isocyanide insertion cyclization reaction for the synthesis of quinazolines-fused benzoimidazole was reported. The synthesized compounds have a unique potential to use as a selective solvatochromic fluorescence probe for methanol detection from other solvents, especially EtOH. Introducing a simple one-step method and using a more acceptable iodine molecule instead of expensive transition metal catalysts are the most important advantages of this strategy. |
| first_indexed | 2024-12-17T03:41:51Z |
| format | Article |
| id | doaj.art-194d19e4cad546ed9f7234872828ee11 |
| institution | Directory Open Access Journal |
| issn | 1873-3905 |
| language | English |
| last_indexed | 2024-12-17T03:41:51Z |
| publishDate | 2021-09-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Catalysis Communications |
| spelling | doaj.art-194d19e4cad546ed9f7234872828ee112022-12-21T22:04:59ZengElsevierCatalysis Communications1873-39052021-09-01157106331I2/TBHP promoted isocyanide insertion cyclization reaction for the synthesis of quinazolin fused benzoimidazole as a selective methanol detection probeFereshteh Ahmadi0Nafiseh Ahmadi1Yaser Balmohammadi2Mohammad Reza Naimi-Jamal3Ayoob Bazgir4Department of Organic Chemistry, Shahid Beheshti University, Tehran 1983963113, IranDepartment of Chemistry, Iran University of Science and Technology, 16846 Tehran, IranDepartment of Organic Chemistry, Shahid Beheshti University, Tehran 1983963113, IranDepartment of Chemistry, Iran University of Science and Technology, 16846 Tehran, Iran; Corresponding authors.Department of Organic Chemistry, Shahid Beheshti University, Tehran 1983963113, Iran; Corresponding authors.An efficient I2/TBHP promoted isocyanide insertion cyclization reaction for the synthesis of quinazolines-fused benzoimidazole was reported. The synthesized compounds have a unique potential to use as a selective solvatochromic fluorescence probe for methanol detection from other solvents, especially EtOH. Introducing a simple one-step method and using a more acceptable iodine molecule instead of expensive transition metal catalysts are the most important advantages of this strategy.http://www.sciencedirect.com/science/article/pii/S1566736721000546I2/TBHP catalystIsocyanide insertion reactionsBenzoimidazoquinazolinsMethanol detectionFluorescence probe |
| spellingShingle | Fereshteh Ahmadi Nafiseh Ahmadi Yaser Balmohammadi Mohammad Reza Naimi-Jamal Ayoob Bazgir I2/TBHP promoted isocyanide insertion cyclization reaction for the synthesis of quinazolin fused benzoimidazole as a selective methanol detection probe Catalysis Communications I2/TBHP catalyst Isocyanide insertion reactions Benzoimidazoquinazolins Methanol detection Fluorescence probe |
| title | I2/TBHP promoted isocyanide insertion cyclization reaction for the synthesis of quinazolin fused benzoimidazole as a selective methanol detection probe |
| title_full | I2/TBHP promoted isocyanide insertion cyclization reaction for the synthesis of quinazolin fused benzoimidazole as a selective methanol detection probe |
| title_fullStr | I2/TBHP promoted isocyanide insertion cyclization reaction for the synthesis of quinazolin fused benzoimidazole as a selective methanol detection probe |
| title_full_unstemmed | I2/TBHP promoted isocyanide insertion cyclization reaction for the synthesis of quinazolin fused benzoimidazole as a selective methanol detection probe |
| title_short | I2/TBHP promoted isocyanide insertion cyclization reaction for the synthesis of quinazolin fused benzoimidazole as a selective methanol detection probe |
| title_sort | i2 tbhp promoted isocyanide insertion cyclization reaction for the synthesis of quinazolin fused benzoimidazole as a selective methanol detection probe |
| topic | I2/TBHP catalyst Isocyanide insertion reactions Benzoimidazoquinazolins Methanol detection Fluorescence probe |
| url | http://www.sciencedirect.com/science/article/pii/S1566736721000546 |
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