(1S*,2S*,4R*,5R*)-Cyclohexane-1,2,4,5-tetracarboxylic acid
The title compound, C10H12O8, a prospective raw material for colourless polyimides which are applied to electronic and microelectronic devices, lies about an inversion centre and the cyclohexane ring adopts a chair conformation. Two crystallographycally independent carboxylic acid groups on adjacent...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813033795 |
| _version_ | 1818914718403788800 |
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| author | Akira Uchida Masatoshi Hasegawa Shinya Yamaguchi Eiichiro Takezawa Atsushi Ishikawa Takashi Kagayama |
| author_facet | Akira Uchida Masatoshi Hasegawa Shinya Yamaguchi Eiichiro Takezawa Atsushi Ishikawa Takashi Kagayama |
| author_sort | Akira Uchida |
| collection | DOAJ |
| description | The title compound, C10H12O8, a prospective raw material for colourless polyimides which are applied to electronic and microelectronic devices, lies about an inversion centre and the cyclohexane ring adopts a chair conformation. Two crystallographycally independent carboxylic acid groups on adjacent C atoms are in equatorial positions, resulting in a mutually trans conformation. In the crystal, O—H...O hydrogen bonds around an inversion centre and a threefold rotoinversion axis, respectively, form an inversion dimer with an R22(8) motif and a trimer with an R33(12) motif. |
| first_indexed | 2024-12-19T23:50:50Z |
| format | Article |
| id | doaj.art-195c1ecc55654d1bae8f702326e69574 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T23:50:50Z |
| publishDate | 2014-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-195c1ecc55654d1bae8f702326e695742022-12-21T20:01:09ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-01-01701o75o7510.1107/S1600536813033795is5327(1S*,2S*,4R*,5R*)-Cyclohexane-1,2,4,5-tetracarboxylic acidAkira Uchida0Masatoshi Hasegawa1Shinya Yamaguchi2Eiichiro Takezawa3Atsushi Ishikawa4Takashi Kagayama5Department of Biomolecular Science, Faculty of Science, Toho University, 2-2-1 Miyama, Funabashi, Chiba 274-8510, JapanDepartment of Chemistry, Faculty of Science, Toho University, 2-2-1 Miyama, Funabashi, Chiba 274-8510, JapanDepartment of Research and Development, Gas Chemical Division, Iwatani Industrial Gases Corporation Ltd., 10 Otakasu-cho, Amagasaki, Hyogo 660-0842, JapanDepartment of Research and Development, Gas Chemical Division, Iwatani Industrial Gases Corporation Ltd., 10 Otakasu-cho, Amagasaki, Hyogo 660-0842, JapanDepartment of Research and Development, Gas Chemical Division, Iwatani Industrial Gases Corporation Ltd., 10 Otakasu-cho, Amagasaki, Hyogo 660-0842, JapanDepartment of Research and Development, Gas Chemical Division, Iwatani Industrial Gases Corporation Ltd., 10 Otakasu-cho, Amagasaki, Hyogo 660-0842, JapanThe title compound, C10H12O8, a prospective raw material for colourless polyimides which are applied to electronic and microelectronic devices, lies about an inversion centre and the cyclohexane ring adopts a chair conformation. Two crystallographycally independent carboxylic acid groups on adjacent C atoms are in equatorial positions, resulting in a mutually trans conformation. In the crystal, O—H...O hydrogen bonds around an inversion centre and a threefold rotoinversion axis, respectively, form an inversion dimer with an R22(8) motif and a trimer with an R33(12) motif.http://scripts.iucr.org/cgi-bin/paper?S1600536813033795 |
| spellingShingle | Akira Uchida Masatoshi Hasegawa Shinya Yamaguchi Eiichiro Takezawa Atsushi Ishikawa Takashi Kagayama (1S*,2S*,4R*,5R*)-Cyclohexane-1,2,4,5-tetracarboxylic acid Acta Crystallographica Section E |
| title | (1S*,2S*,4R*,5R*)-Cyclohexane-1,2,4,5-tetracarboxylic acid |
| title_full | (1S*,2S*,4R*,5R*)-Cyclohexane-1,2,4,5-tetracarboxylic acid |
| title_fullStr | (1S*,2S*,4R*,5R*)-Cyclohexane-1,2,4,5-tetracarboxylic acid |
| title_full_unstemmed | (1S*,2S*,4R*,5R*)-Cyclohexane-1,2,4,5-tetracarboxylic acid |
| title_short | (1S*,2S*,4R*,5R*)-Cyclohexane-1,2,4,5-tetracarboxylic acid |
| title_sort | 1s 2s 4r 5r cyclohexane 1 2 4 5 tetracarboxylic acid |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813033795 |
| work_keys_str_mv | AT akirauchida 1s2s4r5rcyclohexane1245tetracarboxylicacid AT masatoshihasegawa 1s2s4r5rcyclohexane1245tetracarboxylicacid AT shinyayamaguchi 1s2s4r5rcyclohexane1245tetracarboxylicacid AT eiichirotakezawa 1s2s4r5rcyclohexane1245tetracarboxylicacid AT atsushiishikawa 1s2s4r5rcyclohexane1245tetracarboxylicacid AT takashikagayama 1s2s4r5rcyclohexane1245tetracarboxylicacid |