Millennial-scale variations in sedimentary oxygenation in the western subtropical North Pacific and its links to North Atlantic climate

<p>The deep-ocean carbon cycle, especially carbon sequestration and outgassing, is one of the mechanisms to explain variations in atmospheric <span class="inline-formula">CO<sub>2</sub></span> concentrations on millennial and orbital timescales. However, the p...

Full description

Bibliographic Details
Main Authors: J. Zou, X. Shi, A. Zhu, S. Kandasamy, X. Gong, L. Lembke-Jene, M.-T. Chen, Y. Wu, S. Ge, Y. Liu, X. Xue, G. Lohmann, R. Tiedemann
Format: Article
Language:English
Published: Copernicus Publications 2020-02-01
Series:Climate of the Past
Online Access:https://www.clim-past.net/16/387/2020/cp-16-387-2020.pdf
Description
Summary:<p>The deep-ocean carbon cycle, especially carbon sequestration and outgassing, is one of the mechanisms to explain variations in atmospheric <span class="inline-formula">CO<sub>2</sub></span> concentrations on millennial and orbital timescales. However, the potential role of subtropical North Pacific subsurface waters in modulating atmospheric <span class="inline-formula">CO<sub>2</sub></span> levels on millennial timescales is poorly constrained. An increase in the respired <span class="inline-formula">CO<sub>2</sub></span> concentration in the glacial deep-ocean due to biological pump generally corresponds to deoxygenation in the ocean interior. This link thus offers a chance to study oceanic ventilation and coeval export productivity based on redox-controlled sedimentary geochemical parameters. Here, we investigate a suite of geochemical proxies in a sediment core from the Okinawa Trough to understand sedimentary oxygenation variations in the subtropical North Pacific over the last 50&thinsp;000 years (50&thinsp;ka). Our results suggest that enhanced mid-depth western subtropical North Pacific (WSTNP) sedimentary oxygenation occurred during cold intervals and after 8.5&thinsp;ka, while oxygenation decreased during the Bölling-Alleröd (B/A) and Preboreal. The enhanced oxygenation during cold spells is linked to the North Pacific Intermediate Water (NPIW), while interglacial increase after 8.5&thinsp;ka is linked to an intensification of the Kuroshio Current due to strengthened northeast trade winds over the tropics. The enhanced formation of the NPIW during Heinrich Stadial 1 (HS1) was likely driven by the perturbation of sea ice formation and sea surface salinity oscillations in the high-latitude North Pacific. The diminished sedimentary oxygenation during the B/A due to a decreased NPIW formation and enhanced export production, indicates an expansion of the oxygen minimum zone in the North Pacific and enhanced <span class="inline-formula">CO<sub>2</sub></span> sequestration at mid-depth waters, along with the termination of atmospheric <span class="inline-formula">CO<sub>2</sub></span> concentration increase. We attribute the millennial-scale changes to an intensified NPIW and enhanced abyss flushing during deglacial cold and warm intervals, respectively, closely related to variations in North Atlantic Deep Water formation.</p>
ISSN:1814-9324
1814-9332