Tetra(chlorido/iodido)(1,10-phenanthroline)platinum(IV) hemi[di(chlorine/iodine)]
The asymmetric unit of the title compound, [PtCl3.66I0.34(C12H8N2)]·0.5(Cl0.13I1.87), contains a neutral PtIV complex and one half of a halogen molecule. The PtIV ion is six-coordinated in a distorted octahedral environment by two N atoms of the 1,10-phenanthroline ligand and Cl or I at...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-04-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809007703 |
| _version_ | 1818887131105329152 |
|---|---|
| author | Nam-Ho Kim Kwang Ha |
| author_facet | Nam-Ho Kim Kwang Ha |
| author_sort | Nam-Ho Kim |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [PtCl3.66I0.34(C12H8N2)]·0.5(Cl0.13I1.87), contains a neutral PtIV complex and one half of a halogen molecule. The PtIV ion is six-coordinated in a distorted octahedral environment by two N atoms of the 1,10-phenanthroline ligand and Cl or I atoms. The refinement of the structure and the EDX analysis indicate that the compound is a solid solution in which there is some substitution of Cl for I and vice versa. The chemical formula of the pure state of the compound would have been [PtCl4(C12H8N2)]·0.5I2. In the analysed crystal, two Cl atoms are partially (ca 25% and 9%) replaced by I atoms, and the I2 molecule has a minor component modelled as ICl. As a result of the disorder, the different trans effects of the N and Cl/I atoms are not distinct. The complex displays intermolecular π–π interactions between the six-membered rings, with a centroid–centroid distance of 3.771 (4) Å. There are also weak intramolecular C—H...Cl hydrogen bonds. |
| first_indexed | 2024-12-19T16:32:21Z |
| format | Article |
| id | doaj.art-197121f4ad4f4fd295b03c81c7926ffe |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T16:32:21Z |
| publishDate | 2009-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-197121f4ad4f4fd295b03c81c7926ffe2022-12-21T20:14:07ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-04-01654m379m37910.1107/S1600536809007703Tetra(chlorido/iodido)(1,10-phenanthroline)platinum(IV) hemi[di(chlorine/iodine)]Nam-Ho KimKwang HaThe asymmetric unit of the title compound, [PtCl3.66I0.34(C12H8N2)]·0.5(Cl0.13I1.87), contains a neutral PtIV complex and one half of a halogen molecule. The PtIV ion is six-coordinated in a distorted octahedral environment by two N atoms of the 1,10-phenanthroline ligand and Cl or I atoms. The refinement of the structure and the EDX analysis indicate that the compound is a solid solution in which there is some substitution of Cl for I and vice versa. The chemical formula of the pure state of the compound would have been [PtCl4(C12H8N2)]·0.5I2. In the analysed crystal, two Cl atoms are partially (ca 25% and 9%) replaced by I atoms, and the I2 molecule has a minor component modelled as ICl. As a result of the disorder, the different trans effects of the N and Cl/I atoms are not distinct. The complex displays intermolecular π–π interactions between the six-membered rings, with a centroid–centroid distance of 3.771 (4) Å. There are also weak intramolecular C—H...Cl hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536809007703 |
| spellingShingle | Nam-Ho Kim Kwang Ha Tetra(chlorido/iodido)(1,10-phenanthroline)platinum(IV) hemi[di(chlorine/iodine)] Acta Crystallographica Section E |
| title | Tetra(chlorido/iodido)(1,10-phenanthroline)platinum(IV) hemi[di(chlorine/iodine)] |
| title_full | Tetra(chlorido/iodido)(1,10-phenanthroline)platinum(IV) hemi[di(chlorine/iodine)] |
| title_fullStr | Tetra(chlorido/iodido)(1,10-phenanthroline)platinum(IV) hemi[di(chlorine/iodine)] |
| title_full_unstemmed | Tetra(chlorido/iodido)(1,10-phenanthroline)platinum(IV) hemi[di(chlorine/iodine)] |
| title_short | Tetra(chlorido/iodido)(1,10-phenanthroline)platinum(IV) hemi[di(chlorine/iodine)] |
| title_sort | tetra chlorido iodido 1 10 phenanthroline platinum iv hemi di chlorine iodine |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809007703 |
| work_keys_str_mv | AT namhokim tetrachloridoiodido110phenanthrolineplatinumivhemidichlorineiodine AT kwangha tetrachloridoiodido110phenanthrolineplatinumivhemidichlorineiodine |