Poly[μ3-acetato-di-μ3-isonicotinato-μ2-isonicotinato-samarium(III)silver(I)]
In the title homochiral three-dimensional heterometallic complex, [AgSm(C6H4NO2)3(C2H3O2)]n, the eight-coordinate SmIII ion displays a bicapped trigonal-prismatic geometry, being coordinated by two O atoms from one acetate ligand, four O atoms from four bridging isonicotinate ligands and two O atoms...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809048430 |
| _version_ | 1818283527944273920 |
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| author | Li-Cai Zhu |
| author_facet | Li-Cai Zhu |
| author_sort | Li-Cai Zhu |
| collection | DOAJ |
| description | In the title homochiral three-dimensional heterometallic complex, [AgSm(C6H4NO2)3(C2H3O2)]n, the eight-coordinate SmIII ion displays a bicapped trigonal-prismatic geometry, being coordinated by two O atoms from one acetate ligand, four O atoms from four bridging isonicotinate ligands and two O atoms from two terminal isonicotinate ligands. The four-coordinate AgI ion adopts a tetrahedral geometry, being bonded to two N atoms from two bridging isonicotinate ligands and two O atoms from two acetate ligands. These metal coordination units are connected by bridging isonicotinate and acetate ligands, generating a three-dimensional network. |
| first_indexed | 2024-12-13T00:38:20Z |
| format | Article |
| id | doaj.art-19a2345429a149c8ba334ed826f11376 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T00:38:20Z |
| publishDate | 2009-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-19a2345429a149c8ba334ed826f113762022-12-22T00:05:11ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512m1616m161610.1107/S1600536809048430Poly[μ3-acetato-di-μ3-isonicotinato-μ2-isonicotinato-samarium(III)silver(I)]Li-Cai ZhuIn the title homochiral three-dimensional heterometallic complex, [AgSm(C6H4NO2)3(C2H3O2)]n, the eight-coordinate SmIII ion displays a bicapped trigonal-prismatic geometry, being coordinated by two O atoms from one acetate ligand, four O atoms from four bridging isonicotinate ligands and two O atoms from two terminal isonicotinate ligands. The four-coordinate AgI ion adopts a tetrahedral geometry, being bonded to two N atoms from two bridging isonicotinate ligands and two O atoms from two acetate ligands. These metal coordination units are connected by bridging isonicotinate and acetate ligands, generating a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536809048430 |
| spellingShingle | Li-Cai Zhu Poly[μ3-acetato-di-μ3-isonicotinato-μ2-isonicotinato-samarium(III)silver(I)] Acta Crystallographica Section E |
| title | Poly[μ3-acetato-di-μ3-isonicotinato-μ2-isonicotinato-samarium(III)silver(I)] |
| title_full | Poly[μ3-acetato-di-μ3-isonicotinato-μ2-isonicotinato-samarium(III)silver(I)] |
| title_fullStr | Poly[μ3-acetato-di-μ3-isonicotinato-μ2-isonicotinato-samarium(III)silver(I)] |
| title_full_unstemmed | Poly[μ3-acetato-di-μ3-isonicotinato-μ2-isonicotinato-samarium(III)silver(I)] |
| title_short | Poly[μ3-acetato-di-μ3-isonicotinato-μ2-isonicotinato-samarium(III)silver(I)] |
| title_sort | poly amp 956 3 acetato di amp 956 3 isonicotinato amp 956 2 isonicotinato samarium iii silver i |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809048430 |
| work_keys_str_mv | AT licaizhu polyamp9563acetatodiamp9563isonicotinatoamp9562isonicotinatosamariumiiisilveri |