Preparation of Crosslinked Amphiphilic Silver Nanogel as Thin Film Corrosion Protective Layer for Steel
Monodisperse silver nanoparticles were synthesized by a new developed method via reaction of AgNO3 and oleic acid with the addition of a trace amount of Fe3+ ions. Emulsion polymerization at room temperature was employed to prepare a core-shell silver nanoparticle with controllable particle size. N,...
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| Format: | Article |
| Language: | English |
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MDPI AG
2014-07-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/19/7/10410 |
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| author | Ayman M. Atta Gamal A. El-Mahdy Hamad A. Al-Lohedan Abdelrahman O. Ezzat |
| author_facet | Ayman M. Atta Gamal A. El-Mahdy Hamad A. Al-Lohedan Abdelrahman O. Ezzat |
| author_sort | Ayman M. Atta |
| collection | DOAJ |
| description | Monodisperse silver nanoparticles were synthesized by a new developed method via reaction of AgNO3 and oleic acid with the addition of a trace amount of Fe3+ ions. Emulsion polymerization at room temperature was employed to prepare a core-shell silver nanoparticle with controllable particle size. N,N'-methylenebisacrylamide (MBA) and potassium peroxydisulfate (KPS) were used as a crosslinker, and as redox initiator system, respectively for crosslinking polymerization. The structure and morphology of the silver nanogels were characterized by Fourier transform infrared spectroscopy (FTIR), transmission and scanning electron microscopy (TEM and SEM). The effectiveness of the synthesized compounds as corrosion inhibitors for steel in 1 M HCl was investigated by various electrochemical techniques such as potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). Monolayers of silver nanoparticle were self-assembled on the fresh active surface of the steel electrode and have been tested as a corrosion inhibitor for steel in 1 M HCl solution. The results of polarization measurements showed that nanogel particles act as a mixed type inhibitor. |
| first_indexed | 2024-12-22T09:53:57Z |
| format | Article |
| id | doaj.art-19a44edbcfc64678844aa669eaae710f |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-22T09:53:57Z |
| publishDate | 2014-07-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-19a44edbcfc64678844aa669eaae710f2022-12-21T18:30:18ZengMDPI AGMolecules1420-30492014-07-01197104101042610.3390/molecules190710410molecules190710410Preparation of Crosslinked Amphiphilic Silver Nanogel as Thin Film Corrosion Protective Layer for SteelAyman M. Atta0Gamal A. El-Mahdy1Hamad A. Al-Lohedan2Abdelrahman O. Ezzat3Surfactants Research Chair, Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Kingdom of Saudi ArabiaSurfactants Research Chair, Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Kingdom of Saudi ArabiaSurfactants Research Chair, Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Kingdom of Saudi ArabiaSurfactants Research Chair, Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Kingdom of Saudi ArabiaMonodisperse silver nanoparticles were synthesized by a new developed method via reaction of AgNO3 and oleic acid with the addition of a trace amount of Fe3+ ions. Emulsion polymerization at room temperature was employed to prepare a core-shell silver nanoparticle with controllable particle size. N,N'-methylenebisacrylamide (MBA) and potassium peroxydisulfate (KPS) were used as a crosslinker, and as redox initiator system, respectively for crosslinking polymerization. The structure and morphology of the silver nanogels were characterized by Fourier transform infrared spectroscopy (FTIR), transmission and scanning electron microscopy (TEM and SEM). The effectiveness of the synthesized compounds as corrosion inhibitors for steel in 1 M HCl was investigated by various electrochemical techniques such as potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). Monolayers of silver nanoparticle were self-assembled on the fresh active surface of the steel electrode and have been tested as a corrosion inhibitor for steel in 1 M HCl solution. The results of polarization measurements showed that nanogel particles act as a mixed type inhibitor.http://www.mdpi.com/1420-3049/19/7/10410silver nanoparticlesamphiphiliccorrosion inhibitorsnanogelsurface tension |
| spellingShingle | Ayman M. Atta Gamal A. El-Mahdy Hamad A. Al-Lohedan Abdelrahman O. Ezzat Preparation of Crosslinked Amphiphilic Silver Nanogel as Thin Film Corrosion Protective Layer for Steel Molecules silver nanoparticles amphiphilic corrosion inhibitors nanogel surface tension |
| title | Preparation of Crosslinked Amphiphilic Silver Nanogel as Thin Film Corrosion Protective Layer for Steel |
| title_full | Preparation of Crosslinked Amphiphilic Silver Nanogel as Thin Film Corrosion Protective Layer for Steel |
| title_fullStr | Preparation of Crosslinked Amphiphilic Silver Nanogel as Thin Film Corrosion Protective Layer for Steel |
| title_full_unstemmed | Preparation of Crosslinked Amphiphilic Silver Nanogel as Thin Film Corrosion Protective Layer for Steel |
| title_short | Preparation of Crosslinked Amphiphilic Silver Nanogel as Thin Film Corrosion Protective Layer for Steel |
| title_sort | preparation of crosslinked amphiphilic silver nanogel as thin film corrosion protective layer for steel |
| topic | silver nanoparticles amphiphilic corrosion inhibitors nanogel surface tension |
| url | http://www.mdpi.com/1420-3049/19/7/10410 |
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