Sodium and potassium ion rich ferroelectric solid electrolytes for traditional and electrode-less structural batteries
The transition to a sustainable society is vital and requires electrification. Sodium and potassium ion-based electrolytes will likely play an important role in energy storage as these elements are very abundant. The latter cations and chloride are especially interesting since life on the planet is...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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AIP Publishing LLC
2022-03-01
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| Series: | APL Materials |
| Online Access: | http://dx.doi.org/10.1063/5.0080054 |
| _version_ | 1811260339857129472 |
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| author | Federico Danzi Mafalda Valente Sylwia Terlicka M. Helena Braga |
| author_facet | Federico Danzi Mafalda Valente Sylwia Terlicka M. Helena Braga |
| author_sort | Federico Danzi |
| collection | DOAJ |
| description | The transition to a sustainable society is vital and requires electrification. Sodium and potassium ion-based electrolytes will likely play an important role in energy storage as these elements are very abundant. The latter cations and chloride are especially interesting since life on the planet is somehow based on biological transfers of these ions through cell membranes. K+ is the key charge carrier in plants. Here, we characterize electrochemically, electrostatically, and structurally novel electrolytes, K3ClO and K2.99Ba0.005ClO, and compare their performance with Na3ClO and Na2.99Ba0.005ClO in symmetric and asymmetric structural electrode-less cells, such as K/K2.99Ba0.005ClO in a cellulose membrane/K, Na/Na2.99Ba0.005ClO in a cellulose membrane/Na, Al/K2.99Ba0.005ClO composite/Cu, and Al/Na2.99Ba0.005ClO composite/Cu, at temperatures that range from −45 to 65 °C. An ab initio molecular dynamics structural study followed by band structure determination using density functional theory and hybrid simulations allowed us to compare the amorphous character of the structures, bandgap, and electron localization function for both K3ClO at 25 °C and Na3ClO at 37 °C, temperatures at which preliminary studies indicate that these compounds are already amorphous. As in Na+-based electrolytes, the ferroelectric character of the K+-based electrolytes is well recognizable, especially at −45 °C, where the relative real permittivity achieves 1013 in K/K2.99Ba0.005ClO in cellulose membrane/K symmetric cells for an ionic conductivity of ∼120 mS/cm. As in Na+-based electrodes-less structural battery cells, self-charge and self-cycling phenomena are also demonstrated reinforcing the ferroelectric nature of the A3ClO (A = Li, Na, and K) family of electrolytes. These studies may contribute to understanding the K+ and Na+ transfer behavior in energy harvesting and storage as well as the biologic world. |
| first_indexed | 2024-04-12T18:46:00Z |
| format | Article |
| id | doaj.art-19a7efb27bc7402abb472d38464fa7af |
| institution | Directory Open Access Journal |
| issn | 2166-532X |
| language | English |
| last_indexed | 2024-04-12T18:46:00Z |
| publishDate | 2022-03-01 |
| publisher | AIP Publishing LLC |
| record_format | Article |
| series | APL Materials |
| spelling | doaj.art-19a7efb27bc7402abb472d38464fa7af2022-12-22T03:20:37ZengAIP Publishing LLCAPL Materials2166-532X2022-03-01103031111031111-1510.1063/5.0080054Sodium and potassium ion rich ferroelectric solid electrolytes for traditional and electrode-less structural batteriesFederico Danzi0Mafalda Valente1Sylwia Terlicka2M. Helena Braga3LAETA-INEGI, Institute of Science and Innovation in Mechanical and Industrial Engineering, 4200-465 Porto, PortugalEngineering Physics Department, Engineering Faculty, University of Porto, R. Dr. Roberto Frias s/n, 4200-465 Porto, PortugalInstitute of Metallurgy and Materials Science, Polish Academy of Sciences, Reymonta 25 St., 30-059 Krakow, PolandLAETA-INEGI, Institute of Science and Innovation in Mechanical and Industrial Engineering, 4200-465 Porto, PortugalThe transition to a sustainable society is vital and requires electrification. Sodium and potassium ion-based electrolytes will likely play an important role in energy storage as these elements are very abundant. The latter cations and chloride are especially interesting since life on the planet is somehow based on biological transfers of these ions through cell membranes. K+ is the key charge carrier in plants. Here, we characterize electrochemically, electrostatically, and structurally novel electrolytes, K3ClO and K2.99Ba0.005ClO, and compare their performance with Na3ClO and Na2.99Ba0.005ClO in symmetric and asymmetric structural electrode-less cells, such as K/K2.99Ba0.005ClO in a cellulose membrane/K, Na/Na2.99Ba0.005ClO in a cellulose membrane/Na, Al/K2.99Ba0.005ClO composite/Cu, and Al/Na2.99Ba0.005ClO composite/Cu, at temperatures that range from −45 to 65 °C. An ab initio molecular dynamics structural study followed by band structure determination using density functional theory and hybrid simulations allowed us to compare the amorphous character of the structures, bandgap, and electron localization function for both K3ClO at 25 °C and Na3ClO at 37 °C, temperatures at which preliminary studies indicate that these compounds are already amorphous. As in Na+-based electrolytes, the ferroelectric character of the K+-based electrolytes is well recognizable, especially at −45 °C, where the relative real permittivity achieves 1013 in K/K2.99Ba0.005ClO in cellulose membrane/K symmetric cells for an ionic conductivity of ∼120 mS/cm. As in Na+-based electrodes-less structural battery cells, self-charge and self-cycling phenomena are also demonstrated reinforcing the ferroelectric nature of the A3ClO (A = Li, Na, and K) family of electrolytes. These studies may contribute to understanding the K+ and Na+ transfer behavior in energy harvesting and storage as well as the biologic world.http://dx.doi.org/10.1063/5.0080054 |
| spellingShingle | Federico Danzi Mafalda Valente Sylwia Terlicka M. Helena Braga Sodium and potassium ion rich ferroelectric solid electrolytes for traditional and electrode-less structural batteries APL Materials |
| title | Sodium and potassium ion rich ferroelectric solid electrolytes for traditional and electrode-less structural batteries |
| title_full | Sodium and potassium ion rich ferroelectric solid electrolytes for traditional and electrode-less structural batteries |
| title_fullStr | Sodium and potassium ion rich ferroelectric solid electrolytes for traditional and electrode-less structural batteries |
| title_full_unstemmed | Sodium and potassium ion rich ferroelectric solid electrolytes for traditional and electrode-less structural batteries |
| title_short | Sodium and potassium ion rich ferroelectric solid electrolytes for traditional and electrode-less structural batteries |
| title_sort | sodium and potassium ion rich ferroelectric solid electrolytes for traditional and electrode less structural batteries |
| url | http://dx.doi.org/10.1063/5.0080054 |
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